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负载型钴基超细粒子催化剂的催化性能
引用本文:许静,谢凯,陈一民,盘毅,雍成纲.负载型钴基超细粒子催化剂的催化性能[J].国防科技大学学报,2001,23(1):28-30.
作者姓名:许静  谢凯  陈一民  盘毅  雍成纲
作者单位:1. 国防科技大学航天与材料工程学院,湖南 长沙 410073
2. 国防科技大学航天与材料工程学院,湖南 长沙 410073谢凯
摘    要:采用共溶胶 -凝胶法和超临界干燥工艺 ,制备了负载型钴基超细粒子催化剂Co-SiO2 ,研究了该种催化剂对CO氧化反应的催化性能 ,并进一步考察了钴含量对其催化活性的影响。研究结果表明 ,该种催化剂在低钴含量 ( 1 %~ 2 % )时即对CO的氧化反应表现出高的催化活性 ,并具有优良的热稳定性和很宽的反应活性温度区域 ( 1 60℃~ 80 0℃ ) ;钴含量对其催化活性和稳定性有重要影响 ,在 0 1 %~ 2 %的含量范围内 ,随钴含量增加 ,催化活性和稳定性逐渐升高。

关 键 词:溶胶-凝胶法  钴基催化剂  超细粒子
文章编号:1001-2486(2001)01-0028-03
收稿时间:2000/10/5 0:00:00
修稿时间:2000年10月5日

Catalytic Performance of Supported Cobalt Ultrafine ParticalCatalysts
XU Jing,XIE Kai,CHEN Yimin,PAN Yi and YONG Chengang.Catalytic Performance of Supported Cobalt Ultrafine ParticalCatalysts[J].Journal of National University of Defense Technology,2001,23(1):28-30.
Authors:XU Jing  XIE Kai  CHEN Yimin  PAN Yi and YONG Chengang
Affiliation:College of Aerospace and Materials Engineering, National Univ. of Defense Technology, Changsha 410073, China;College of Aerospace and Materials Engineering, National Univ. of Defense Technology, Changsha 410073, China;College of Aerospace and Materials Engineering, National Univ. of Defense Technology, Changsha 410073, China;College of Aerospace and Materials Engineering, National Univ. of Defense Technology, Changsha 410073, China;College of Aerospace and Materials Engineering, National Univ. of Defense Technology, Changsha 410073, China
Abstract:Supported Co ultrafine partical catalysts were prepared by means of sol-gel methods and supercritical drying. Their catalytic performance for CO oxidation was studied. The results indicate that the catalysts have high activity even with low content (1%~2%). They show good heat stability and can be performed in a wide reaction temperature area ranging from 160℃ to 800℃ .With the increase of Co Concentration, the activity and stability of Co-SiO2 increase.
Keywords:sol-gel methods  ultrafine particle  supported cobalt catalysts
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