Tuning the particle size and morphology of high energetic material nanocrystals

Morphology controlled synthesis of nanoparticles of powerful high energetic compounds(HECs) such as l,3,5-trinitro-l,3,5-triazinane(RDX) and 1,3,5,7-tetranitro-l,3,5,7-tetrazocane(HMX) were achieved by a simple solvent—antisolvent interaction(SAI) method at 70 ℃.The effects of different solvents on particle size and morphology of the prepared nano-HECs were studied systematically.Particle size and morphology of the nano-HECs was characterized using field emission scanning electron microscopy(FE-SEM) imaging.X-ray diffraction(XRD) and Fourier transform infrared(FTIR) spectroscopy studies revealed that RDX and HMX were precipitated in their most stable polymorphic forms,i.e.a and P,respectively.Thermogravimetric analysis coupled with differential scanning calorimetry(TGA-DSC) studies showed that the thermal response of the nanoparticles was similar to the respective raw-HECs.HEC nanoparticles with spherical and rod shaped morphology were observed under different solvent conditions.The mean particle size also varied considerably with the use of different solvents.     

Enhanced structural damage behavior of liquid-filled tank by reactive material projectile impact

A series of ballistic experiments were performed to investigate the damage behavior of high velocity reactive material projectiles(RMPs) impacting liquid-filled tanks, and the corresponding hydrodynamic ram(HRAM) was studied in detail. PTFE/Al/W RMPs with steel-like and aluminum-like densities were prepared by a pressing/sintering process. The projectiles impacted a liquid-filled steel tank with front aluminum panel at approximately 1250 m/s. The corresponding cavity evolution characteristics an...     

Study on Aging Precipitation Characteristic of High Strength Al-Zn-Mg-Cu Alloy

The precipitation of MgZn2 phase in aging process of Al-Zn-Mg-Cu alloy forging was characterized qualitatively after transmission electron microscope(TEM)observation,X-ray diffraction phase analysis and the exact measure of lattice parameter.And,the precipitation of the second-phase in aging process was simulated after test the resistivity of the alloy in a continuous heating process and delayed time processing.The results show that when heating in the same rate,the alloy resistivity increases with temperature first,a mutation point appears at 110℃,and the resistivity reaches its peak at 120℃.Then,the resistivity decreases and achieves a minimum at about 170℃.Afterwards,it increases again.The change of resistivity results from a combined effect of the temperature and phase transformation.The volume precipitation of η' phase dominates at about 120℃,and the resistivity of forgings decreases accordingly.When the specimen cools in a furnace at 240℃,the phase transformation finishes basically and the alloy content of Al-matix keeps stable,thus,the alloy resistivity depends on the temperature only.It decreases with temperature and time since the end of precipitation.The higher the temperature is,the bigger it will be.With a big descending rate of the resistivity curve,the time to reach the stable value becomes shorter.     

Nano-silica modified lightweight and high-toughness carbon fiber/phenolic ablator with excellent thermal insulation and ablation performance

Lightweight and high-toughness carbon fiber/phenolic ablator(CFPA) is required as the Thermal Protection System(TPS) material of aerospace vehicles for next-generation space missions. To improve the ablative properties, silica sol with good particle size distribution prepared using tetramethoxysilane(TMOS) was blended with natural rubber latex and deposited onto carbon fiber felt, which was then integrated with phenolic aerogel matrix, introducing nano-silica into the framework of CFPA. The modi...     

The effect of Ti and Zr content on the structure,mechanics and energy-release characteristics of Ti—Zr—Ta alloys

Energetic structural materials(ESMs) are a new type of structural materials with bearing and damage characteristics.In this work the microstructure,mechanical properties and energy release characteristics of multi-element Ti-Zr-Ta alloys with good casting performance were studied.The microstructure of the Ti_xZrTa alloys gradually change from BCC+HCP to single BCC structure with the increase of Ti.While the Ti₂Zr_yTa alloys was still uniform and single BCC structur...     

Interfacial reinforcement of core-shell HMX@energetic polymer composites featuring enhanced thermal and safety performance

The weak interface interaction and solid-solid phase transition have long been a conundrum for 1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane(HMX)-based polymer-bonded explosives(PBX). A two-step strategy that involves the pretreatment of HMX to endow —OH groups on the surface via polyalcohol bonding agent modification and in situ coating with nitrate ester-containing polymer, was proposed to address the problem. Two types of energetic polyether—glycidyl azide polymer(GAP) and nitrate modified G...     

Optimization of friction stir welding parameters for improved corrosion resistance of AA2219 aluminum alloy joints

The aluminium alloy AA2219(Al—Cu—Mg alloy) is widely used in the fabrication of lightweight structures with high strength-to-weight ratio and good corrosion resistance.Welding is main fabrication method of AA2219 alloy for manufacturing various engineering components.Friction stir welding(FSW) is a recently developed solid state welding process to overcome the problems encountered in fusion welding.This process uses a non-consumable tool to generate frictional heat on the abutting surfaces.The welding parameters,such as tool pin profile,rotational speed,welding speed and axial force,play major role in determining the microstructure and corrosion resistance of welded joint.The main objective of this work is to develop a mathematical model to predict the corrosion resistance of friction stir welded AA2219 aluminium alloy by incorporating FSW process parameters.In this work a central composite design with four factors and five levels has been used to minimize the experimental conditions.Dynamic polarization testing was carried out to determine critical pitting potential in millivolt,which is a criteria for measuring corrosion resistance and the data was used in model.Further the response surface method(RSM) was used to develop the model.The developed mathematical model was optimized using the simulated annealing algorithm optimizing technique to maximize the corrosion resistance of the friction stir welded AA2219 aluminium alloy joints.     

H_∞-Mixed Sensitivity Design of Roll Channel of Bank-to-Turn Autopilot for Small Diameter Bomb

According to requirements of the bank-to-turn (BTT) control for a small diameter bomb (SDB), the robust design problem for the roll autopilot was studied by H∞-mixed sensitivity control method. A roll channel dynamics model was established. Considering the couple between the yaw and roll channel as uncertain disturbance, the roll autopilot was designed using dual-loop scheme which takes a linear quadratic regulator (LQR) as inner-loop, to ensure the control effect of the certain part in model, and an H∞-mixed sensitivity control as outer-loop, to restrain coupling disturbance and strengthen the system's robust performance. The dynamic tracking performance and the robustness for the parameter disturbance of the roll controller were analyzed. The simulated results show that the roll control system functions better and robustly.     

Optimal trajectory and heat load analysis of different shape lifting reentry vehicles for medium range application

The objective of the paper is to compute the optimal burn-out conditions and control requirements that would result in maximum down-range/cross-range performance of a waverider type hypersonic boost-glide(HBG) vehicle within the medium and intermediate ranges,and compare its performance with the performances of wing-body and lifting-body vehicles vis-a-vis the g-load and the integrated heat load experienced by vehicles for the medium-sized launch vehicle under study.Trajectory optimization studies were carried out by considering the heat rate and dynamic pressure constraints.The trajectory optimization problem is modeled as a nonlinear,multiphase,constraint optimal control problem and is solved using a hp-adaptive pseudospectral method.Detail modeling aspects of mass,aerodynamics and aerothermodynamics for the launch and glide vehicles have been discussed.It was found that the optimal burn-out angles for waverider and wing-body configurations are approximately 5° and 14.8°,respectively,for maximum down-range performance under the constraint heat rate environment.The down-range and cross-range performance of HBG waverider configuration is nearly 1.3 and 2 times that of wing-body configuration respectively.The integrated heat load experienced by the HBG waverider was found to be approximately an order of magnitude higher than that of a lifting-body configuration and 5 times that of a wing-body configuration.The footprints and corresponding heat loads and control requirements for the three types of glide vehicles are discussed for the medium range launch vehicle under consideration.     

Quaternion-Based Adaptive Trajectory Tracking Control of a Rotor-Missile with Unknown Parameters Identification

This paper investigates the adaptive trajectory tracking control problem and the unknown parameter identification problem of a class of rotor-missiles with parametric system uncertainties. First, considering the uncertainty of structural and aerodynamic parameters, the six-degree-of-freedom(6Do F) nonlinear equations describing the position and attitude dynamics of the rotor-missile are established, respectively,in the inertial and body-fixed reference frames. Next, a hierarchical adaptive traje...     

Quantitative Analysis of Components in OC-CS Sprays by High Performance Liquid Chromatography with Double Wavelength UV Detection

The method of reversed-phase high performance liquid chromatography was established for the determination of effective components in OC-CS spray using double wavelength UV detection.The method was utilized under following conditions:a column of Kromasil C18(250 mm × 4.6 mm,5 μm),mobile phase consisting of methanol/water(80 /20) at a flow rate of 0.8 mL/min,column temperature of 25 ℃,and the UV detection at 227 nm and 300 nm.Three key components in OC-CS spray could be distinguished clearly,including o-chlorobenzalmalononitrile(CS),oleoresin capsicum(OC) and dihydrocapsaicin(DC).This method has the advantages of fast,simple and satisfactory linear relationship between UV absorption and concentration.It may be considered to turn into a standard method for detection of related components in the spray.     

Molecular Dynamics Simulation of Shock Response of CL-20 Co-crystals Containing Void Defects

To investigate the effect of void defects on the shock response of hexanitrohexaazaisowurtzitane(CL-20)co-crystals, shock responses of CL-20 co-crystals with energetic materials ligands trinitrotoluene(TNT),1,3-dinitrobenzene(DNB), solvents ligands dimethyl carbonate(DMC) and gamma-butyrolactone(GBL)with void were simulated, using molecular dynamics method and reactive force field. It is found that the CL-20 co-crystals with void defects will form hot spots when impacted, significantly affecting...     

An Aid to Adults'learning English Words

<正>With the implementation of the policy of oponing to the outside,more and more people inChina have come to realize the importance of learnin and mastering a foreign 1anguage,English in particular,as an instrument of communicating with people from other countriesand.more often,of seeking for information contained in myriads of foreing publications soas to keep themselves posted in and keep up with the latest advences in the world.     

当代军语快译通⒄

Army corps——a tactical unit larger than a division and smaller than a field army.A corps usually consists of two or more divisions together with auxiliary arms and service.军比师大、比野战军团小的战术集团。一个军往往包括2个或更多的师,以及其他保障性单位和后勤单位。Army special operations com-ponent——the army component of a joint force spe-cial operations component.陆军特种作战编成联合部队特种作战编成中的陆军编成。Armyspecialoperationsforces——thoseactiveandreservecomponentarmyforcesdes-ign…     

Influence of Accelerated Aging on Detonation Performance of Explosives

To understand the aging effects on detonation performances of explosives,an accelerated aging mechanism and effect of explosives were analyzed.Based on the thermo-gravimetric(TG) curves of explosives under the heat rate of 5,10 and 20 K·min-1,the thermal decomposition activation energy,pre-exponential factor,mechanism function and kinetic equation of the explosives were calculated by Ozawa's equation and decomposition extents.Then,according to the derived kinetic equation,the density,composition and heat of formation of GI-1,PBX-1 and PBX-2 explosive in different decomposition extents were calculated at accelerated aging temperatures of 70 ℃ and 75 ℃,respectively.Furthermore,the detonation parameters of GI-1,PBX-1 and PBX-2 explosives were found out by means of VLWR code.The results show that after accelerated aging,the density are decrease,the detonation velocity and pressure are all decreased slightly.     

Cold Flow Experiments and Acoustic Investigation on Pressure Oscillation Induced by Flow Instability

Pressure oscillation in solid rocket motor is believed to be the results of the interaction between the flow instability and the acoustics of combustion chamber.Several reasonable and necessary hypothesizes are given to establish an equation to describe this coupling.A cold flow motor called CVS60D(corner vortex shedding 60°)was designed to study the flow-acoustic coupling based on theoretical analysis.Experimental investigations were carried out to determine the acoustics of CVS60D.Corner vortex shedding is generated at the backward facing step which is designed similar to the geometry of the motor with finocyl propellant after the burnout of its fins.A pintle was used to modify the velocity in the duct to change the frequency of vortex shedding.It is found that large amplitude pressure oscillation occurs when the pintle moves to a range of specific position,which indicates that the frequency of vortex shedding is close to one order of acoustic modes of combustion chamber.The amplitude of pressure oscillation changes as the pintle moves.     

Propagation Properties of Shock Waves in Polyurethane Foam based on Atomistic Simulations

Porous materials are widely used in the field of protection because of their excellent energy absorption characteristics. In this work, a series of polyurethane microscopic models are established and the effect of porosity on the shock waves is studied with classical molecular dynamics simulations. Firstly, shock Hugoniot relations for different porosities are obtained, which compare well with the experimental data.The pores collapse and form local stress wave, which results in the complex multi...     

Experimental investigation on weak shock wave mitigation characteristics of flexible polyurethane foam and polyurea

In recent years, explosion shock wave has been considered as a signature injury of the current military conflicts. Although strong shock wave is lethal to the human body, weak shock wave can cause many more lasting consequences. To investigate the protection ability and characteristics of flexible materials and structures under weak shock wave loading, the blast wave produced by TNT explosive is loaded on the polyurethane foam with the density of 200.0 kg/m3(F-200) and 400.0 kg/m3(F-400), polyur...     

Model Versions and Fast Algorithms for Network Epidemiology

Network epidemiology has become a core framework for investigating the role of human contact patterns in the spreadingof infectious diseases. In network epidemiology, one represents the contact structure as a network of nodes（individuals） connected bylinks（sometimes as a temporal network where the links are not continuously active） and the disease as a compartmental model（whereindividuals are assigned states with respect to the disease and follow certain transition rules between the states）. In this paper, we discussfast algorithms for such simulations and also compare two commonly used versions,one where there is a constant recovery rate（the numberof individuals that stop being infectious per time is proportional to the number of such people）;the other where the duration of the diseaseis constant. The results show that, for most practical purposes, these versions are qualitatively the same.     

Defence Technology Aims and Scope

<正>Defence Technology(ISSN:2214-9147).sponsored by China Ordnance Society,is published quarterly and aims to become one of the well-known comprehensive journals in the world,which reports on the breakthroughs in defence technology by building up an international academic exchange platform for the defence technology related research.It publishes original research papers having direct bearing on defence,with a balanced coverage on analytical,experimental,numerical simulation and applied investigations.It covers various disciplines of science,technology and engineering.