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1.
《防务技术》2022,18(10):1748-1759
Three-dimensional (3D) micro-jet printing is a droplet deposition technique based on liquid-phase materials. To improve the deposition density and performance of energetic films with micro/nanoscale on an energetic chip, polydopamine (PDA) was utilized as a linker bridge to induce the in-situ self-assembly of CL-20-based energetic film via 3D micro-jet printing. The self-assembly was extensively characterized by confocal laser scanning microscopy (CLSM), SEM, power-XRD, XPS, and DSC. The performance of the self-assembled film was verified by the mechanical properties and detonation properties, and a possible self-assembly mechanism in the layer-by-layer micro-jet printing process was proposed. The results indicated PDA-induced self-assembly enhanced the physical entanglement between the binders and energetic crystal, reduced the porosity from 15.87% to 11.28%, and improved the elastic modulus and the detonation performance of the CL-20-based energetic film. This work proposes a novel and promising energetic film design and fabrication strategy to enhance the interaction between the energetic composite layers in the micro-jet printing process.  相似文献   

2.
《防务技术》2022,18(10):1914-1921
The monolithic foamed propellants with high densities were prepared by casting and two-step foaming processes. Glycidyl azide polymer (GAP) and isocyanate were used as the binder system and 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (HNIW, CL-20) was employed as the energetic component. The newly designed formulation containing 60 % CL-20 produced a force constant of 1077 J/g and low flame temperature of 2817 K. Two foamed propellants with densities of 1.32 g/cm3 and 1.53 g/cm3 were fabricated by a confined foaming process and examined by closed bomb tests. The results revealed that porosity significantly affects burning performance. A size effect on combustion behaviors was observed for the foamed propellant with 5.56 % porosity, and a double-hump progressive dynamic vivacity curve was obtained. At last, the 30 mm gun test was carried out to demonstrate the interior ballistic performance, and the muzzle velocity increased by 120 m/s at the same maximum chamber pressure when monolithic propellant was added in the charge.  相似文献   

3.
A new type of explosive ink formulation that can be quickly cured was prepared with unsaturated polyester as binder,styrene as active monomer,2,4,6-trimethylbenzoyl-diphenylphosphine oxide as photoinitiator,and hexanitrohexaazaisowurtzitane (CL-20) as the main explosive.Then the explosive ink direct writing technology was used to charge the micro-sized energetic devices,the curing mechanism of the explosive ink was discussed,and the microstructure,safety performance and explosive transfer performance of the explosive ink molded samples were tested and analyzed.Results indicate that the composite material has a fast curing molding speed,its hardness can reach 2H within 8 min.The crystal form of CL-20 in the molded sample is still ε type.The CL-20 based W-curing explosive ink formulation has good compatibility,its apparent activation energy is increased by about 3.5 kJ/mol.The composite presents a significant reduction in impact sensitivity and its characteristic drop height can reach 39.8 cm,which is about 3 times higher than the raw material.When the line width of charge is 1.0 mm,the critical thickness of the explosion can reach 0.015 mm,and the explosion velocity is 7129 m/s when the charge density is 1.612 g/cm3.  相似文献   

4.
The core-shell 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane/2,4,6-Trinitrotoluene (CL-20/TNT) composite was prepared by spray-drying method in which sensitive high energy explosive (CL-20) was coated with insensitive explosive (TNT). The structure and properties of different formulations of CL-20/TNT composite and CL-20/TNT mixture were characterized by scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Laser particle size analyzer, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), differential scanning calorimetry (DSC), impact sensitivity test and detonation performance. The results of SEM, TEM, XPS and XRD show that ϵ-CL-20 particles are coated by TNT. When the ratio of CL-20/TNT is 75/25, core-shell structure is well formed, and thickness of the shell is about 20–30 nm. And the analysis of heat and impact show that with the increase of TNT content, the TNT coating on the core-shell composite material can not only catalyze the thermal decomposition of core material (CL-20), but also greatly reduce the impact sensitivity. Compared with the CL-20/TNT mixture (75/25) at the same ratio, the characteristic drop height of core-shell CL-20/TNT composite (75/25) increased by 47.6% and the TNT coating can accelerate the nuclear decomposition in the CL-20/TNT composites. Therefore, the preparation of the core-shell composites can be regarded as a unique means, by which the composites are characterized by controllable decomposition rate, high energy and excellent mechanical sensitivity and could be applied to propellants and other fields.  相似文献   

5.
《防务技术》2020,16(3):588-595
3D-Honeycombed CL-20 structures with low critical size of detonation have been fabricated successfully for intelligent weapon systems using a micro-flow direct ink writing (DIW) technology. The CL-20-based explosive ink for DIW technology was prepared by a two-component adhesive system with waterborne polyurethane (WPU) and ethyl cellulose (EC). Not only the preparation of the explosive ink but also the principle of DIW process have been investigated systematically. The explosive ink displayed strong shear-thinning behavior that permitted layer-by-layer deposition from a fine nozzle onto a substrate to produce complex shapes. The EC content was varied to alter the pore structure distribution and rheological behavior of ink samples after curing. The deposited explosive composite materials are of a honeycombed structure with high porosity, and the pore size distribution increases with the increase of EC content. No phase change was observed during the preparation process. Both WPU and EC show good compatibility with CL-20 particles. Apparently high activation energy was realized in the CL-20-based composite ink compared with that of the refined CL-20 due to the presence of non-energetic but stable WPU. The detonation performance of the composite materials can be precisely controlled by an adjustment in the content of binders. The 3D honeycombed CL-20 structures, which are fabricated by DIW technology, have a very small critical detonation size of less than 69 μm, as demonstrated by wedge shaped charge test. The ink can be used to create 3D structures with complex geometries not possible with traditional manufacturing techniques, which presents a bright future for the development of intelligent weapon systems.  相似文献   

6.
以聚碳硅烷和锑改性聚硅烷为先驱体,利用先驱体转化SiC材料的富余自由碳高温石墨化的微观结构演变特点,采用热压烧结、先驱体浸渍—裂解法以及退火工艺制备出先驱体转化SiC纳米复合材料。采用SEM、TEM、XRD和Raman等测试手段表征和分析了相组成和微观结构,讨论了样品的热导率、电导率和塞贝克系数等热电参数随温度变化关系。研究表明,所得致密SiC纳米复合材料为n型热电材料。由于纳米石墨的作用,材料热导率抑制在4–8W/(m?K)范围。1600°C退火处理能够降低热导率,同时提高电导率和塞贝克系数绝对值,使先驱体转化法得到的SiC纳米复合材料无量纲热电优值ZT达到0.0028(650°C),高于其他已报道的致密SiC/C复合材料和纳米复合材料体系。  相似文献   

7.
以聚碳硅烷和锑改性聚硅烷为先驱体,利用先驱体转化Si C材料的富余自由碳高温石墨化的微观结构演变特点,采用热压烧结、先驱体浸渍-裂解法以及退火工艺制备出先驱体转化Si C纳米复合材料。采用SEM、TEM、XRD和Raman等测试手段表征和分析了相组成和微观结构,讨论了样品的热导率、电导率和塞贝克系数等热电参数随温度变化关系。研究表明,所得致密Si C纳米复合材料为n型热电材料。由于纳米石墨的作用,材料热导率抑制在4~8W/(m·K)范围。1600℃退火处理能够降低热导率,同时提高电导率和塞贝克系数绝对值,使先驱体转化法得到的Si C纳米复合材料无量纲热电优值ZT达到0.0028(650℃),高于其他已报道的致密Si C/C复合材料和纳米复合材料体系。  相似文献   

8.
In nanocomposites, the interphase thickness may be comparable to the size of nano-particles, and hence, the effect of interphase layers on the mechanical properties of nanocomposites may be substantial. The interphase thickness to the nano-particle size ratio and properties variability across the interphase thickness are the most important affecting parameters on the overall behavior of nanocomposites. In this study, the effect of properties variability across the interphase thickness on the overall elastic and elasto-plastic properties of a polymeric clay nanocomposite (PCN) using a functionally graded (FG) interphase is investigated in detail. The results of the computational homogenization on the mesoscopic level show that Young's modulus variation of the interphase has a significant effect on the overall elastic response of nanocomposites in a higher clay weight ratio (Wt). Moreover, strength variation through the interphase has a notable effect on the elasto-plastic properties of PCNs. Also, the increase or decrease in stiffness of interphase from clay to matrix and vice versa have a similar effect in the overall behavior of nanocomposites.  相似文献   

9.
To study the thermal decomposition of Al/ZrH2/PTFE with different Al particle size as well as mechanical strength and impact sensitivity under medium and low strain rates, molding-vacuum sintering was adopted to prepare four groups of power materials and cylindrical specimens with different Al particle size. The active decomposition temperature of ZrH2 was obtained by TG-DSC, and the quasi-static me-chanics/reaction characteristics as well as the impact sensitivity of the specimen were studied respec-tively by quasi-static compression and drop-hammer test. The results show that the yield strength of the material decreased with the increase of the Al particle size, while the compressive strength, failure strain and toughness increased first and then decreased, which reached the maximum values of 116.61 MPa, 191%, and 119.9 MJ/m respectively when the Al particle size is 12—14μm because of particle size grading. The specimens with the highest strength and toughness formed circumferential open cracks and reacted partly when pressed. Those with developmental cracks formed inside did not react. It is considered that fracture of specimens first triggered initial reaction between Al and PTFE to release an amount of heat. Then ZrH2 was activated and decomposed, and participated in subsequent reaction to generate ZrC. The impact sensitivity of the specimens decreased with the increase of Al particle size.  相似文献   

10.
Ceramic reinforced metal matrix nanocomposites are widely used in aerospace and auto industries due to their enhanced mechanical and physical properties. In this research, we investigate the mechanical properties of aluminum/Nano-silica composites through experiments and simulations. Aluminum/Nano-silica composite samples with different weight percentages of silica nanoparticles are prepared via powder metallurgy. In this method, Nano-silica and aluminum powders are mixed and compressed in a mold, followed by sintering at high temperatures. Uniaxial tensile testing of the nanocomposite samples shows that adding one percent of Nano-silica causes a considerable increase in mechanical properties of nanocomposite compared to pure aluminum. A computational micromechanical model, based on a representative volume element of aluminum/silica nanocomposite, is developed in a commercial finite element software. The model employs an elastoplastic material model along with a ductile damage model for aluminum matrix and linear elastic model for nano-silica particles. Via careful determination of model parameters from the experimental results of pure aluminum samples prepared by powder metallurgy, the proposed computational model has shown satisfactory agreement with experiments. The validated computational model can be used to perform a parametric study to optimize the micro-structure of nanocomposite for enhanced mechanical properties.  相似文献   

11.
Hexagonal boron nitride nanosheets(HBNNSs)have huge potential in the field of coating materials owing to their remarkable chemical stability,mechanical strength and thermal conductivity.Thin-layer hBNNSs were obtained by a liquid-phase exfoliation of h-BN powders and incorporated into EVA coatings for improving the safety performance of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX).HBNNSs and ethylene-vinyl acetate copolymer(EVA)were introduced to HMX by a solvent-slurry process.For com-parison,the HMX/EVA and HMX/EVA/graphene(HMX/EVA/G)composites were also prepared by a similar process.The morphology,crystal form,surface element distribution,thermal decomposition property and impact sensitivity of HMX/EVA/hBNNSs composites were contrastively investigated.Results showed that as prepared HMX/EVA/hBNNSs composites were well coated with hBNNSs and EVA,and exhibited better thermal stability and lower impact sensitivity than that of HMX/EVA and HMX/EVA/G composites,suggesting superior performance of desensitization of hBNNSs in explosives.  相似文献   

12.
采用纳米电刷镀技术在钢基体表面制备了n-Al2O3/Ni-P复合刷镀层,研究了复合刷镀液中纳米颗粒含量、刷镀电压和刷镀笔移动速度对复合刷镀层中P和Al2O3含量的影响.优化后的工艺参数范围为刷镀液中n-Al2O3颗粒含量20~30 g/L、刷镀电压8~12 V、刷镀笔移动速度5~10 m/min.制备的n-Al2O3/Ni-P复合刷镀层组织致密,含有纳米颗粒和非晶相.  相似文献   

13.
本系统为以AT89C51单片机作为主控芯片的温度测量系统,采用一线温度传感器DS18820实现温度的检测,结合128×64点阵式液晶显示模块OCM12864作为显示器,形象直观地显示测得的温度值。主要介绍了该系统的硬件结构和软件编程实现的方法,数字温度传感器DS18820的基本特性,阐述了DDRAM寻址与液晶点阵的对应关系及中文字符、中文菜单在液晶模块上的显示规则。  相似文献   

14.
针对超高温环境应用需求,采用化学气相渗透工艺(CVI)与先驱体浸渍-裂解工艺(PIP)联用制备了3维碳纤维增强SiC-ZrC基复合材料(C/SiC-zrC),并研究了SiC含量对C/SiC-ZrC复合材料力学性能、抗氧化性能和抗烧蚀性能的影响.结果表明,随着SiC含量的增加,C/SiC-ZrC复合材料的强度逐渐降低,静...  相似文献   

15.
以聚己内酯二醇(PCL)、异佛尔酮二异氰酸酯(IPDI)、二羟甲基丙酸(DMPA)和季戊四醇三丙烯酸酯(PETA)为原料,合成了高官能度水性聚氨酯丙烯酸酯WPUA。以WPUA为有机相,γ-甲基丙烯酰氧丙基三甲氧基硅烷(TMSPM)改性纳米SiO2为无机相,制备了水性光固化有机/无机纳米杂化体系。通过傅立叶变换红外光谱对合成产物进行了表征,并对杂化薄膜的表面形貌、热稳定性、光固化动力学及力学性能进行了分析。结果表明合成了预期产物,杂化体系中改性纳米SiO2分散均匀稳定;随着SiO2含量的增加,材料的热稳定性、力学性能均有明显提高;不同SiO2条件下体系均保持了较高的光固化速率和最终凝胶含量。  相似文献   

16.
Explosive welding technique is widely used in many industries. This technique is useful to weld different kinds of metal alloys that are not easily welded by any other welding methods. Interlayer plays an important role to improve the welding quality and control energy loss during the collision process. In this paper, the Ti6Al4V plate was welded with a copper plate in the presence of a commercially pure titanium interlayer. Microstructure details of welded composite plate were observed through optical and scanning electron microscope. Interlayer-base plate interface morphology showed a wavy structure with solid melted regions inside the vortices. Moreover, the energy dispersive spectroscopy analysis in the interlayer-base interface reveals that there are some identified regions of different kinds of chemical equilibrium phases of Cu–Ti, i.e. CuTi, Cu2Ti, CuTi2, Cu4Ti, etc. To study the mechanical properties of composite plates, mechanical tests were conducted, including the tensile test, bending test, shear test and Vickers hardness test. Numerical simulation of explosive welding process was performed with coupled Smooth Particle Hydrodynamic method, Euler and Arbitrary Lagrangian-Eulerian method. The multi-physics process of explosive welding, including detonation, jetting and interface morphology, was observed with simulation. Moreover, simulated plastic strain, temperature and pressure profiles were analysed to understand the welding conditions. Simulated results show that the interlayer base plate interface was created due to the high plastic deformation and localized melting of the parent plates. At the collision point, both alloys behave like fluids, resulting in the formation of a wavy morphology with vortices, which is in good agreement with the experimental results.  相似文献   

17.
航天器姿态控制系统需要特殊的运行环境,在地面很难考核,这给系统可靠性带来一定的风险。针对微纳卫星的特点,设计并研制了一套面向微纳卫星的姿态确定与控制半实物仿真系统。该系统通过数字化模型模拟卫星姿态轨道运动、敏感器模型产生敏感器测量数据、执行器模型生成控制力矩、敏感器模拟器实现通信协议,最终实现姿态控制系统的全系统仿真。这套系统可以接入卫星控制系统回路,实现对姿控系统软件、硬件的考核,同时验证算法的性能。基于该系统,对天拓三号卫星姿控系统进行地面半实物仿真,并对比在轨试验数据,结果表明系统设计合理,仿真结果可信。  相似文献   

18.
分析了馈能型交流电子负载谐波间谐波产生的机理,基于馈能型电子负载工作原理,对电子负载输出信号进行研究,得出输出信号含有谐波间谐波等多种成分.采用MUSIC算法估计电力谐波信号频率,针对电力信号实值的特点,对MUSIC算法进行相应改进,获得较高的检测精度,同时对比了FFT算法的频率估计结果,得出MUSIC对电力谐波信号尤其是间谐波等负载谐波具有更高的精度,对电力系统监测及电能质量评估有较大应用价值.  相似文献   

19.
纳米Si-C-N粒子增强Si3N4 复合材料的结构与性能   总被引:2,自引:0,他引:2       下载免费PDF全文
本文用Si-C-N纳米微粉做增强相,Si3N4微粉为基相,采用热压的方法制备了SiCp/Si3N4纳米复相陶瓷,所得的SiCp/Si3N4复合材料的室温弯曲强度为878.5MPa,断裂韧性达11.96MPam1/2,同时应用扫描电镜(SEM)、高分辨透射电镜(HRTEM)对其结构进行了观察,讨论了结构与性能之间的关系。  相似文献   

20.
利用视觉/惯导对空间非合作目标进行相对导航时,两敏感器的外参数对导航精度有较大影响。考虑到敏感器间的外参数标定复杂且耗时,提出一种利用视觉/惯导在估计相对状态过程中对其外参数进行标定的方法。该方法将视觉/惯导的外参数作为状态变量,与相对轨道运动学方程、相对姿态方程及惯导模型共同组成系统状态方程。利用该状态方程和单目视觉的观测量设计扩展卡尔曼滤波器对相对位姿、惯导偏差及视觉/惯导外参数进行估计,并通过数学仿真对该方法的有效性进行验证。仿真结果表明,该方法能够在视觉/惯导初始外参有偏差的情况下,有效估计相对位姿及惯导漂移,并对视觉/惯导外参数进行标定。  相似文献   

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