H2O2/HTPB固液混合发动机点火试验研究

利用H2O2催化分解原理,设计了烃类燃料在催化分解的90%H2O2中能燃烧的点火器,然后采用该点火器进行H2O2/HTPB固液混合发动机点火试验研究.试验结果表明,该点火器能够成功启动H2O2/HTPB固液混合发动机,且当混合比偏离最佳混合比后,发动机的燃烧效率降低.     

Al/H2O2作为无人水下航行器动力电池的研究

概述了Al/H2O2半燃料电池的原理及在水下无人航行器动力电源中的运用,系统分析了国内外在电极材料(包括阳极和阴极材料)、电解液和电解液补充优化系统几个方面的发展,提出了国内在这方面研究的重点技术和可能的解决途径.     

基于动力学和扩散分段控制的Mg/H2O反应模型及数值分析

为了数值研究宽广温度范围内Mg/H2O的反应特性,分别建立了考虑部分MgO在液滴表面凝聚的Mg/H2O扩散燃烧模型和基于Arrhenius公式的Mg/H2O反应动力学模型.数值研究了Mg/H2O反应速率在扩散控制和化学动力学控制下随反应条件变化的规律.研究结果表明,Mg液滴扩散燃烧时间计算结果与文献值相符;提高温度和水...     

高pH条件纳米Fe_3O_4催化H_2O_2分解去除水中4-氯酚

为了克服非均相fenton催化反应中溶液初始pH过低的缺点,开展了pH=5时Fe3O4/H2O2体系催化氧化去除水中4-氯酚实验。试验结果表明:制备的铁氧化物为纯Fe3O4,具有反尖晶石八面体结构。纳米Fe3O4能够高效催化H2O2分解氧化水中的4-氯酚,反应180 min后4-氯酚的去除率达到96.8%。当催化剂投量小于2.0 g/L,4-氯酚的去除率随着催化剂投量的增加而升高;当催化剂投量大于2.0 g/L,去除率会随着投量的增加而降低。随着H2O2投量的增加,4-氯酚的去除率先升高后降低。溶液的初始pH对4-氯酚的去除影响较大,pH越低,去除速率和效率越高。重复使用5次以后,纳米Fe3O4仍然保持较高的催化活性。     

燃烧合成原位增韧氧化铝基复合陶瓷的显微结构与力学性能

通过燃烧合成技术制备出了氧化铝棒晶为基的Al2O3/ZrO2复合陶瓷棒材,研究了大体积Al2O3/ZrO2复合陶瓷的显微结构及力学性能.经对其性能测试发现,陶瓷的硬度和断裂韧性最高可达22.1 GPa和9.16 MPa·m0.5;通过对裂纹扩展路径观察,发现材料增韧是通过以氧化铝棒晶桥接与拔出增韧为主并伴有α-Al2O3片晶桥接多重增韧机制予以实现;经实验分析,可进一步认为以增大燃烧放热量来提高实际熔体温度,并在离心力作用下,进行材料高温高压合成,可显著提升材料的强韧性.     

空气/煤油/水燃气发生器点火特性试验

燃气发生器是超燃冲压发动机地面试验系统中的关键设备,为提高系统安全性和经济性设计了空气/煤油/水燃气发生器,在富燃状态下进行了一系列点火试验,试验结果表明:该型燃气发生器,实现可靠点火的余氧系数下限为0.51;水的加入使得化学反应速率和火焰传播速度降低,燃气发生器点火和火焰稳定困难,提高余氧系数可以提高点火可靠性。同时,水的加入容易引起燃烧不稳定,通过提高余氧系数来消除低频不稳定燃烧。     

空气/煤油/水燃气发生器点火特性试验研究

燃气发生器是超燃冲压发动机地面试验系统中的关键设备,为提高系统安全性和经济性设计了空气/煤油/水燃气发生器,在富燃状态下进行了一系列点火试验,试验结果表明：该型燃气发生器,实现可靠点火的余氧系数下限为0.51;水的加入使得化学反应速率和火焰传播速度降低,燃气发生器点火和火焰稳定困难,提高余氧系数可以提高点火可靠性。同时水的加入容易引起燃烧不稳定,通过提高余氧系数可消除低频不稳定燃烧。     

(CH3)2SiCl2和N2H4 反应产物为先驱体制备Si/C/N纳米微粉

采用(CH3)2SiCl2和N2H4反应产物为先驱体,在H2、NH3气条件下,用化学气相裂解法制备出Si/C/N纳米复合微粉这一全新的合成体系.对温度、气体流量,H2/NH3的比例等合成工艺条件对微粉的性质、形貌、组成等的影响进行了较为系统的讨论,并从热力学和动力学的角度初步讨论了产物裂解机理及组成的变化形成机理.所合成的Si/C/N微粉为无定型球状颗粒,N的含量从16.49%～26.75%可调,粒径最小达40 nm.     

纳米Al2O3／聚酰亚胺耐高温应急粘接堵漏材料的研究

研究了纳米Al2O3粒子对聚酰亚胺粘接材料性能的影响.结果表明,纳米Al2O3粒子能明显提升聚酰亚胺粘接堵漏材料的粘接性能.当纳米Al2O3粒子添加量为8%～12%时,聚酰亚胺粘接堵漏材料的剪切强度可提高37%;纳米Al2O3/聚酰亚胺粘接堵漏材料在高温固化过程中,纳米Al2O3产生向粘接界面偏析现象.     

Na_2SO_4·10H_2O相变过程及其相变潜热的计算

利用CDR-34P差动热分析仪测试Na2SO4·10H2O相变前后的热效应,结合Na2SO4-H2O体系的二元相图,分析相变前后热效应的来源及体系相态、组分的变化;提出无机水合盐相变潜热除来源结晶水脱离外还包括固相物质溶解、溶液浓度梯度变化的热效应的观点;根据上述相变过程计算Na2SO4·10H2O相变潜热,误差仅为2%.     

烧结助剂对热压SiCw/Si3N4复合材料性能的影响

本文通过热压的方法分别制得以Ｙ２Ｏ３－Ａｌ２Ｏ３和Ｙ２Ｏ３－Ｌａ２Ｏ３为烧结助剂的ＳｉＣｗ／Ｓｉ３Ｎ４陶瓷基复合材料，对比了采用不同种类及含量的烧结助剂的ＳｉＣｗ／Ｓｉ３Ｎ４复合材料的性能结果，发现烧结助剂的种类及含量对ＳｉＣｗ／Ｓｉ３Ｎ４复合材料的弯曲强度和断裂韧性有明显的影响，对高温弯曲强度的影响尤为显著。     

低Ni/改性Al2O3催化剂表面性质表征

本文用氧吸附法和程序升温脱附（ＴＰＤ）法分别考察低Ｎｉ／改性Ａｌ２Ｏ３催化剂的分散度，环已烷和苯的吸附脱附性能。结果表明：该催化剂分散性好，表面至少存在两种吸附中心。苯、环已烷在该催化剂的表面上属于一级可逆吸附脱附过程，催化剂表面能量分布不均匀。     

Study on Effects of Oxydal on Diesel Engine Combustion

Based on the analysis of the high temperature decomposition of oxydal(H2O2)and the combustion of diesel engine,the effects of H2O2 on the improvement of diesel combustion were studied.An oxydal spray system was designed to inject H2O2/water mixture into the manifold.The experiment was carried out on a 1135 diesel engine bench.The results show that H2O2 injection can make the curve of heat release rate move forward and decrease its peak value.The specific fuel consumption is decreased a little,while both NOx and PM emission are obviously reduced.     

火箭推进剂废水的危害及其治理

我国目前常用的推进剂是以偏二甲肼、四氧化二氮为主的液体双组元推进剂,其毒性为Ⅲ级。文中主要论述了推进剂废水对水体、土壤的污染和对人体健康、牲畜、渔业等的危害,以及臭氧-紫外线、自然净化等治理方法,并提出了加强管理、开发新的废水处理方法的建议。     

The surface activation of boron to improve ignition and combustion characteristic

Boron is a very promising and highly attractive fuel because of high calorific value. However, the practical applications in explosives and propellants of boron have been limited by long ignition delay time and low combustion efficiency. Herein, nano-Al and graphene fluoride (GF) as surface activated materials are employed to coat boron (B) particles to improve ignition and combustion performance. The reaction heat of nano-Al coated B/KNO₃ and GF coated B/KNO₃ are 1116.83 J/g and 862.69 J/g, respectively, which are higher than that of pure B/KNO₃ (823.39 J/g). The ignition delay time of B/KNO₃ could be reduced through nano-Al coating. The shortest ignition delay time is only 75 ms for B coated with nano-Al of 8 wt%, which is much shorter than that of pure B/KNO₃ (109 ms). However, the ignition delay time of B/KNO₃ coated with GF has been increased from 109 to 187 ms. B coated with GF and nano-Al shown significantly influence on the pressure output and flame structure of B/KNO₃. Furthermore, the effects of B/O ratios on the pressure output and ignition delay time have been further fully studied. For B/KNO₃ coated with nano-Al and GF, the highest pressures are 88 KPa and 59 KPa for B/O ratio of 4:6, and the minimum ignition delay time are 94 ms and 148 ms for B/O ratio of 7:3. Based on the above results, the reaction process of boron coated with GF and nano-Al has been proposed to understand combustion mechanism.     

Gas metal arc welding of high nitrogen stainless steel with Ar-N2-O2 ternary shielding gas

High nitrogen stainless steel with nitrogen content of 0.75％was welded by gas metal arc welding with Ar—N2-O2 ternary shielding gas. The effect of the ternary shielding gas on the retention and improvement of nitrogen content in the weld was identified. Surfacing test was conducted first to compare the ability of O2 and CO2 in prompting nitrogen dissolution. The nitrogen content of the surfacing metal with O2 is slightly higher than CO2. And then Ar—N2-O2 shielding gas was applied to weld high nitrogen stainless steel. After using N2-containing shielding gas, the nitrogen content of the weld was improved by 0.1 wt％. As N2 continued to increase, the increment of nitrogen content was not obvious, but the ferrite decreased from the top to the bottom. When the proportion of N2 reached 20％, a full austenitic weld was obtained and the tensile strength was improved by 8.7％. Combined with the results of surfacing test and welding test, it is concluded that the main effect of N2 is to inhibit the escape of nitrogen and suppress the ni-trogen diffusion from bottom to the top in the molten pool.