长期贮存的固体发动机药柱脱粘界面裂纹分析

为了分析长期贮存的固体导弹发动机药柱脱粘层界面裂纹在燃气内压和轴向过载联合作用下的扩展情况,建立了发动机药柱在包覆层与推进剂之间脱粘的三维有限元计算模型,并于脱粘界面的裂纹尖端设置三维奇异裂纹元,模拟脱粘界面裂纹扩展。在包覆层与推进剂之间设置不同深度脱粘,计算了在燃气内压和轴向过载联合作用下不同贮存期、不同深度的界面裂纹尖端的应力强度因子,得到了界面裂纹应力强度因子随贮存时间、脱粘深度的变化规律,对长期贮存的固体发动机脱粘界面裂纹的扩展进行了分析。     

定应变作用下NEPE推进剂老化特性及寿命预估研究

为考察定应变作用下NEPE推进剂的老化特性,研究了20%定应变作用下NEPE推进剂贮存老化过程中力学性能、凝胶性能和界面性能的变化.研究结果表明:定应变作用下NEPE推进剂在贮存老化过程中最大抗拉强度降低,最大延伸率变化较小,其老化失效主要表现为强度的失效;定应变下NEPE推进剂的凝胶百分数和粘附功随老化时间的延长而降低,NEPE推进剂粘合剂基体的降解断裂和界面的"脱湿"是其主要的老化机理;定应变下NEPE推进剂的力学性能与细观性能的相关性研究表明,最大抗拉强度与凝胶百分数和粘附功存在相关关系,计算了其关系式,建立了由细观性能评估推进剂宏观力学性能的方法;选择最大抗拉强度下降30%时失效,20%定应变下NEPE推进剂的贮存寿命为8.3年.     

材料性能对固体发动机结构完整性的影响

基于描述粘弹性材料特性的Burgers模型的本构关系以及基于该本构关系下的有限元方法 ,根据温度载荷和内压载荷的特点 ,分别建立了分析某固体发动机材料性能参数对结构完整性影响的有限元模型。应用MSC/NAS TRAN结构分析软件 ,详细分析了在温度和内压载荷作用下固体发动机材料性能参数对结构完整性的影响。在温度载荷的作用下 ,主要影响结构完整性的是推进剂的泊松比与热膨胀系数 ;在内压载荷作用下 ,主要影响结构完整性的是包覆层和推进剂的泊松比以及推进剂的初始模量。所得的结论可为固体发动机的生产设计提供参考     

位移不连续法在裂纹扩展仿真中的应用

探讨了在应用位移不连续法仿真裂纹扩展时对加载方式、裂纹扩展长度及应力强度因子计算等问题的处理方法,并据此编制了仿真程序,分析了裂纹在单向压载作用下的扩展趋势和应力变化,具有一定的工程应用价值。     

铝制贮箱箱底初步断裂分析

本报告应用断裂力学方法,对铝合金贮箱箱底进行了初步的分析。应力计算主要考虑了箱底在内压作用下的薄膜应力和由边缘效应引起的弯曲应力以及假定的焊接残余应力。断裂分析包括对表面裂纹临界尺寸的线弹性和弹塑性计算,给出了母材和焊缝处的临界裂纹尺寸;确定了加载20次到201次时所允许的最大初始裂纹尺寸。对一维和二维裂纹扩展模型进行了比较,指明二维扩展模型更为合理。最后对验证实验以及超声波检查配合使用进行了简单的讨论。给出了在本文条件下,贮箱箱底的无损检验标准和确定验证试验的方案。     

内压作用下复合材料修复裂纹管道的失效分析

为准确评估在内压作用下纤维复合材料修复含裂纹管道的有效性及失效压力,建立复合材料修复后裂纹管道的失效数值模型。该数值模型通过扩展有限元法模拟管道裂纹的扩展,利用cohesive单元模拟胶层的脱粘失效,复合材料的失效通过最大应力失效准则进行判定。通过静水压爆裂试验对所提失效数值模型进行验证,实验结果与数值计算结果具有较好的一致性。失效数值分析结果表明:当内压增大至一定值后,未修复管道的初始裂纹沿轴向及壁厚方向逐渐扩展,进而使得管道内壁单元扩展成真实裂纹,此时真实裂纹贯穿整个壁厚方向,即认为裂纹管道发生爆裂失效,爆裂失效压力随初始裂纹半长呈指数形式下降。复合材料修复裂纹管道的不同修复工况呈现相同的失效模式:在单调递增的内压作用下,管道内表面首先出现黏结裂纹,而后其外表面裂纹张开趋势急剧上升,使得复合材料层应力急剧上升,达到极限强度而失效。且对于不同的初始裂纹尺寸,存在对应的复合材料缠绕层数临界值。     

橡胶-钢粘接界面断裂问题非线性有限元分析

为解决橡胶-钢粘接界面断裂非线性有限元计算问题,建立了含初始裂纹的橡胶-钢粘接复合结构有限元模型;用张开位移作为裂纹开裂的判定参数并模拟了裂纹的扩展,计算值与试验值的对比证明了该方法的可行性;计算了开裂前粘接界面的层间应力,分析了开裂前裂纹前沿和沿裂纹扩展方向的层间应力变化情况;用断裂力学中的柔度法计算橡胶-钢复合结构的能量释放率,计算并分析了能量释放率沿裂纹扩展方向的变化情况,并与实验结果进行了对比验证,结果证明:该方法是可行的。     

复合固体推进剂等效力学性能VCFEM细观预示方法

根据固体推进剂的细观结构特征,采用等圆最优装载方式生成代表性体积单元(Representative Volume Element,RVE)模型,并结合Voronoi单元有限元方法(Voronoi Cell Finite Element Method,VCFEM)和均匀化方法,发展了一种可预示固体推进剂等效力学性能的数值分析方法,从而得到体分比和组分材料对等效模量和等效泊松比的影响规律。为证明该方法的有效性,设计一个对称数值模型,通过对该方法和传统有限元方法的节点位移结果的比较,发现两者之间的相对误差小于5%,且VCFEM用少量单元就完成了分析,提高了计算效率。通过对不同细观结构下推进剂RVE模型的计算,发现随着夹杂体分比的增大,夹杂的颗粒增强效应越明显,基体材料的变化比夹杂材料对等效力学性能有着更加显著的影响。     

在爆炸载荷作用下固支梁或筒形弯曲板的塑性动态断裂

本文运用刚塑性分析方法研究了在爆炸载荷作用下固支梁的全塑性动态断裂过程。在爆炸载荷作用下,固支梁将首先在固支端进入塑性变形,当固支端塑性铰转角达到其临界值,或固支端处初始裂纹尖端张开位移达到其临界值时(如果固支端有初始裂纹的话),固支端将产生开裂和裂纹扩展。本文解给出了在动态断裂过程中固支梁裂纹扩展长度、裂纹扩展速度以及梁的轴向约束力随时间变化的规律,并给出了不同载荷幅值下梁的启裂条件和止裂条件以及最终裂纹扩展长度和最大挠度。该分析解也适用于固支筒形弯曲板的断裂问题。     

低温推进剂供应管道系统充填过程的动力学模型

研究了低温推进剂液体火箭发动机供应管道系统充填过程的建模问题。低温推进剂的充填相变过程采用均相模型,对推进剂充填管道系统进行有限元分割,应用基本守恒定律于充满推进剂的单元和充满气体的单元,两相单元采用等效流容方程,建立了低温推进剂管道充填过程的有限元状态变量模型。充填的容腔视为两相单元,建立了其动力学模型。利用本文的模型,对液氢、液氧推进剂的管道充填过程进行了仿真计算,给出了有关计算结果。     

复合固体推进剂颗粒填充模型及其统计特性分析

复合固体推进剂属于高填充比颗粒类复合材料,氧化剂和金属颗粒在基体中的随机分布使其在细观尺度具有非均质的特点。从细观尺度研究固体推进剂燃烧及力学性能时,必须考虑颗粒级配、空间分布和种类等因素的影响。采用分子动力学方法,以硝酸酯增塑聚醚高能复合固体推进剂为研究对象,将固体颗粒模型化为球形,生成其在基体内随机分布的颗粒填充模型。利用Monte-Carlo算法模拟计算颗粒填充模型细观结构的两点概率函数,并研究了颗粒填充体积分数、尺寸与级配等参数对其的影响规律。从统计意义上给出具有各态历经性、统计均匀性和各向同性特点的颗粒填充构型最小周期性代表体元尺寸,可有效减小后续研究的计算量,节约计算成本。所构建的推进剂细观几何构型及对最小周期性代表体元尺寸的计算为后续开展复合固体推进剂细观尺度燃烧、燃面处铝团聚及力学性能数值研究奠定了基础。     

Recent progress on transition metal oxides and carbon-supported transition metal oxides as catalysts for thermal decomposition of ammonium perchlorate

As a main oxidizer in solid composite propellants, ammonium perchlorate (AP) plays an important role because its thermal decomposition behavior has a direct influence on the characteristic of solid com-posite propellants. To improve the performance of solid composite propellant, it is necessary to take measures to modify the thermal decomposition behavior of AP. In recent years, transition metal oxides and carbon-supported transition metal oxides have drawn considerable attention due to their extraor-dinary catalytic activity. In this review, we highlight strategies to enhance the thermal decomposition of AP by tuning morphology, varying the types of metal ion, and coupling with carbon analogue. The enhanced catalytic performance can be ascribed to synergistic effect, increased surface area, more exposed active sites, and accelerated electron transportation and so on. The mechanism of AP decom-position mixed with catalyst has also been briefly summarized. Finally, a conclusive outlook and possible research directions are suggested to address challenges such as lacking practical application in actual formulation of solid composite propellant and batch manufacturing.     

Sandwich structure for enhancing the interface reaction of hexanitrohexaazaisowurtzitane and nanoporous carbon scaffolds film to improve the thermal decomposition performance

Improving the thermal decomposition performance of hexanitrohexaazaisowurtzitane (CL-20) by appropriate methods is helpful to promote the combustion performance of CL-20-based solid propellants. In this study, we synthesized a sandwich structure of CL-20 and nanoporous carbon scaffolds film (NCS) and emphatically studied the thermal decomposition performance of the composite structure. Thermogravimetric analysis and differential scanning calorimetry were used to measure the thermal decomposition process of the composite structure. The kinetic parameters of thermal decomposition were calculated by the thermal dynamic analysis software AKTS. These results showed that the thermal decomposition performance of the sandwich structure of CL-20 and NCS was better than CL-20. Among the tested samples, NCS with a pore size of 15 nm had the best catalytic activity for the thermal decomposition of CL-20. Moreover, the thermal decomposition curve of the composite structure at the heating rate of 1 K/min was deconvoluted by mathematical method to study the thermal decomposition process. And a possible catalytic mechanism was proposed. The excellent thermal decomposition performance is due to the sandwich structure enhances the interface reaction of CL-20 and NCS. This work may promote the extensive use of CL-20 in the field of solid rocket propellant.     

Analysis on damage characteristics and detonation performance of solid rocket engine charge subjected to jet

To further explore the damage characteristics and impact response of the shaped charge to the solid rocket engine (SRE) in storage or transportation, protective armor was designed and the shelled charges model (SCM)/SRE with protective armor impacting by shaped charge tests were conducted. Air overpressures at 5 locations and axial acceleration caused by the explosion were measured, and the experimental results were compared with two air overpressure curves of propellant detonation obtained by related scholars. Afterwards, the finite element software AUTODYN was used to simulate the SCM impacted process and SRE detonation results. The penetration process and the formation cause of damage were analyzed. The detonation performance of TNT, reference propellant, and the propellant used in this experiment was compared. The axial acceleration caused by the explosion was also analyzed. By comprehensive comparison, the energy released by the detonation of this propellant is larger, and the HMX or Al particles contained in this propellant are more than the reference propellant, with a TNT equivalent of 1.168–1.196. Finally, advanced protection armor suggestions were proposed based on the theory of woven fabric rubber composite armor (WFRCA).     

Preparation of ammonium nitrate-based solid composite propellants supplemented with polyurethane/nitrocellulose blends binder and their thermal decomposition behavior

To improve the performance of solid composite propellants (SCPs) supplemented with ammonium nitrate (AN) as an oxidizer, the incorporation of energetic ingredients such as explosives, energetic binders or catalysts is a common effective approach. For this purpose, polyurethane (PU), a typical inert binder, was mixed with nitrocellulose (NC) as an energetic polymer. Numerous composite solid propellant compositions based on AN and NC-modified polyurethane binder with different NC ratios were prepared. The prepared formulations were characterized using Fourier transform infrared spectroscopy (FTIR), RAMAN spectroscopy, X-ray diffraction (XRD), electron densimetry, thermogravimetric (TG) analysis, and differential scanning calorimetry (DSC). A kinetic study was then performed using the iterative Kissinger-Akahira-Sunose (It-KAS), Flynn-Wall-Ozawa (It-FWO), and non-linear Vyazovkin integral with compensation effect (VYA/CE) methods. The theoretical performances, such as theoretical specific impulse, adiabatic flame temperature, and ideal exhaust gaseous species, were also determined using the NASA Lewis Code, Chemical Equilibrium with Application (CEA). Spectroscopic examinations revealed the existence of NC and full polymerization of PU in the prepared propellants. According to density tests, the density of the propellant increases as the nitrocellulose component increases. According to the thermal analysis and kinetics study, the increase in NC content catalyzed the thermal decomposition of the AN-based composite solid propellants. Based on the theoretical study, increasing the amount of NC in the propellant increased the specific impulse and, as a result, the overall performance.     

Simulation of the plasticizing behavior of composite modified double-base (CMDB) propellant in grooved calendar based on adaptive grid technology

The frequent occurrence of safety accidents during the calendering process is caused by the flammable and explosive properties of composite modified double-base (CMDB) propellant. Optimization of process parameters with the aid of fluid simulation technology could effectively ensure the safety of the calendering process. To improve the accuracy of the simulation results, material parameters and model structure were corrected based on actual conditions, and adaptive grid technology was applied in the local mesh refinement. In addition, the rheological behavior, motion trajectories and heat transfer mechanisms of CMDB propellant slurry were studied with different gaps, rotational rates and temperatures of two rollers. The results indicated that the refined mesh could significantly improve the contour clarity of boundaries and simulate the characteristics of CMDB propellant slurry reflux movement caused by the convergent flow near the outlet. Compared with the gap, the increased rotational rate of roller could promote the reflux movement and intensify the shear flow of slurry inside the flow region by viscous shear dragging. Meanwhile, under the synergistic effect of contact heat transfer as well as convective heat exchange, heat accumulated near the outlet and diffused along the reflux movement, which led to the countercurrent heat dissipation behavior of CMDB propellant slurry. The plasticizing mechanism of slurry and the safety of calendering under different conditions were explored, which provided theoretical guidance and reference data for the optimization of calendering process conditions. Based on the simulation results, the safety of the CMDB propellant calendering process could be significantly improved with a few tests conducted during a short research and development cycle.     

基于低周疲劳理论的身管横向裂纹萌生研究

基于非线性有限元理论建立弹带挤进的动力学模型,依据低周疲劳理论对身管内壁横向裂纹的萌生时机进行研究.在仅考虑热载荷的作用下,研究热疲劳因素对身管裂纹萌生的影响;再利用热力耦合分析方法,研究将弹带的挤压和摩擦作用考虑进来后身管横向裂纹的萌生时机.结果表明,通过热力耦合模型得到的疲劳射弹发数与实弹射击实验发现的横向裂纹的萌生时机相吻合,验证了在考虑热力耦合作用下所建模型的正确性.     

磁控溅射工艺对CrN基复合涂层微观结构及摩擦学性能的影响

采用闭合场非平衡磁控溅射技术在不锈钢基体上制备了不同质量分数Mo的CrMoN复合涂层。采用X射线衍射仪（XRD）、扫描电子显微镜（SEM）、能谱仪（EDX）和光电子能谱仪（XPS）,系统分析了CrMoN复合涂层的相结构、表面形貌、成分、原子化合价价态等,结果表明：添加Mo后,CrMoN涂层的择优取向由CrN涂层的（220）转变为（200）,CrMoN涂层中的Mo原子取代了CrN晶格中的Cr原子,形成（Cr,Mo）N置换固溶体。采用Nano Test 600硬度测试仪测定了CrMoN复合涂层的纳米硬度,结果表明：由于CrN相和MoN两种硬相的协同作用,使得CrMoN复合涂层的纳米硬度值增大。采用多功能摩擦磨损试验机测定了CrN涂层及CrMoN复合涂层的摩擦因数,结果表明：CrMoN复合涂层的摩擦因数低于CrN涂层,磨损过程中由于摩擦热反应生成大量MoO3,使得复合膜的摩擦因数降低,起到了一定的润滑效果,降低了磨损量。     

THE CREEP-DAMAGE MODELING CORRELATED TO TEMPERATURE FOR COMPOSITE SOLID PROPELLANT

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液体火箭发动机碳/碳复合材料喷管烧蚀分析

对液体火箭发动机碳／碳复合材料喷管的烧蚀过程进行研究。理论模型包括固相和气相守恒方程。气相湍流反应边界层流动应用质量加权平均控制方程分析，喷管壁温分布由非稳态传热方程进行数值计算获得。分析了推进剂混合比、液膜冷却量、燃烧室压力、壁面材料的密度对烧蚀速率的影响。