Thermal and combustion behavior of Al-MnO2 nanothermite with poly(vinylidene fluoride -co- hexafluoropropylene) energetic binder

Fluoropolymers get increasing attention in energetic materials application due to the high fluorine content. To explore the effect of poly(vinylidene fluoride-co-hexafluoropropylene) (P(VDF-HFP)) on Al/MnO2 nanothermite, the samples with different contents are prepared and characterized by SEM, TG-DSC, XRD, and their ignition and combustion behavior are tested and recorded. The results show that P(VDF-HFP) as an energetic binder can combine the nanothermite components together, even exist in the gaps. The integrity of energetic materials has been improved. Thermal analysis shows that the addition of P(VDF-HFP) greatly changes the thermal reaction processes, and the exothermic peaks appear early, but the utilization of fuel and oxidizer is not efficient from the XRD results. Furthermore, the appropriate addition of P(VDF-HFP) can directly reduce the ignition energy threshold and increase the combustion time, which is necessary for the potential ignition charge application. The possible reasons for above phenomena are discussed and analyzed. This research provides a reference for improvement of thermite-based ignition charge formulation.     

中小型客车用钢──水热管式采暖装置工作温度控制研究

讨论了影响热管工作温度ｔｖ的主要因素,提出了控制钢──水热管工作温度（采暖装置的工作温度）的管长参数的确定原则,介绍了用于客车上的实例。     

高压大容量脉冲电容器保压过程中电压跌落的定量分析

针对金属化膜脉冲电容器在实际使用中由于充电结束以后较长的保压时间而产生电压跌落和能量损失，并最终导致脉冲功率电源系统的实际有效储能和储能密度下降这一实际问题，基于一种高压大容量脉冲电容器电压跌落的实验数据，分别从电导特性、自愈特性、极化特性及其与能量损失的相关性出发，推导了介质薄膜电导率与电压跌落的定量关系并进行了电导率测量实验，推导了自愈能量与电压跌落的定量关系并进行了寿命实验，阐述了松弛极化与电压跌落的定量关系并进行了仿真。结果表明，介质泄漏、自愈以及松弛极化在电压跌落中所占比例分别为29.64%、11.75%及58.35%，导致所研究电容器电压跌落的主要因素是松弛极化。     

界面热阻对金刚石/银复合材料导热率的影响

研究了金刚石／银复合材料的导热率与金刚石的含量、粒度等之间的关系,着重讨论了界面热阻对复合材料导热率的影响。并阐述了金刚石表面镀钛,能有效改善金刚石对银的润湿性,降低界面热阻,从而提高金刚石／银复合材料的导热率。     

Recent progress on transition metal oxides and carbon-supported transition metal oxides as catalysts for thermal decomposition of ammonium perchlorate

As a main oxidizer in solid composite propellants, ammonium perchlorate (AP) plays an important role because its thermal decomposition behavior has a direct influence on the characteristic of solid com-posite propellants. To improve the performance of solid composite propellant, it is necessary to take measures to modify the thermal decomposition behavior of AP. In recent years, transition metal oxides and carbon-supported transition metal oxides have drawn considerable attention due to their extraor-dinary catalytic activity. In this review, we highlight strategies to enhance the thermal decomposition of AP by tuning morphology, varying the types of metal ion, and coupling with carbon analogue. The enhanced catalytic performance can be ascribed to synergistic effect, increased surface area, more exposed active sites, and accelerated electron transportation and so on. The mechanism of AP decom-position mixed with catalyst has also been briefly summarized. Finally, a conclusive outlook and possible research directions are suggested to address challenges such as lacking practical application in actual formulation of solid composite propellant and batch manufacturing.     

Insensitive energetic microspheres DAAF/RDX fabricated by facile molecular self-assembly

Insensitive energetic materials are promising in the defense weapons field. However, energetic materials still suffer from great challenges and the concern about their safety limits their utilization. In this work, insensitive energetic explosive 3,3′-diamino-4,4′-azoxyfurazan/hexahydro-1,3,5-trinitro-1,3,5-triazine (DAAF/RDX) microspheres were fabricated by self-assembly method. Rod-like DAAF/RDX was prepared by mechanical ball milling for comparison. DAAF/RDX composites with different mass ratios (90:10, 80:20, and 70:30) were obtained. The morphologies and structures of as-obtained DAAF/RDX composites were characterized by scanning electron microscopy (SEM), powder x-ray diffraction (PXRD) and fourier transform infrared spectroscopy (FT-IR). The results showed that DAAF/RDX microspheres exhibited regular shaped microspheres with sizes from 0.5 to 1.2 μm. There was no crystal transition during the modification process. The thermal properties of as-obtained materials were then evaluated by differential scanning calorimetry (DSC) and materials studio software. DAAF/RDX microspheres showed an advanced decomposition peak temperature compared with rod-like DAAF/RDX. The binding energy and peak temperature values at zero β_i (T_P0) of DAAF/RDX (90:10) increased by 36.77 kJ/mol, 1.6 °C, and 58.11 kJ/mol, 12.3 °C compared to DAAF/RDX (80:20) and DAAF/RDX (70:30), indicating the better thermal stability of DAAF/RDX (90:10). The characteristic drop height (H₅₀) of DAAF/RDX (higher than 100 cm) composites was higher than that of raw RDX (25 cm), suggesting significant improvements in mechanical safety. The preparation of DAAF/RDX microspheres is promising for the desensitization of RDX and useful for the formation of other materials and future wide applications.     

Preparation and characterization of HMX/EVA/hBNNSs micro-composites with improved thermal stability and reduced sensitivity

Hexagonal boron nitride nanosheets(HBNNSs)have huge potential in the field of coating materials owing to their remarkable chemical stability,mechanical strength and thermal conductivity.Thin-layer hBNNSs were obtained by a liquid-phase exfoliation of h-BN powders and incorporated into EVA coatings for improving the safety performance of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX).HBNNSs and ethylene-vinyl acetate copolymer(EVA)were introduced to HMX by a solvent-slurry process.For com-parison,the HMX/EVA and HMX/EVA/graphene(HMX/EVA/G)composites were also prepared by a similar process.The morphology,crystal form,surface element distribution,thermal decomposition property and impact sensitivity of HMX/EVA/hBNNSs composites were contrastively investigated.Results showed that as prepared HMX/EVA/hBNNSs composites were well coated with hBNNSs and EVA,and exhibited better thermal stability and lower impact sensitivity than that of HMX/EVA and HMX/EVA/G composites,suggesting superior performance of desensitization of hBNNSs in explosives.     

集成电导检测流动注射微流控芯片的研究

探讨了集成电导检测流动注射微流控芯片的设计与制作,研究出了能在普通实验室制作集成电导检测流动注射微流控芯片的方法,自制了集成电导检测微流控芯片,利用氯化钾标液验证了制作电导检测流动注射微流控芯片方法的可靠性,并用该系统测定了阿斯匹林片中乙酰水杨酸含量,证明该微分析系统应用于样品分析的有效性和适用性。     

油脂的导电特性与新型水分快速检测方法

研究了油脂在无线电频率范围内的导电特性,发现了油脂的导电浴盆效应,提出了一种新的油脂水分快速检测方法,研制了相应的仪器。仪器已在我国粮油行业推广使用,解决了长期以来油脂现场水分快速、准确测量的难题。