铜包钢复合导线的高电导特性

复合导线具有一种很有价值的高电导特性:在一定的频率区域,铜包钢复合导线的导电性能明显地高于铜导线.文章给出了这种高电导特性与传输频率及导线结构的关系.     

舰船利用柴油机冷却水余热作吸收式制冷空调装置热源的研究

对某型舰利用６—１５０Ｃ柴油发电机冷却水余热作为低品位热源进行溴化锂吸收式制冷进行了热力计算和节能分析。计算及分析结果表明：利用６—１５０Ｃ柴油发电机组冷却水余热作为某型舰吸收式空调机组的热源是可行的,它不仅满足该型舰制冷量的要求,还具有明显的节能效果。     

Recent progress on transition metal oxides and carbon-supported transition metal oxides as catalysts for thermal decomposition of ammonium perchlorate

As a main oxidizer in solid composite propellants, ammonium perchlorate (AP) plays an important role because its thermal decomposition behavior has a direct influence on the characteristic of solid com-posite propellants. To improve the performance of solid composite propellant, it is necessary to take measures to modify the thermal decomposition behavior of AP. In recent years, transition metal oxides and carbon-supported transition metal oxides have drawn considerable attention due to their extraor-dinary catalytic activity. In this review, we highlight strategies to enhance the thermal decomposition of AP by tuning morphology, varying the types of metal ion, and coupling with carbon analogue. The enhanced catalytic performance can be ascribed to synergistic effect, increased surface area, more exposed active sites, and accelerated electron transportation and so on. The mechanism of AP decom-position mixed with catalyst has also been briefly summarized. Finally, a conclusive outlook and possible research directions are suggested to address challenges such as lacking practical application in actual formulation of solid composite propellant and batch manufacturing.     

Preparation and characterization of HMX/EVA/hBNNSs micro-composites with improved thermal stability and reduced sensitivity

Hexagonal boron nitride nanosheets(HBNNSs)have huge potential in the field of coating materials owing to their remarkable chemical stability,mechanical strength and thermal conductivity.Thin-layer hBNNSs were obtained by a liquid-phase exfoliation of h-BN powders and incorporated into EVA coatings for improving the safety performance of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX).HBNNSs and ethylene-vinyl acetate copolymer(EVA)were introduced to HMX by a solvent-slurry process.For com-parison,the HMX/EVA and HMX/EVA/graphene(HMX/EVA/G)composites were also prepared by a similar process.The morphology,crystal form,surface element distribution,thermal decomposition property and impact sensitivity of HMX/EVA/hBNNSs composites were contrastively investigated.Results showed that as prepared HMX/EVA/hBNNSs composites were well coated with hBNNSs and EVA,and exhibited better thermal stability and lower impact sensitivity than that of HMX/EVA and HMX/EVA/G composites,suggesting superior performance of desensitization of hBNNSs in explosives.     

Insensitive energetic microspheres DAAF/RDX fabricated by facile molecular self-assembly

Insensitive energetic materials are promising in the defense weapons field. However, energetic materials still suffer from great challenges and the concern about their safety limits their utilization. In this work, insensitive energetic explosive 3,3′-diamino-4,4′-azoxyfurazan/hexahydro-1,3,5-trinitro-1,3,5-triazine (DAAF/RDX) microspheres were fabricated by self-assembly method. Rod-like DAAF/RDX was prepared by mechanical ball milling for comparison. DAAF/RDX composites with different mass ratios (90:10, 80:20, and 70:30) were obtained. The morphologies and structures of as-obtained DAAF/RDX composites were characterized by scanning electron microscopy (SEM), powder x-ray diffraction (PXRD) and fourier transform infrared spectroscopy (FT-IR). The results showed that DAAF/RDX microspheres exhibited regular shaped microspheres with sizes from 0.5 to 1.2 μm. There was no crystal transition during the modification process. The thermal properties of as-obtained materials were then evaluated by differential scanning calorimetry (DSC) and materials studio software. DAAF/RDX microspheres showed an advanced decomposition peak temperature compared with rod-like DAAF/RDX. The binding energy and peak temperature values at zero β_i (T_P0) of DAAF/RDX (90:10) increased by 36.77 kJ/mol, 1.6 °C, and 58.11 kJ/mol, 12.3 °C compared to DAAF/RDX (80:20) and DAAF/RDX (70:30), indicating the better thermal stability of DAAF/RDX (90:10). The characteristic drop height (H₅₀) of DAAF/RDX (higher than 100 cm) composites was higher than that of raw RDX (25 cm), suggesting significant improvements in mechanical safety. The preparation of DAAF/RDX microspheres is promising for the desensitization of RDX and useful for the formation of other materials and future wide applications.     

界面改性对SiCp/Cu复合材料导热性能的影响

采用磁控溅射法结合结晶化热处理工艺在SiC颗粒表面成功制备了金属Mo涂层,分析Mo涂层的成分和形貌;采用热压烧结工艺制备SiCp/Cu复合材料,重点对比分析Mo界面阻挡层厚度对复合材料导热性能的影响。结果表明:磁控溅射法能够在SiC颗粒表面沉积得到Mo涂层,随溅射时间的延长,Mo涂层的厚度增加、粗糙度增大,且磁控溅射后SiC颗粒表面直接得到的Mo涂层为非晶态,结晶化热处理后,变为致密平整的晶态Mo涂层。磁控溅射时间对Mo涂层厚度和复合材料导热性能影响明显。随磁控溅射时间的增加,复合材料的热导率呈先增后减趋势。采用磁控溅射9h镀Mo改性并经过800℃结晶化热处理的SiC复合粉体在850℃下热压烧结制备的SiCp/Cu复合材料(VSiC=50%),其热导率达到了最高值274.056W/(m·K)。     

高超声速飞行器的热电技术热管理系统参数

提出了集成热电发电装置的超燃冲压发动机热管理系统,将热电发电器与发动机壁面结构相结合。集成的热电发电热管理系统可以将传入发动机壁面的热量部分转换为电能,同时减少了冷却用燃料流量,"间接"提高了燃料的吸热能力。燃料在冷却过程中提高了自身温度和焓值,具有一定的做功能力。高温高压的燃料经过涡轮机膨胀做功,输出可以被高超声速飞行器利用的能量。采用热力学的分析方法对集成热电发电热管理系统的相关参数进行研究,结果表明其比传统的再生冷却防热具有极好的潜在优势,提升了燃料的吸热能力,同时对外输出了可用功。     

石墨烯微片尺寸对石墨烯纸热导率的影响

石墨烯热导率远高于传统金属薄膜等导热材料,可用作热扩散材料。石墨烯纸由石墨烯微片组装而成,石墨烯微片尺寸大小对其组装方式微观结构以及宏观导热性能等具有重要影响。采用溶液过滤自组装方法制备了分散均匀的氧化石墨烯纸,然后在Ar/H2气氛下对氧化石墨烯纸进行热还原处理,得到了石墨烯纸。结果表明,大尺寸石墨烯微片组成的石墨烯纸结构更加致密、结晶度更高;0.5μm~3μm和50μm~100μm的氧化石墨烯所制备的石墨烯纸的热导率分别为632.8 W/m K和683.7 W/m K,大尺寸石墨烯微片组成的石墨烯纸热导率提高了8%。     

双电层吸附离子的动力学研究

以电化学理论和双电层理论为依据建立模型,分析了离子在稀溶液中的动力学规律,并自制实验装置检验了双电层对NaCl稀溶液吸附离子的能力.电极吸附实验的结果表明,对特定的电吸附装置,存在溶液温度、流量和电极电势的最佳参数组合.     

稳态法测量热系数的计算方法改进研究

不良导体热系数测量普遍采用的是稳态法，但表面散热率的间接测量和样品侧面散热与漏热给测量带来一定误差，使得热系数实际测量值略微偏大。介绍了新的实验装置和实验数值计算方法，并且分析研究了样品边缘（侧面）热损失的物理模型，提出了新的数学模型和数据处理方法，纠正了这些偏差，与实验吻合较好。