Mechanical properties and thermal conductivity of pristine andfunctionalized carbon nanotube reinforced metallic glass composites:A molecular dynamics approach

This work uses the molecular dynamics approach to study the effects of functionalization of carbon nanotubes (CNTs) on the mechanical properties of Cu64Zr36 metallic glass (MG). Three types of functional groups, carboxylic, vinyl and ester were used. The effect of CNT volume fraction (Vf) and the number of functional groups attached to CNT, on the mechanical properties and thermal conductivity of CNT-MG composites was analysed using Biovia Materials Studio. At lower values of Vf (from 0 to 5％), the per-centage increase in Young's modulus was approximately 66％. As the value of Vf was increased further (from 5 to 12％), the rate of increase in Young's modulus was reduced to 16％. The thermal conductivity was found to increase from 1.52 W/mK at Vf=0％to 5.88 W/mK at Vf=12％, thus giving an increase of approximately 286％. Functionalization of SWCNT reduced the thermal conductivity of the SWCNT-MG composites.     

Effect of organo-modified montmorillonite nanoclay on mechanical,thermal and ablation behavior of carbon fiber/phenolic resin composites

The mechanical, thermal and ablation properties of carbon phenolic (C-Ph) composites (Type-I) rein-forced with different weight percentages of organo-modified montmorillonite (o-MMT) nanoclay have been studied experimentally. Ball milling was used to disperse different weight (wt) percentages (0, 1,2,4,6 wt.％) of nanoclay into phenolic resin. Viscosity changes to resin due to nanoclay was studied. On the other hand, nanoclay added phenolic matrix composites (Type-II) were prepared to study the dispersion of nanoclay in phenolic matrix by small angle X-ray scattering and thermal stability changes to the matrix by thermogravimetric analyser (TGA). This data was used to understand the mechanical, thermal and ablation properties of Type-I composites. Inter laminar shear strength (ILSS), flexural strength and flexural modulus of Type I composites increased by about 29％, 12％and 7％respectively at 2 wt.％ addition of nanoclay beyond which these properties decreased. This was attributed to reduced fiber volume fraction (％Vf) of Type-I composites due to nanoclay addition at such high loadings. Mass ablation rate of Type-I composites was evaluated using oxy acetylene torch test at low heat flux (125 W/cm2) and high heat flux levels (500 W/cm2). Mass ablation rates have increased at both flux levels marginally up to 2 wt.％ addition of nanoclay beyond which it has increased significantly. This is in contrast to increased thermal stability observed for Type-I and Type-Ⅱ composites up to 2 wt.％addition of nanoclay. Increased ablation rates due to nanoclay addition was attributed to higher insulation effi-ciency of nanolcay, which accumulates more heat energy in limited area behind the ablation front and self-propagating ablation mechanisms triggered by thermal decomposition of organic part of nanoclay.     

Improvement of VIS and IR camouflage properties by impregnating cotton fabric with PVB/IF-WS2

In order to examine the possibility to improve its camouflage properties standard cotton fabric with camouflage print was impregnated with poly(vinyl butyral), PVB and fullerene-like nanoparticles of tungsten disulfide, PVB/IF-WS₂. FTIR analysis excluded any possible chemical interaction of IF-WS₂ with PVB and the fabric. The camouflage behavior of the impregnated fabric has been examined firstly in the VIS part of the spectrum. Diffuse reflection, specular gloss and color coordinates were measured for three different shades (black, brown and dark green). Thermal imaging was applied to examine the camouflage abilities of this impregnation in IR part of the spectrum. The obtained results show that PVB/IF-WS₂ impregnation system induced enhacement of the materials camouflage properties, i.e. that IF-WS₂ have a positive effect on spectrophotometric characteristics of the fabric.     

An interface shear damage model of chromium coating/steel substrate under thermal erosion load

The Cr-plated coating inside a gun barrel can effectively improve the barrel's erosion resistance and thus increase the service life.However,due to the cyclic thermal load caused by high-temperature gun-powder,micro-element damage tends to occur within the Cr coating/steel substrate interface,leading to a gradual deterioration in macro-mechanical properties for the material in the related region.In order to mimic this cyclic thermal load and,thereby,study the thermal erosion behavior of the Cr coating on the barrel's inner wall,a laser emitter is utilized in the current study.With the help of in-situ tensile test and finite element simulation results,a shear stress distribution law of the Cr coating/steel substrate and a change law of the interface ultimate shear strength are identified.Studies have shown that the Cr coating/steel substrate interface's ultimate shear strength has a significant weakening effect due to increasing temperature.In this study,the interfacial ultimate shear strength decreases from 2.57 GPa(no erosion)to 1.02 GPa(laser power is 160 W).The data from this experiment is employed to establish a Cr coating/steel substrate interface shear damage model.And this model is used to predict the flaking process of Cr coating by finite element method.The simulation results show that the increase of coating crack spacing and coating thickness will increase the service life of gun barrel.     

热真空条件下工作的电气电缆载流量计算与试验

高空制导飞行器从母舱释放后,制导舱与仪器舱之间部分电气电缆处于热真空条件下工作。对此种特定条件下的电缆进行了载流量计算。理论计算表明,给定的电缆设计满足在热真空条件下正常工作要求。最后简略介绍了载流量试验。     

THE DEFENCE SPENDING–EXTERNAL DEBT NEXUS IN ETHIOPIA

The aim of this paper is to examine the impact of defence spending and income on the evolution of Ethiopia’s external debt over the period 1970–2005. Using the bounds test approach to cointegration and Granger causality tests, we find a long run and a causal relationship between external debt, defence spending and income. Defence spending had a positive and a significant impact on the stock of external debt while income had a negative and a statistically significant impact on external debt. Our findings suggest that an increase in defence spending contributes to the accumulation of Ethiopia’s external debt, while an increase in economic growth helps Ethiopia to reduce its external debt.     

基于时滞分割法的具有leakage项时滞的离散型神经网络状态估计

摘要：研究一类具有leakage时滞的离散型神经网络的状态估计问题．通过构造新的Lyapunov泛函得到保证估计误差全局渐近稳定的充分条件,并通过求解一个线性矩阵不等式（LMI）得到状态估计器的增益矩阵．采用一种新的时滞分割方法将变时滞区间分割为多个子区间,使该结果在获得更小的保守性同时也降低了计算的复杂度．     

基于奇异值分解的潜艇磁场推算

针对潜艇磁性防护,基于磁偶极子阵列模型,建立了潜艇磁性目标高精度磁场计算模型。提出了利用奇异值分解的方法对模型进行求解,利用该求解算法进行了模型计算与实测数据比对,结果表明,该计算方法能够有效适用于计算高精度潜艇磁场。基于奇异分解的方法计算了潜艇高空磁场,计算结果可供潜艇防护磁性探测参考。     

多站时差定位中的病态性分析及其改善方法

在多站时差定位过程中,传统定位算法在传感器布站不合理的情况下通常会表现出明显的病态性,其导致定位结果不稳定、精度低。针对此问题,首先分析了时差定位过程中病态性产生的物理场景,并通过奇异值分解揭示了病态性的本质;其次根据时差定位观测矩阵的特征值分布特点,提出了一种改进的多站时差定位改善方法,该方法基于LS估计信息矩阵的条件指标进行奇异值修正,兼顾了目标定位的分辨率与方差,能显著提高多站时差目标定位的精度和稳定性,且没有增加系统和算法复杂度;最后将该算法与传统算法进行了仿真比较,结果证明了该算法优越性。     

Sandwich structure for enhancing the interface reaction of hexanitrohexaazaisowurtzitane and nanoporous carbon scaffolds film to improve the thermal decomposition performance

Improving the thermal decomposition performance of hexanitrohexaazaisowurtzitane (CL-20) by appropriate methods is helpful to promote the combustion performance of CL-20-based solid propellants. In this study, we synthesized a sandwich structure of CL-20 and nanoporous carbon scaffolds film (NCS) and emphatically studied the thermal decomposition performance of the composite structure. Thermogravimetric analysis and differential scanning calorimetry were used to measure the thermal decomposition process of the composite structure. The kinetic parameters of thermal decomposition were calculated by the thermal dynamic analysis software AKTS. These results showed that the thermal decomposition performance of the sandwich structure of CL-20 and NCS was better than CL-20. Among the tested samples, NCS with a pore size of 15 nm had the best catalytic activity for the thermal decomposition of CL-20. Moreover, the thermal decomposition curve of the composite structure at the heating rate of 1 K/min was deconvoluted by mathematical method to study the thermal decomposition process. And a possible catalytic mechanism was proposed. The excellent thermal decomposition performance is due to the sandwich structure enhances the interface reaction of CL-20 and NCS. This work may promote the extensive use of CL-20 in the field of solid rocket propellant.