A novel formulation of material nonlinear analysis in structural mechanics

This article demonstrates a novel approach for material nonlinear analysis. This analysis procedure eliminates tedious and lengthy step by step incremental and then iterative procedure adopted classically and gives direct results in the linear as well as in nonlinear range of the material behavior. Use of elastic moduli is eliminated. Instead, stress and strain functions are used as the material input in the analysis procedure. These stress and strain functions are directly derived from the stress-strain behavior of the material by the method of curve fitting. This way, the whole stress-strain diagram is utilized in the analysis which naturally exposes the response of structure when loading is in nonlinear range of the material behavior. It is found that it is an excellent computational procedure adopted so far for material nonlinear analysis which gives very accurate results, easy to adopt and simple in calculations. The method eliminates all types of linearity assumptions in basic derivations of equations and hence, eliminates all types of possibility of errors in the analysis procedure as well. As it is required to know stress distribution in the structural body by proper modelling and structural idealization, the proposed analysis approach can be regarded as stress-based analysis procedure. Basic problems such as uniaxial problem, beam bending, and torsion problems are solved. It is found that approach is very suitable for solving the problems of fracture mechanics. Energy release rate for plate with center crack and double cantilever beam specimen is also evaluated. The approach solves the fracture problem with relative ease in strength of material style calculations. For all problems, results are compared with the classical displacement-based liner theory.     

Recent advances in catalytic combustion of AP-based composite solid propellants

Composite solid propellants (CSPs) have widely been used as main energy source for propelling the rockets in both space and military applications. Internal ballistic parameters of rockets like characteristic exhaust velocity, specific impulse, thrust, burning rate etc., are measured to assess and control the performance of rocket motors. The burn rate of solid propellants has been considered as most vital parameter for design of solid rocket motors to meet specific mission requirements. The burning rate of solid propellants can be tailored by using different constituents, extent of oxidizer loading and its particle size and more commonly by incorporating suitable combustion catalysts. Various metal oxides (MOs), complexes, metal powders and metal alloys have shown positive catalytic behaviour during the com-bustion of CSPs. These are usually solid-state catalysts that play multiple roles in combustion of CSPs such as reduction in activation energy, enhancement of rate of reaction, modification of sequences in reaction-phase, influence on condensed-phase combustion and participation in combustion process in gas-phase reactions. The application of nanoscale catalysts in CSPs has increased considerably in recent past due to their superior catalytic properties as compared to their bulk-sized counterparts. A large surface-to-volume ratio and quantum size effect of nanocatalysts are considered to be plausible reasons for improving the combustion characteristics of propellants. Several efforts have been made to produce nanoscale combustion catalysts for advanced propellant formulations to improve their energetics. The work done so far is largely scattered. In this review, an effort has been made to introduce various combustion catalysts having at least a metallic entity. Recent developments of nanoscale combustion catalysts with their specific merits are discussed. The combustion chemistry of a typical CSP is briefly discussed for providing a better understanding on role of combustion catalysts in burning rate enhancement. Available information on different types of combustion nanocatalysts is also presented with critical comments.