| 苯乙炔与二苯丁二炔的共聚及共聚物的表征 |
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| 引用本文： | 李银奎,罗淑芳.苯乙炔与二苯丁二炔的共聚及共聚物的表征[J].国防科技大学学报,1991,13(1):51-56. |
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| 作者姓名： | 李银奎 罗淑芳 |
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| 作者单位： | 国防科技大学材料科学与应用化学系
(李银奎)，国防科技大学材料科学与应用化学系(罗淑芳) |
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| 摘 要： | 本文以(Ph_3P)_2PdCl_2作催化剂,合成出聚二苯丁二炔和二苯丁二炔与苯乙炔共聚物。均聚物及共聚物产率都在90%以上,均聚物分子量为900,二苯丁二炔与苯乙炔最佳摩尔比为1/2(数均分子量为1205)。结构分析表明,均聚物及共聚物均具有反—反式结构。
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| 关 键 词： | 共聚物 苯乙炔 二苯丁二炔 |
| 收稿时间： | 1988/11/8 0:00:00 |
Synthesis and Characterization of Copolymer of Phenylacetylene and Diphenylbutadiyne |
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| Li Yinkui and Luo Shufang.Synthesis and Characterization of Copolymer of Phenylacetylene and Diphenylbutadiyne[J].Journal of National University of Defense Technology,1991,13(1):51-56. |
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| Authors: | Li Yinkui and Luo Shufang |
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| Institution: | Department of Materials Science and Applied Chemistry |
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| Abstract: | In this paper,polydiphenylbutadiyne(1)and phenylacetylene-(?)iphenyl-butadiyne copolymer(2)are synthesised using(Ph_3P)_2PdCl_2 as catalyst.In the copolymerization,the best mole ratio of two monomers diphe-nylbutadiyne and phenylacetylene is 1/2.The catalytic homopolymerizationof diphenylbutadiyne is superior to that of the thermal homopolymeriza-tion.According to infrared and 1~H-NMR spectra,the structure of polymer(1) and copolymer (2) may all be trans-transoidal confignration. |
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| Keywords: | copolymer phenylacetylene diphenylbutadiyne |
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