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二元共晶系相变材料热力学模型的研究
引用本文:李志广,黄红军,张敏,万红敬.二元共晶系相变材料热力学模型的研究[J].军械工程学院学报,2009,21(3):71-74.
作者姓名:李志广  黄红军  张敏  万红敬
作者单位:军械工程学院基础部;
摘    要:推导了二元共晶系的热力学模型,改进了单参数的Margules方程,引入了温度项,利用实验值对方程中的参数进行了回归,结果表明该热力学模型是可行的,从而可以应用该模型计算二元共晶系相变材料的最低共熔点和组成。

关 键 词:十二醇  脂肪酸  相变材料  热力学模型

A Study of Thermodynamics Model for Binary Eutectic System Phase Change Material
LI Zhi-guang,HUANG Hong-jun,ZHANG Min,WAN Hong-jing.A Study of Thermodynamics Model for Binary Eutectic System Phase Change Material[J].Journal of Ordnance Engineering College,2009,21(3):71-74.
Authors:LI Zhi-guang  HUANG Hong-jun  ZHANG Min  WAN Hong-jing
Institution:Department of Basic Courses;Ordnance Engineering College;Shijiazhuang 050003;China
Abstract:The thermodynamics model of binary eutectic liquid phase line is presented.The single parameter Margules equation is improved and the temperature added to the parameter.The equation parameters are regressed by the experiment values of five group binary system dodecanol-stearic acid,palmitic acid,myristic acid,lauric acid,capric acid and this system phase diagram is predicted.The predicted results indicate that this thermodynamics model can be used to predict the eutectic PCM binary system phase diagram and ...
Keywords:dodecanol  fatty acid  phase change material (PCM)  thermodynamics model
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