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热重法研究聚芳基乙炔的热分解性能
引用本文:童乙青,李银奎,陈朝辉.热重法研究聚芳基乙炔的热分解性能[J].国防科技大学学报,1990,12(1):110-115.
作者姓名:童乙青  李银奎  陈朝辉
作者单位:国防科技大学材料科学与应用化学系 (童乙青,李银奎),国防科技大学材料科学与应用化学系(陈朝辉)
摘    要:本文用热重法测定了芳基乙炔均聚物及其与苯乙炔的共聚物的热分解温度和成碳率,所得结论有:共聚物中含二乙炔芳烃量越多,交联度越大,则其热分解温度越高,成碳率也越大;二乙炔芳烃和苯乙炔共聚物的成碳率远高于按其均聚物计算所得的成碳率。

关 键 词:聚芳烃  热重分析  成碳率
收稿时间:1988/11/12 0:00:00

Study on Thermal Degradation Properties of the Polyarylacetylenes by Thermogravimetry
Tong Yiqing,Li Yinkui and Chen Zhaohui.Study on Thermal Degradation Properties of the Polyarylacetylenes by Thermogravimetry[J].Journal of National University of Defense Technology,1990,12(1):110-115.
Authors:Tong Yiqing  Li Yinkui and Chen Zhaohui
Institution:Department of Materials Science and Applied Chemistry
Abstract:The thermal degradation temperatures and the rate of char yields ofhomopolymers and coplymers of arylacetylenes were determined by thermogr-avimetry.The correlations between these properties and the composition andstructure of polyarylacetylenes were also revealed.The more diethynylaromaticcopolymer contains and the bigger cross link density,the higher the thermaldegradation temperature and char yields.Char yields of copolymer ofdiethynylaromatic and phenylacetylene are much greater than that of thecalculated data from their homopolymers.
Keywords:polyaromatic hydrocarbon  thermogravimetry  char yield
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