| 聚对苯撑及其衍生物的合成、表征和电性能 |
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| 引用本文： | 李银奎,刘清芝,黄钐,孙巍,龙永福,刘玉明,孙乐民.聚对苯撑及其衍生物的合成、表征和电性能[J].国防科技大学学报,1996,18(3):49-53. |
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| 作者姓名： | 李银奎 刘清芝 黄钐 孙巍 龙永福 刘玉明 孙乐民 |
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| 作者单位： | 国防科技大学材料工程与应用化学系，国防科技大学图书馆 |
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| 摘 要： | 从溴苯合成出了聚对苯撑，从对苯二酚合成出了几种聚对苯撑的衍生物：聚（２，５－Ｍ甲氧基）对苯撑，聚（２，５－二乙氧基）对苯撑和聚（２，５－二丁氧基）对苯撑。用ＩＲ表征了中间体和聚合物的结构，测定了聚合物的电导率和伏安特性曲线，并讨论了实验条件对产率的影响。
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| 关 键 词： | 聚对苯撑，聚（2，5－二甲氧基）对苯撑，聚（2，5－二乙氧基）对苯撑，聚（2，5－二丁氧基）对苯撑 |
| 收稿时间： | 2/5/1996 12:00:00 AM |
The Study of Synthesis, Characteristics and Conductivity of Poly-p-phenylene and its Derivatives |
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| Li Yinkui,Liu Qingzhi,Huang Shan,Sun Wei,Loug Yongfu,Liu Yuming and Sun Lemin.The Study of Synthesis, Characteristics and Conductivity of Poly-p-phenylene and its Derivatives[J].Journal of National University of Defense Technology,1996,18(3):49-53. |
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| Authors: | Li Yinkui Liu Qingzhi Huang Shan Sun Wei Loug Yongfu Liu Yuming and Sun Lemin |
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| Abstract: | With tetrapyridine nickel dinitrile(TPNDN) as Catalyst, the poly-p-phenylene(ppph) is synthesized from bromobenzene. The derivatives of ppph, poly (2,5-dimethoxy) -p-phenylene, poly (2, 5-diethoxy)-p-phenylene and poly (2, 5-dibutoxy) -p-phenylene are synthesized from hydroquinone by using FeCl3 as catalyst. IR spectra of these polymers are presented and conductivity and current versus voltage(IV) characteristics are determined. |
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| Keywords: | poly-p-phenylene poly (2 5-dimethoxy) -p-phenylene poly(2 5-diethoxy)-p-phenylene poly (2 5-dibutoxy)-p-phenylene |
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