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价层电子对互斥理论的一种简洁推导
引用本文:邓玉良,张健,王勇,夏春风,杨勤,李彩云,李秀娟.价层电子对互斥理论的一种简洁推导[J].中国人民武装警察部队学院学报,2008,24(2):90-92.
作者姓名:邓玉良  张健  王勇  夏春风  杨勤  李彩云  李秀娟
作者单位:邓玉良(武警学院,基础部,河北,廊坊,065000);张健(武警学院,基础部,河北,廊坊,065000);王勇(武警学院,基础部,河北,廊坊,065000);夏春风(武警学院,基础部,河北,廊坊,065000);杨勤(武警学院,基础部,河北,廊坊,065000);李彩云(武警学院,基础部,河北,廊坊,065000);李秀娟(武警学院,基础部,河北,廊坊,065000)
摘    要:价层电子对互斥理论在推测分子构型方面有着广泛的应用,是现代分子结构理论的一个重要知识点,通过简洁的数学推导证明了分子构型与价层电子对之间的对应关系,并根据解析几何学分析多面体各顶点与其中心的距离,借以判断多原子分子中中心原子的孤对电子应处的位置,其结论完全符合价层电子对互斥理论的预测。

关 键 词:价层电子对互斥理论  分子空间构型  欧拉公式
文章编号:1008-2077(2008)02-0090-03
修稿时间:2007年6月13日

A Concise Proof to the VSEPR Theory and Its Model Presentation by Paper-folding
DENG Yu-liang,ZHANG Jian,WANG Yong,XIA Chun-feng,YANG Qing,LI Cai-yun,LI Xiu-juan.A Concise Proof to the VSEPR Theory and Its Model Presentation by Paper-folding[J].Journal of the Chinese People's Armed Police Force Academy,2008,24(2):90-92.
Authors:DENG Yu-liang  ZHANG Jian  WANG Yong  XIA Chun-feng  YANG Qing  LI Cai-yun  LI Xiu-juan
Institution:DENG Yu - liang, ZHANG Jian, WANG Yong, XIA Chun - feng, YANG Qing, LI Cai - yun, LI Xiu - juan (Basic Courses Teaching Department, The Armed Police Academy, Langfang , Hebei Province 065000, China)
Abstract:The VSEPR theory is widely applied in predicting the geometries of molecules and ions and it is an important theory of modern molecular structure. In the process of teaching, students usually feel difficult to understand the relation between the valence shell electron pair (VP) and the molecular structure, and they can hardly predict the position of the lone pair (LP) of the valence shell electron about the central atom. In this paper, we prove the relation between the valence shell electron pair and its molecular structure by means of stereo - geometry, and furthermore we can determine the positions in which the lone pair should stay by paper- folding model. We can get all of the molecular structure just through a stretch of thick paper, therefore it can make students feel relaxed in learning and easily to comprehend and grasp the theory, and it may excite them to extensive study.
Keywords:paper - folding model  VSEPR  molecular structure  euler' s formula
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