新型涂层固相微萃取-气相色谱分析检测VX

以溶胶凝胶和交联固化相结合的方法制备了杯[4]芳烃开链冠醚／羟基硅油（Calix[4]open chain ether／OH-TSO）复合涂层固相微萃取探头,采用固相微萃取与气相色谱联用的方法测定水和土壤中的VX．并对自制探头的萃取效率、热稳定性、抗溶剂冲洗能力、使用寿命,保质期以及探头制备重现性等性能进行了系统研究．     

顶空固相微萃取——气相色谱法测定擦拭样品基质中的芥子气

固相微萃取是在20世纪90年代初发展起来的新的样品预处理方法,它集萃取、浓缩和进样于一身。具有快速、高效、简便等优点。研究用顶空固相微萃取一气相色谱法测定擦拭样品基质中的芥子气,实验结果表明,该方法在5～280ng间有良好的线性关系,最小检出量为5ng。     

固相微萃取－气相色谱法测定土壤基质中痕量的路易氏剂

详细论述了用固相微萃取－气相色谱法检测水相中的路易氏剂。在此研究基础之上,通过液－固提取方法对土壤基质中的路易氏剂进行提取,提取液经过滤、巯剂化衍生后,直接进行固相微萃取,经气相色谱－火焰光度（硫）检测器进行定量检测。该方法与传统的液－液萃取相比具有简便、快捷、无溶剂消耗、选择性好的特点。最小检出浓度为5ng/ml。在5－300ng/ml的浓度范围内具有良好的线性关系。对土壤中加标化合物的回收率在80％以上。     

固相微萃取技术及其在毒剂分析中的应用

综述了固相微萃取的装置,原理、发展及其在毒剂分析中的应用．     

固相微萃取技术及应用

综述了一种新的样品前处理方法——固相微萃取(Solid—Phase Microextraction,简称SPME),该技术集萃取、富集、进样于一体,具有操作简单、价廉、无污染、易于自动化等优点。针对分析所需的固定相、样品量和容器体积、萃取时间、无机盐的使用、pH值、温度等进行分析,优化反应条件,并对该技术的应用进行了综述。     

固相微萃取-气相色谱法测定擦拭样品基质中路易氏剂

建立了擦拭棉签基质中路易氏剂的固相微萃取一气相色谱法(SPME-GC)测定方法,结果表明,擦拭棉签基质中加标回收率大于80％;相对标准偏差小于5％。     

CTAB反相微乳体系的相行为研究

阳离子表面活性剂CTAB在微乳领域有广泛的应用.以CTAB为表面活性剂,分别将几种不同烷烃作为油相、几种不同醇作为助表面活性剂制备反相微乳体系,对微乳体系增溶纯水和增溶盐溶液时的相行为进行了研究.结果表明,当体系的水相为纯水或盐溶液时,正庚烷作为油相、正丁醇作为助表面活性剂使体系有最佳的增溶效果.     

纳米Si-C-N粒子增强Si3N4 复合材料的结构与性能

本文用Ｓｉ－Ｃ－Ｎ纳米微粉做增强相,Ｓｉ３Ｎ４微粉为基相,采用热压的方法制备了ＳｉＣｐ／Ｓｉ３Ｎ４纳米复相陶瓷,所得的ＳｉＣｐ／Ｓｉ３Ｎ４复合材料的室温弯曲强度为８７８．５ＭＰａ,断裂韧性达１１．９６ＭＰａｍ１／２,同时应用扫描电镜（ＳＥＭ）、高分辨透射电镜（ＨＲＴＥＭ）对其结构进行了观察,讨论了结构与性能之间的关系。     

甲醇气相氧化羰基化合成碳酸二甲酯的研究

采用固体离子交换法制备Cu^I／分子筛催化剂和沉淀法制备碱式氯化铜催化剂,利用微反-色谱装置进行活性评价。通过实验发现,当固体离子交换法制备的Cu^I／分子筛催化剂表面生成Cu2（OH）3Cl化合物时,催化剂的转化率、选择性的定量数据得到很大提高;而单纯以沉淀法制备的碱式氯化铜催化剂基本上没有什么活性。     

气—固两相自由射流的粒子仿真方法

采用粒子仿真方法直接跟踪颗粒相运动轨迹,采用NND格式求解NS方程,数值模拟了气-固两相自由射流流场.计算结果表明,将粒子仿真与CFD方法相结合是研究气-固两相流动问题的有效途径.颗粒相参数变化将对气体流场产生一定影响.     

Reviews

Douglas S. Derrer, We Are All the Target: A Handbook of Terrorism Avoidance and Hostage Survival. Annapolis, MD: US Naval Institute Press, 1992. Pp. x+135, notes, index. $14.95. ISBN 01–55750–150–5

Ian Knight, Zulu: Isandlwana and Rorke's Drift, 22–23 January 1879. London: Windrow & Greene, 1992. Pp.136, 150 illus., incl 8 colour plates, maps, biblio. £35. ISBN 1–872004–23–7

Ian Knight, By the Orders of the Great White Queen: Campaigning in Zululand through the Eyes of the British Soldiers, 1879. London: Greenhill Books and Novato: Presidio Press, 1992. Pp. 272, 17 illus., 1 map. £18.95. ISBN 1–85367–122–3

Manfried Rauchensteiner and Erwin A. Schmidl (eds.), Formen des Krieges: vom Mittelalter zum ‘Low‐intensity’ Conflict’. Graz : Verlag Styria, 1991. Pp.208. DM35. ISBN 3–22–12139–7

Harold J. Kearsley, Maritime Power and the Twenty‐First Century. Dartmouth: Dartmouth Publishing Company, Limited, 1992. Pp.xv + 203, 13 diagrams, index. £32.50. ISBN 1–85521–288–9     

Panjwai: a tale of two COINs in Afghanistan

The US Army has two approaches to counterinsurgency operations in Afghanistan. One is hard, or combat-focused, and the other is soft, or development-focused. This study examines two US Army task forces deployed to Panjwai District, Afghanistan from 2012 to 2013. CTF 4-9 and 1-38 offer a meaningful comparison because they pursued these contrasting approaches among the same population and against the same enemy at the same time and place. The study compares each unit’s approach and finds that neither approach was successful absent the other. The article concludes by recommending further research into combining the approaches at the operational level.     

线性核时频信号表示及其仿真

根据ｃｈｉｒｐ信号在模糊域的特点,本文提出了线性核时频表示方法。这种方法在提高分辨率、消除交叉项以及抑制噪声等方面都具有较高的性能。理论分析和实验结果都证实了这种方法的有效性     

Forecasting a Hurricane: Israeli and American Estimations of the Khomeini Revolution

The surprising ‘Arab Spring’ raises the question as to what would enable national intelligence to provide high quality warnings prior to the eruption of popular revolutions. This article uses new sources of evidence to trace and explain Israel's success in comparison to US failure at correctly estimating the course of the Iranian Revolution in 1977–79. In explaining this variance, the article shows that it was mainly the result of the intimate acquaintance of Israel's representatives in Iran with the local language, history and culture, as well as the ability to communicate with locals – tools which the Americans completely lacked.     

关于教师继续教育培训模式的思考

继续教育作为终身教育的重要组成部分和基本形式,对教师的发展成长意义重大。继续教育工作开展十多年来,取得了一定的成绩,但还存在不少问题,如学习动机较为被动,管理认识不到位,教学内容陈旧空泛,教学方法呆板机械等。随着课程改革的不断深入,继续教育必须采取相应的改进措施,树立以人为本,服务至上的观点,教学内容的前瞻性与实用性并重,教学人员进行整合,教学方法灵活多样,评价考核规范科学等,以此激活受训教师内在的学习动机,更大程度地提高继续教育培训的实际效果。     

用DirectShow实现网络视频

目前市场上的网络监控技术一般用昂贵的硬件设备来支撑,投资较大。在深入研究微软的DirectX9.0的基础上,提出如何用DirectShow软件技术和普通的数字摄像头来实现网络视频的监控和实现技术,内容涉及通信协议、视频的编码与解码技术、视频的编码格式和COM组件编程技术等,最终的实验结果令人满意,且费用低廉,技术可靠,为在高速局域网内构建视频监控系统提供有效的技术支持。     

Interpreting the Ribchester Helmet

In 1796 a 13-year-old boy playing on wasteland behind his father’s house in Ribchester, Lancashire discovered an assemblage of over 30 Roman artefacts, including a decorated brass helmet. Although partially corroded the Ribchester helmet is a fine example of a first-century AD cavalry sports helmet. This article considers how the interpretation of the helmet has evolved since its discovery. The multi-faceted iconography of the helmet with its mural crown diadem is that of an elite soldier and is paralleled in other examples of cavalry sports helmets of the Ribchester type. The long-neglected imagery on the helmet bowl is reinterpreted and seen not as a haphazard collection of randomly placed combatants but as a highly structured, symmetrical composition specifically designed to be viewed from different directions.     

Putin – the masked nemesis of the strategy of ambiguity

Recent events demonstrate the complex and adaptive approach employed by Russia to reassert influence in Europe. The changing face of Russia’s strategy commenced in 2007 when it launched a crippling cyber-attack against Estonia. This was followed by a large Russian conventional attack against Georgia in 2008, occupying two large areas of the nation. 2014 witnessed the Russian annexation of Crimea where in just a week, Russia seized control of Crimea “without firing a shot.” The annexation of Crimea was rapidly followed by a Russian inspired and led subversive war in eastern Ukraine. The common thread among these diverse Russian operations is its use of ambiguity to confound and confuse decision makers in the West.     

Desert insurgency: lessons from the third Tuareg rebellion

This article provides an in-depth examination and analysis of the 2006–2009 Tuareg rebellion in Mali and Niger. It identifies the underlying reasons behind the rebellion, explores contrasting counter-insurgency (COIN) strategies employed by the two governments, and presents some lessons learned. While both COIN approaches ultimately produced similar peace settlements, the article argues that the Malian strategy of reconciliation combined with the selective use of force was far more effective than the Nigerien iron fist approach at limiting the size and scope of the insurgency and producing a more sustainable peace. It concludes by looking at the role of external actors, particularly the United States, and how the failure to internationalize the conflict was actually more beneficial to the local COIN effort, as well as to the longer strategic interests of the United States in the region.