纳米二氧化硅增强硬质聚氨酯泡沫塑料的制备

采用功率超声,将纳米二氧化硅颗粒分散到多次甲基多苯基多异氰酸酯体系内,然后与聚醚多元醇聚合制得了纳米二氧化硅增强的硬质聚氨酯泡沫塑料。SEM分析表明,纳米二氧化硅均匀分散在聚氨酯泡沫中。在较低添加量时,纳米二氧化硅使压缩强度和冲击强度有一定提高,但会引起多次甲基多苯基多异氰酸酯粘度迅速增加,从而导致发泡反应困难,当添加量为7wt%时,压缩强度和冲击强度开始下降。     

烧结温度对 Cf/SiC 复合材料界面的影响

系统地研究了烧结温度对Cf/SiC复合材料界面和力学性能的影响.结果表明,烧结温度较低(1700℃)时,由于复合材料的烧结性差,纤维与基体间仅仅为一种机械结合,因此纤维与基体间结合很弱,从而导致复合材料力学性能低.烧结温度提高至1800℃后,由于适量的富碳界面相不仅可避免纤维与基体间的直接结合,而且使纤维与基体间的结合强度适中,因而复合材料具有很好的力学性能.进一步提高烧结温度至1850℃或更高温度时,由于界面相与纤维间的反应加重,纤维本身性能大大降低.同时,纤维与基体间结合强度提高,因此复合材料的力学性能大大降低.     

超音速等离子制备Al/Ni涂层的性能特点

以超音速等离子喷涂系统(HEPJet)为平台,采用铝包镍(Al/Ni)自粘结粉末,借助Spray Watch2i在线监测系统、扫描电子显微镜(SEM)、X射线衍射仪(XRD)和WE-10A万能拉伸试验机,研究了超音速等离子喷涂Al/Ni粒子的速度、温度及涂层的组织性能。研究结果表明:超音速等离子喷涂Al/Ni自粘结粉末时,与普通火焰喷涂不同,射流中无明显的放热反应特征,涂层中也未发现Al-Ni化合物;超音速等离子的喷涂功率、喷涂距离等参数对Al/Ni喷涂粒子的状态和涂层组织性能影响显著,当功率为54.6kW、喷涂距离为150mm时,Al/Ni涂层组织致密,与基体的结合强度高达56MPa。     

结构吸波材料 SiC-C纤维的研究

本文用聚碳硅烷(PCS)与煤沥青(P)共混,制得PCS-P 共混物,再经纺丝、氧化、高温烧成,制成了SiC-C 纤维。该纤维电阻率随碳含量的增加而减少,强度和模量随碳含量的增高而降低,而且该纤维与环氧树脂复合制得的层合板材,具有良好的吸收电磁波性能。     

环氧树脂/CTBN/无机颗粒高分子合金修补剂材料的制备与性能分析

通过端羧基丁腈液态橡胶(Carboxyl Terminated Butadiene Acrylonitrile,CTBN)协同纳米Al2O3、SiO2颗粒与微米MoS2颗粒共混改性环氧树脂,制备了双组分的耐磨高分子合金修补剂材料。采用拉伸、摩擦磨损等试验及SEM等方法测试和分析了该高分子合金修补剂的拉伸强度、显微硬度等基本性能及摩擦学性能,并对其耐磨减摩机理进行了分析。结果表明:该材料的拉伸强度为42.3MPa,拉伸剪切强度为13.8MPa,显微硬度为231.1MPa,摩擦因数为0.17,耐磨性比LY12铝合金提高了50%。     

改性双酚A环氧树脂固化机理及其性能

用脂环族三官能度环氧树脂TDE-85改性双酚A型环氧树脂,达到提高耐热性与强韧性的目的.利用DSC对其固化反应机理进行了深入研究,并借助DDA确定中温固化工艺,对中温固化树脂基体的力学性能和热性能的研究表明固化物力学性能优良,与普通双酚A型树脂相比,相同固化体系树脂浇铸体的拉伸强度由47.30 MPa提高到 70.50 MPa,弯曲强度由62.74 MPa提高到85.48 MPa,冲击韧性由9.08×103 J/m2提高到1.09×104 J/m2,拉伸强度、断裂延伸率、弯曲强度及冲击韧性分别提高49.05%、50.0%、36.24%及19.53%.IR 分析表明,固化物的固化度为92.3%.     

聚氨酯阻尼性能研究（Ⅰ）

本文讨论了影响硬段在聚氨酯中分布的因素及其对聚氨酯的形态结构和阻尼性能的影响,指出：软段或硬段交联、固化温度及合成方法都对聚氨酯的形态结构和阻尼性能有影响。在相分离较严重的聚氨酯体系中,增加硬段在软相中的分散程度,有利于提高聚氨酯的阻尼性能。     

硬质聚氨酯泡沫塑料填充薄壁钢管横向压缩吸能特性分析

为研究硬质聚氨酯泡沫塑料填充薄壁钢管后的吸能特性,对单钢管、钢管嵌套系统及填充硬质聚氨酯泡沫塑料后的钢管进行横向静力压缩试验,并对试验结果进行对比分析。结果表明:硬质聚氨酯泡沫塑料填充管比空钢管的吸能效果有明显提高,其中双钢管嵌套系统填充硬质聚氨酯泡沫塑料后吸能效果提高最明显,三钢管嵌套系统吸收外来的能量值最大。薄壁钢管填充硬质聚氨酯泡沫塑料是一种性能优良的吸能装置,在防护工程中可作为隔爆抗侵彻材料。     

铝青铜水下湿法激光焊接焊缝成形与力学性能

为解决湿法焊接焊缝质量不高的问题,对铝青铜材料展开水下湿法激光焊接实验,利用扫描电子显微镜(Scanning Electron Microscope,SEM)、显微硬度仪、万能试验机分别检测和分析了焊接接头的微观组织和力学性能。结果表明:铝青铜水下湿法焊接会出现大量气孔,水深增加会导致气孔增多,提高焊接速度可以改善焊缝成形质量,通过在基体表面预置自蔓延粉末能够有效减少气孔;焊缝中上部为胞状晶组织,底部为发达的树枝晶;焊缝平均硬度为240 HV,与基体相比提高了50%;拉伸试验试件均断裂在焊缝处,平均拉伸强度为235 MPa,为基体的43%。     

纳米SiO_2增韧改性环氧乙烯基酯树脂的性能研究

为了对环氧乙烯基酯树脂(EVER)进行增韧改性,采用KH570硅烷偶联剂对纳米SiO2进行表面处理,考察了纳米SiO2表面改性及其质量分数对EVER力学性能的影响。经过偶联剂处理的纳米SiO2复合材料在树脂基体中具备更好的分散性和相容性,力学性能明显优于纯EVER材料和未经偶联剂处理的复合材料。纳米SiO2质量分数为3%时,纳米SiO2复合材料的拉伸强度、断裂伸长率、冲击强度分别比纯EVER材料提高了42.10%,43.38%和91.91%;纳米SiO2质量分数为4%时,纳米SiO2复合材料的拉伸模量比纯EVER材料提高了34.57%。通过观察冲击断面的SEM照片,分析了纳米SiO2增韧改性的作用机理。结果表明:纳米SiO2增韧改性的关键在于诱发基体产生银纹,使其对裂纹扩展起到钝化、阻碍的作用。     

Heat treatment optimization for tensile properties of 8011 Al/15% SiCp metal matrix composite using response surface methodology

In this study,a mathematical model was developed to optimize the heat treatment process for maximum tensile strength and ductility of aluminum(8011) silicon carbide particulate composites.The process parameters are solutionizing time,aging temperature,and aging time.The experiments were performed on an universal testing machine according to centre rotatable design matrix.A mathematical model was developed with the main and interactive effects of the parameters considered.The analysis of variance technique was used to check the adequacy of the developed model.The optimum parameters were obtained for maximum tensile strength.Fractographic examination shows the cracks and dimples on the fractured surfaces of heat-treated specimen.     

复合陶瓷含片状夹杂共晶体的理论断裂强度

应用四相模型法研究含片状夹杂复合共晶体的细观应力场．在基体、界面相和片状夹杂为各向同性的条件下,得到细观应力分布规律,并表现出明显的尺度效应．应用位错塞积理论研究片状夹杂内的位错运动,通过两相界面处位错塞积产生的应力集中确定其在基体内产生的最大张应力,导致基体首先被破坏失效,当基体内最大张应力等于分子理论的断裂强度时,得到共晶体断裂强度的理论表达式．结果表明：含片状夹杂共晶复合陶瓷强度随夹杂厚度增加而减小．     

Effect of post weld heat treatment on tensile properties and microstructure characteristics of friction stir welded armour grade AA7075-T651 aluminium alloy

This paper reports the effects of post weld heat treatments, namely artificial ageing and solution treatment followed by artificial ageing, on microstructure and mechanical properties of 12 mm thick friction stir welded joints of precipitation hardenable high strength armour grade AA7075-T651 aluminium alloy. The tensile properties, such as yield strength, tensile strength, elongation and notch tensile strength, are evaluated and correlated with the microhardness and microstructural features. The scanning electron microscope is used to characterie the fracture surfaces. The solution treatment followed by ageing heat treatment cycle is found to be marginally beneficial in improving the tensile properties of friction stir welds of AA7075-T651 aluminium alloy.     

UHMWPE复合材料抗爆实验研究

运用定制的聚偏四氟乙烯(PVDF)压电传感器,直接测量爆炸载荷下UHMWPE层叠无纬布和PU基体的UHMWPE复合材料内部冲击波压力峰值,对其冲击波衰减特性进行了实验研究。实验结果表明:UHMWPE复合材料对爆炸冲击波有很好的衰减作用,含有PU基体的UHMWPE复合材料比UHMWPE层叠无纬布对爆炸冲击波有更好的衰减效果。UHMWPE复合材料具有轻质、吸收冲击波效率高等特性,在爆炸冲击波防护领域有很好的应用前景。     

高能微脉冲表面强化修复45CrNiMoVA传动轴性能试验研究

针对某大型船用传动轴工作轴颈表面产生腐蚀坑的问题,采用高能微脉冲表面强化修复技术对试验样轴进行修复。通过拉伸试验筛选了焊丝,采用光学显微镜和显微硬度计分析了修复层的显微组织和硬度,研究了扭转条件下修复层与基体的结合强度。结果表明:Ni-818焊丝修复层与基体的结合强度高,抗拉强度为557MPa;修复层显微组织均匀、致密,硬度差异小;当扭矩为200N.m,且表面最大剪应力为438MPa时,修复层和基体之间结合良好。由此得出结论:采用高能微脉冲表面强化修复技术,使用Ni-818焊丝可实现对45CrNiMoVA传动轴的表面强化修复。     

Friction welding of AA6061 to AISI 4340 using silver interlayer

The present work pertains to the study on joining of AA6061 and AISI 4340 through continuous drive friction welding. The welds were evaluated by metallographic examination, X-ray diffraction, electron probe microanalysis, tensile test and microhardness. The study reveals that the presence of an intermetallic compound layer at the bonded interface exhibits poor tensile strength and elongation. Mg in AA6061 near to the interface is found to be favourable for the formation and growth of Fe2Al5 intermetallics. Introduction of silver as an interlayer through electroplating on AISI 4340 resulted in accumulation of Si at weld interface, replacing Mg at AA6061 side, thereby reducing the width of intermetallic compound layer and correspondingly increasing the tensile strength. Presence of silver at the interface results in partial replacement of Fe-Al based intermetallic compounds with Ag-Al based compounds. The presence of these intermetallics was confirmed by X-ray diffraction technique. Since Ag-Al phases are ductile in nature, tensile strength is not deteriorated and the silicon segregation at weld interface on AA6061 in the joints with silver interlayer acts as diffusion barrier for Fe and further avoids formation of Fe-Al based intermetallics. A maximum tensile strength of 240 MPa along with 4.9% elongation was obtained for the silver interlayer dissimilar metal welds. The observed trends in tensile properties and hardness were explained in relation to the microstructure.     

Optimization of process parameters of aluminum alloy AA 2014-T6 friction stir welds by response surface methodology

The heat treatable aluminum-copper alloy AA2014 finds wide application in the aerospace and defence industry due to its high strength-toweight ratio and good ductility. Friction stir welding(FSW) process, an emerging solid state joining process, is suitable for joining this alloy compared to fusion welding processes. This work presents the formulation of a mathematical model with process parameters and tool geometry to predict the responses of friction stir welds of AA 2014-T6 aluminum alloy, viz yield strength, tensile strength and ductility. The most influential process parameters considered are spindle speed, welding speed, tilt angle and tool pin profile. A four-factor, five-level central composite design was used and a response surface methodology(RSM) was employed to develop the regression models to predict the responses.The mechanical properties, such as yield strength(YS), ultimate tensile strength(UTS) and percentage elongation(%El), are considered as responses. Method of analysis of variance was used to determine the important process parameters that affect the responses. Validation trials were carried out to validate these results. These results indicate that the friction stir welds of AA 2014-T6 aluminum alloy welded with hexagonal tool pin profile have the highest tensile strength and elongation, whereas the joints fabricated with conical tool pin profile have the lowest tensile strength and elongation.     

聚氨酯型复合推进剂的性能研究

本文研究聚氨酯型复合推进剂的力学性能和燃烧性能,给出了提高推进剂力学性能的有效途径,测试了推进剂燃烧性能的基本特征参数,采用光电子能谱(ESCA)对这种复合推进剂的界面作用机理进行了微观探讨.     

Investigation of the mechanical and ballistic properties of hybrid carbon/ aramid woven laminates

High-performance ballistic fibers, such as aramid fiber and ultra-high-molecular-weight polyethylene (UHMWPE), are commonly used in anti-ballistic structures due to their low density, high tensile strength and high specific modulus. However, their low modulus in the thickness direction and insufficient shear strength limits their application in certain ballistic structure. In contrast, carbon fiber reinforced epoxy resin matrix composites (CFRP) have the characteristics of high modulus in the thickness direction and high shear resistance. However, carbon fibers are rarely used and applied for protection purposes. A hybridization with aramid fiber reinforced epoxy resin matrix composites (AFRP) and CFRP has the potential to improve the stiffness and the ballistic property of the typical ballistic fiber composites. The hybrid effects on the flexural property and ballistic performance of the hybrid CFRP/AFRP laminates were investigated. Through conducting mechanical property tests and ballistic tests, two sets of reliable simulation parameters for AFRP and CFRP were established using LS-DYNA software, respectively. The experimental results suggested that by increasing the content of CFRP that the flexural properties of hybrid CFRP/AFRP laminates were enhanced. The ballistic tests’ results and the simulation illustrated that the specific energy absorption by the perforation method of CFRP achieved 77.7% of AFRP. When CFRP was on the striking face, the shear resistance of the laminates and the resistance force to the projectiles was promoted at the initial penetration stage. The proportion of fiber tensile failures in the AFRP layers was also enhanced with the addition of CFRP during the penetration process. These improvements resulted in the ballistic performance of hybrid CFRP/AFRP laminates was better than AFRP when the CFRP content was 20 wt% and 30 wt%.     

聚氨酯/环氧树脂(PU/EP)AB-交联聚合物的研究

用二胺同时固化聚醚氨酯预聚物及环氧树脂,制得了PU/EP AB-交联聚合物(AB-CP)。以动态粘弹仪对其进行了表征,结果表明:形成AB-CP后,PU与EP相之间的相互作用大大加强(强于PU/EF IPN中PU与EP之间的作用),使PU链运动受到限制,其Tg移向高温区并形成了一个单一的Tg峰;研究了物料比、环氧值等对其动态力学谱(DMS)的影响。预期该化合物是一类有前途的增韧环氧树脂材料。