Insensitive energetic microspheres DAAF/RDX fabricated by facile molecular self-assembly

Insensitive energetic materials are promising in the defense weapons field. However, energetic materials still suffer from great challenges and the concern about their safety limits their utilization. In this work, insensitive energetic explosive 3,3′-diamino-4,4′-azoxyfurazan/hexahydro-1,3,5-trinitro-1,3,5-triazine (DAAF/RDX) microspheres were fabricated by self-assembly method. Rod-like DAAF/RDX was prepared by mechanical ball milling for comparison. DAAF/RDX composites with different mass ratios (90:10, 80:20, and 70:30) were obtained. The morphologies and structures of as-obtained DAAF/RDX composites were characterized by scanning electron microscopy (SEM), powder x-ray diffraction (PXRD) and fourier transform infrared spectroscopy (FT-IR). The results showed that DAAF/RDX microspheres exhibited regular shaped microspheres with sizes from 0.5 to 1.2 μm. There was no crystal transition during the modification process. The thermal properties of as-obtained materials were then evaluated by differential scanning calorimetry (DSC) and materials studio software. DAAF/RDX microspheres showed an advanced decomposition peak temperature compared with rod-like DAAF/RDX. The binding energy and peak temperature values at zero β_i (T_P0) of DAAF/RDX (90:10) increased by 36.77 kJ/mol, 1.6 °C, and 58.11 kJ/mol, 12.3 °C compared to DAAF/RDX (80:20) and DAAF/RDX (70:30), indicating the better thermal stability of DAAF/RDX (90:10). The characteristic drop height (H₅₀) of DAAF/RDX (higher than 100 cm) composites was higher than that of raw RDX (25 cm), suggesting significant improvements in mechanical safety. The preparation of DAAF/RDX microspheres is promising for the desensitization of RDX and useful for the formation of other materials and future wide applications.     

Mitigation effects on the reflected overpressure of blast shock with water surrounding an explosive in a confined space

The mitigation of blast shock with water has broad application prospects. Understanding the mitigation effects on the reflected overpressure of the explosion shock with water surrounding an explosive in a confined space is of great significance for military explosives safety applications. To estimate the effects of the parameters on the reflected overpressure of blasted shock wave, a series of experiments were carried out in confined containers with spherical explosives immersed in a certain thickness of water, and numerical simulations were conducted to explore the corresponding mechanisms. The results reveal that the reflected overpressure is abnormally aggravated at a small scaled distance. This aggravation is due to the high impulse of the bulk accelerated water shell converted from the explosion. With increasing scaled distance, the energy will be gradually dissipated. The mitigation effects will appear with the dispersed water phase front impacting at a larger scaled distance, except in the case of a dense water phase state. A critical scaled distance range of 0.7—0.8 m/kg1/3 for effective mitigation was found. It is suggested that the scaled distance of space walls should be larger than the critical value for a certain water-to-explosive weight ratio range (5—20).     

90纳米CMOS双阱工艺下STI深度对电荷共享的影响

基于3维TCAD器件模拟,研究了90nm CMOS双阱工艺下STI对电荷共享的影响.研究结果表明:增大STI深度能有效抑制NMOS电荷共享,且550nm为抑制电荷共享的有效深度,超过这个深度收集的电荷量几乎保持不变;而对于PMOS,STI深度的增加使电荷共享线性减小.这对于电荷共享加固具有重要指导意义.     

角度欺骗有源假目标的动力学特性

针对高空高速目标探测过程中可能出现的角度类欺骗有源假目标,从理论上系统地分析了其动力学性质,导出了假目标的动力学方程,并分析了假目标的机械能和动量矩守恒问题。理论分析和仿真试验均表明,具有固定角度欺骗的方位有源假目标其动力学特性和真实目标完全一致,在动力学上是无法鉴别真伪的;除此之外的其他角度类欺骗有源假目标均不满足高空高速目标椭圆轨道特性以及动力学守恒定律,利用这种差异可以在数据处理层对假目标进行鉴别。     

美军军法官制度简介

美军的政治性工作一般由两“师”完成,一个是牧师,另一个则是随军律师。而随军律师是处理法律问题的军官的泛称,主要指的就是军法官(JudgeAdvocate)和其领导下的法律助手、律师等。2003年的伊拉克战争中,美军约有103位军法官、62名法律专职助手深入战场。①他们在拘押战犯,发表对外声明,与英军建立联合军事司法系统和提供交战规则,促使官兵遵守国际战争法、军事行动法上起了相当大的作用。一、起源与概念在美军中没有法律战的明确词汇和概念,但是这并不意味着美军不运用法律武器以达到军事目的。相反,他们相当擅长和重视这一工作,而且已有…     

辅助鞅下投资消费资产模型的一些基本性质

针对所给出的有交易费的资产模型,引入了资产折算函数,并利用辅助鞅和凸函数对偶方法,讨论了该模型下折算资产优化的性质.     

B介子的稀有非轻子衰变和CP破坏

在BS理论框架下,求解了ρ和K*的波函数,计算了B→ρ和B→K*跃迁的形状因子,进而计算出B介子衰变到2个轻介子稀有过程的分支比和CP破坏量.     

用能量法确定层状复合材料疲劳裂纹的扩展方向

含裂纹体疲劳寿命的预测,必须首先了解裂纹扩展路径的全过程,而在层状复合材料中,裂纹扩展的路径非常复杂,不仅可以拐弯,而且可以分叉.因此,首先提出一个简单、适用、统一的裂纹扩展方向的相对强度准则,即应变能释放率比值判据;然后,利用有效解决高梯度问题的数值方法--任意线法,对实测试件的关键时刻(例如,拐弯或进入界面),进行了数值分析;并对典型试件进行了疲劳断裂实验研究.3方面的结果,得到相互的验证.这种一致性,不仅初步证明了这一方法的正确性和适用性,而且为疲劳裂纹扩展全过程的解决,提供了必要的基础.     

A comparative study of three tool replacement/operation sequencing strategies in a flexible manufacturing system

This paper studies three tool replacement/operation sequencing strategies for a flexible manufacturing system over a finite time horizon: (1) failure replacement—replace the tool only upon failure, (2) optimal preventive tool replacement for a fixed sequence of operations, and (3) joint scheduling of the optimal preventive tool replacement times and the optimal sequence of operations. Stochastic dynamic decision models are used for strategies 2 and 3. The optimization criterion for strategies 2 and 3 is the minimization of the total expected cost over the finite time horizon. We will show through numerical studies that, with the same amount of information, the total expected costs can be reduced considerably by choosing an optimal strategy. Our conclusion is that in flexible manufacturing, optimal tool replacement and optimal operations sequencing are not separate issues. They should be considered jointly to minimize the expected total cost. © 2000 John Wiley & Sons, Inc. Naval Research Logistics 47: 479–499, 2000