Insensitive energetic microspheres DAAF/RDX fabricated by facile molecular self-assembly

Insensitive energetic materials are promising in the defense weapons field. However, energetic materials still suffer from great challenges and the concern about their safety limits their utilization. In this work, insensitive energetic explosive 3,3′-diamino-4,4′-azoxyfurazan/hexahydro-1,3,5-trinitro-1,3,5-triazine (DAAF/RDX) microspheres were fabricated by self-assembly method. Rod-like DAAF/RDX was prepared by mechanical ball milling for comparison. DAAF/RDX composites with different mass ratios (90:10, 80:20, and 70:30) were obtained. The morphologies and structures of as-obtained DAAF/RDX composites were characterized by scanning electron microscopy (SEM), powder x-ray diffraction (PXRD) and fourier transform infrared spectroscopy (FT-IR). The results showed that DAAF/RDX microspheres exhibited regular shaped microspheres with sizes from 0.5 to 1.2 μm. There was no crystal transition during the modification process. The thermal properties of as-obtained materials were then evaluated by differential scanning calorimetry (DSC) and materials studio software. DAAF/RDX microspheres showed an advanced decomposition peak temperature compared with rod-like DAAF/RDX. The binding energy and peak temperature values at zero β_i (T_P0) of DAAF/RDX (90:10) increased by 36.77 kJ/mol, 1.6 °C, and 58.11 kJ/mol, 12.3 °C compared to DAAF/RDX (80:20) and DAAF/RDX (70:30), indicating the better thermal stability of DAAF/RDX (90:10). The characteristic drop height (H₅₀) of DAAF/RDX (higher than 100 cm) composites was higher than that of raw RDX (25 cm), suggesting significant improvements in mechanical safety. The preparation of DAAF/RDX microspheres is promising for the desensitization of RDX and useful for the formation of other materials and future wide applications.     

Preparation and characterization of HMX/EVA/hBNNSs micro-composites with improved thermal stability and reduced sensitivity

Hexagonal boron nitride nanosheets(HBNNSs)have huge potential in the field of coating materials owing to their remarkable chemical stability,mechanical strength and thermal conductivity.Thin-layer hBNNSs were obtained by a liquid-phase exfoliation of h-BN powders and incorporated into EVA coatings for improving the safety performance of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX).HBNNSs and ethylene-vinyl acetate copolymer(EVA)were introduced to HMX by a solvent-slurry process.For com-parison,the HMX/EVA and HMX/EVA/graphene(HMX/EVA/G)composites were also prepared by a similar process.The morphology,crystal form,surface element distribution,thermal decomposition property and impact sensitivity of HMX/EVA/hBNNSs composites were contrastively investigated.Results showed that as prepared HMX/EVA/hBNNSs composites were well coated with hBNNSs and EVA,and exhibited better thermal stability and lower impact sensitivity than that of HMX/EVA and HMX/EVA/G composites,suggesting superior performance of desensitization of hBNNSs in explosives.     

构建和谐社会与促进人的全面发展

构建社会主义和谐社会与促进人的全面发展,是社会发展同一历史过程的不同方面,二者在价值目标导向上高度一致,在社会历史进程上高度契合,归根到底都要以社会生产力的高度发达为支撑。深刻理解二者之间的辩证统一关系及其在实践中的双向互动作用,对于我们在构建社会主义和谐社会的进程中真正做到以人为本、不断促进人的全面发展,具有重要意义。     

国防科技工业专利研究

本文主要阐述了国防专利的基本特点,分析了我国国防专利的现状、问题及制约因素,针对我国实施知识产权战略的要求,结合国防专利的特点,研究提出了加强国防专利保护的若干对策。     

努力创新不断完善"三大规范"体系——谈火工品"三大规范"编制

根据火工品“三大规范”编制工作实践经验,介绍了企事业单位开展“三大规范”工作的程序,“三大规范”体系构成的条件和特点,火工品“三大规范”编制项目设置思路,以及做好“三大规范”编制工作的体会。     

军车内饰设计浅析

军车的内饰设计和普通客车相比有更高的要求,目前军车内饰的设计、制作和选择都显得日益重要,逐渐成为一个新兴的科研方向。本文主要通过对国内外内饰面料的设计、选择等方面的介绍分析,为读者掀开军车内饰设计的一角,展现军车内饰设计的发展趋势。     

信息化车辆装备试验场建设探析

本文主要阐述了建设信息化车辆装备试验场的必要性、基本概念、基本特点与建设的基本途径,旨在为我军轮式车辆装备试验场的信息化建设提供参考。     

硫二甘醇及其相关氧化产物的硅烷化衍生反应条件优化及应用

研究了衍生气相色谱法测定芥子气的降解产物硫二甘醇、硫二甘醇亚砜和硫二甘醇砜的方法,并对影响衍生反应的溶剂、温度、时间和衍生试剂用量进行了优化,该法操作简便、灵敏度高。     

磷碳键的构建

含有磷碳键的有机磷化合物广泛应用于农药、医药、塑料添加剂等领域,构建磷碳键是有机磷化学研究的基本问题之一．概要的评述了Michaelis-Arbuzov反应、Becker反应、过渡金属催化反应和含磷氢键化合物对不饱和烯炔的加成等几种形成磷碳键的化学反应．     

等离子体销毁日本遗弃化学武器排放气体采集方法选择探讨

等离子体销毁日本化学武器是目前正在探索的新课题,销毁过程排放尾气采集方法是该课题中需研究的内容之一。在认真分析、综合比较的基础上,提出了适应等离子体销毁日本遗弃化学武器的排放尾气采集方法的看法及其须关注的问题。