Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

Prediction of three-dimensional elastic behavior of filament-wound composites based on the bridging model

This work provides a method to predict the three-dimensional equivalent elastic properties of the filament-wound composites based on the multi-scale homogenization principle.In the meso-scale,a representative volume element(RVE)is defined and the bridging model is adopted to establish a theoretical predictive model for its three-dimensional equivalent elastic constants.The results obtained through this method for the previous experimental model are compared with the ones gained respec-tively by experiments and classical laminate theory to verify the reliability of this model.In addition,the effects of some winding parameters,such as winding angle,on the equivalent elastic behavior of the filament-wound composites are analyzed.The rules gained can provide a theoretical reference for the optimum design of filament-wound composites.     

国内装备采购研究现状与趋势研究——基于CiteSpace知识图谱软件的可视化分析

本文利用CiteSpace知识图谱分析和可视化工具,从时间分布、期刊来源和作者机构等方面对CNKI中文期刊全文数据库2001年1月1日至2020年6月30日间收录的以"装备采购"为关键词的642篇学术论文及文献进行数据可视化分析,并通过关键词词频共现分析对该领域的高频关键词进行了词频统计。在利用CiteSpace软件对"装备采购"相关文献进行统计分析后,详细论述了装备采购研究的发展趋势,并总结出目前军队装备采购研究的现状与不足,如军队内部科研力量作为装备采购领域研究的核心组成部分,相互间缺乏交流研究;装备采购领域研究方向多元,但基础理论、概念研究不够深入等。在此基础上梳理出优化后期装备采购领域研究发展的建议,以期为完善军队装备采购领域的研究工作提供一定参考。     

Investigate the effects of magnetic fields on the penetration ability of a shaped charge jet at different standoffs

The influence of a magnetic field on the stability of a shaped charge jet is experimentally investigated at standoffs of 490, 650 and 800 mm. The experimental results without and with the magnetic field are compared in terms of the shaped charge jet form, stability and penetration ability. A theoretical model based on one-dimension fluid dynamics is then developed to assess the depth of penetration of the shaped charge at those three standoffs and magnetic conditions. The results show that the penetration capability can be enhanced in more than 70% by the magnetic field. The theoretical calculations are compared with the experimental results with reasonably good correlation. In addition, the parameters introduced in the theory are discussed together with the experiments at three standoffs studied.     

排队论在导弹防御体系射击效能中的应用

针对当前空袭手段多样化、综合化和一体化的特点,运用排队论方法,设计了一种基于排队论的射击效能评估模型。该模型综合考虑了各种因素对舰空导弹射击效能的影响,当编队的配置(如防御层数、通道数量)有所变化时,依然可以灵活运用上述模型对编队射击效能做出准确评估。     

三坐标雷达目标真实高度估计算法研究

在目标跟踪领域,通过三坐标雷达的测量值(斜距、仰角及方位角)来估算目标的真实高度一直是个难点。目前主要有两类处理方法:坐标转换法和等效地球半径法。前者把与雷达天线相关的三坐标测量值转换到大地坐标系统来计算目标高度;后者充分考虑地球曲率以及大气折射的特性,通过增加地球半径来估算目标的高度。最后对上述的两类方法进行总结、比较与分析。     

新型驱护舰编队舰空导弹防御体系射击效能研究

针对新型驱护舰编队舰空导弹防御体系射击效能评估这一难题,对其射击效能准则进行了确立,提出了基于排队论的射击效能评估模型,对体系射击效能进行仿真计算,总结出能对系统射击效能做出准确评估的方法,并利用实例对模型进行了验证。     

舰艇编队协同反导火力分配的改进多目标粒子群算法

为提高协同反导时的多目标火力分配计算能力,首先建立了火力分配多目标数学模型;然后,针对火力分配多目标规划具有的线性不等式约束条件难以使用多目标粒子群优化算法、粒子群算法自身存在的盲目搜索等问题进行了改进,并明确了计算流程;最后,对算法进行了仿真实验,仿真实验表明:改进的多目标粒子群算法求解多目标火力分配规划模型得到的非劣解集可构成Pareto前端,且非劣解集的适应度最大值随迭代步数演变具有稳定的收敛性,验证了改进多目标粒子群算法的有效性.     

两个积分中值定理内点性的新证明

积分第一中值定理和第二中值定理是定积分理论中两个十分重要的定理,近年来关于其内点性的讨论非常广泛。首先根据连续函数的介值定理,用一种新方法证明积分第一中值定理的内点性;然后提出一个实例,说明积分第二中值定理在通常条件下不具有内点性;最后利用定积分存在的充要条件和Abel变换的手段,证明积分第二中值定理在加上一个非常一般化的条件时具有内点性。     

阈下情绪面孔及其脑机制

以阈下情绪面孔为切入点,了解阈下视觉及其脑机制.文章在总结阈下情绪面孔实验的实验范式、刺激材料、实验技术的基础上,重点阐述了阈下情绪面孔加工的脑机制,提出了下一步的研究展望.