Theoretical design of new bridge-ring insensitive high energy compounds by selected normal Diels-Alder reactions between NH2-substituted oxazoles and NO2/NF2/NHNO2-substituted ethylenes/acetylenes

In this work, NH₂-substituted oxazoles and NO₂/NF₂/NHNO₂-substituted ethylenes/acetylenes were designed and used as dienes and dienophiles, respectively, in order to develop new bridge-ring insensitive high energy compounds through the Diels-Alder reaction between them. The reaction type, reaction feasibility and performance of reaction products were investigated in detail theoretically. The results showed that dienes most possibly react with dienophiles through the HOMO-diene controlled normal Diels-Alder reaction at relatively low energy barrier. Tetranitroethylene could react with the designed dienes much more easily than other dienophiles, and was employed to further design 29 new bridge-ring energetic compounds. Due to high heat of formation, density and oxygen balance, all designed bridge-ring energetic compounds have outstanding detonation performance, 16 of them have higher energy than HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazocine) and 2 others even possess comparative energy with the representative of high energy compounds CL-20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane). The predicted average h₅₀ value of these bridge-ring energetic compounds is 83 cm, showing their low impact sensitivity. The NH₂ groups could obviously impel the proceeding of Diels-Alder reactions, but would slightly decrease the energy and sensitivity performance. In all, the new designed bridge-ring compounds have both high energy and low sensitivity, and may be produced through Diels-Alder reactions at relatively low energy barrier. This paper may be helpful for the theoretical design and experiment synthesis of new advanced insensitive high energy compounds.     

基于改进噪声检测的迭代中值滤波算法

提出了一种基于改进噪声检测的迭代中值滤波算法。该算法首先检测出噪声点,然后利用信号点对噪声点滤波。其中噪声检测方法改进了IMFLED方法,进一步降低了误检率和漏检率。经过仿真实验并与其他滤波算法进行比较表明,该算法可以有效地去除图像中的脉冲噪声并且保留原图像的细节。     

装甲车辆电传动技术现状、关键技术与发展

介绍了目前世界上装甲车辆电传动发展的现状和趋势,分析了国外相关研究成果,阐述了装甲车辆电传动中的关键技术,并对我国装甲车辆电传动的发展,提供了参考性建议.     

关于在教师队伍中弘扬兵团精神的几点思考

针对兵团教师队伍的现状,本文认为需要在教师队伍中进一步弘扬兵团精神。新时期弘扬兵团精神必须要加大对兵团精神的宣传力度,提高青年教师对兵团精神的认识;弘扬兵团精神必须与加强教师职业道德建设相结合,帮助教师形成新型的师德观;弘扬兵团精神必须与切实提高教师的待遇相结合,倡导奉献精神与改善教师待遇并不矛盾;弘扬兵团精神必须把加强学校管理与加强教师自我修养相结合,提高教师的整体素质。     

地面无人作战系统机械臂运动学建模与仿真

以某地面无人作战系统中的机械臂为研究对象,探讨其运动学模型建立中的相关问题．结合该机械臂的结构特点,利用D-H方法建立其相应的运动学模型,并在该基础上求解机械臂的正、逆运动学方程．最后在Matlab环境下,借助Robotics Toolbox工具箱对该机械臂的结构和运动学问题进行验证和仿真．仿真结果表明：该设计方法是正确可行的．     

网络全域:Cyberspace的概念辨析与思考

通过词源分析和背景介绍,从军事、物理学和社会学等角度给出对Cyberspace的内涵与特征的理解,在定义了Cyberspace概念的基础上,给出"网络全域"的译名及其考量因素。     

登月舱制动段最优机动中的状态跟踪

本文根据登月舱的运动方程,在固定推力条件下,给出最优推力方向。在最优推力方向上对摄动方程加入自适应调节控制,得到状态跟踪的稳定性,使受控系统的输出跟踪状态精度得到保证。     

电磁轨道发射装置动态电感梯度分析

推导了导轨间磁场均匀分布和非均匀分布两种情况下电感梯度数学计算模型。引入了速度频率来模拟电枢发射过程速度趋肤效应,对导轨二维模型以及三维电磁场模型进行时谐仿真,并将获得的单位长度电感以及电感梯度,分别用于电气仿真系统中电感和电枢推力的计算。电气仿真和试验结果表明,电流和出口速度误差均在2%以内,证明了动态电感梯度分析及参数提取方法的正确性和准确性。     

增量元学习IDBD算法在轴频电场信号检测中的应用

为了提高海洋环境电场背景中微弱舰船轴频电场的检测能力,针对传统的最小均方误差算法进行了改进,提出了一种基于增量元学习IDBD算法的自适应线谱增强器。利用所提算法对舰船缩比模型产生的实测轴频电场信号数据进行处理,结果表明该算法在低信噪比的情况下能够有效地将微弱轴频电场信号从宽带背景噪声中分离出来。所提算法相比于普通的自适应线谱算法,在改善信号的信噪比方面效果更加显著,且具有更快的收敛速度和更小的稳态误差,极大提高了舰船轴频电场的检测能力。     

Statistical equivalency and optimality of simple step‐stress accelerated test plans for the exponential distribution

Accelerated life testing (ALT) is commonly used to obtain reliability information about a product in a timely manner. Several stress loading designs have been proposed and recent research interests have emerged concerning the development of equivalent ALT plans. Step‐stress ALT (SSALT) is one of the most commonly used stress loadings because it usually shortens the test duration and reduces the number of required test units. This article considers two fundamental questions when designing a SSALT and provides formal proofs in answer to each. Namely: (1) can a simple SSALT be designed so that it is equivalent to other stress loading designs? (2) when optimizing a multilevel SSALT, does it degenerate to a simple SSALT plan? The answers to both queries, under certain reasonable model assumptions, are shown to be a qualified YES. In addition, we provide an argument to support the rationale of a common practice in designing a SSALT, that is, setting the higher stress level as high as possible in a SSALT plan. © 2012 Wiley Periodicals, Inc. Naval Research Logistics, 2013