Thermodynamics and performance of Al/CuO nanothermite with different storage time

The storage stability of energetic materials is important for its application. Here, the storage stability of Al/CuO nanothermite, which was prepared by electrospray method and stored with different storage time, was systematically researched. The activation energy of Al/CuO nanothermite was calculated by differential scanning calorimetry (DSC). The ignition temperature and the curve pressure history of Al/CuO nanothermite was measured using ignition temperature measuring device and constant-volume pressurization tests, respectively. Further, the thermites were characterized by X-ray Diffractometer (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and Transmission electron microscopy (TEM). The results show that the morphology of the thermites did not change significantly. The activation energy was decreased from 254.1 kJ/mol to 181.8 kJ/mol after storage for 13 months. When stored for 0, 7 and 13 months, the peak pressures of Al/CuO nanothermite were 685.8 kPa, 626.3 kPa and 625.5 kPa, respectively. In addition to the ignition temperature, it was 775 ℃, 739 ℃ and 754 ℃, respectively. This result indicated that the ignition and combustion properties of Al/CuO nano-thermite are obviously reduced when stored for a long time, at room temperature.     

A reusable planar triggered spark-gap switch batched-fabricated with PCB technology for medium-and low-voltage pulse power systems

Triggered spark-gap switch is a popular discharge switch for pulse power systems. Previous studies have focused on planarizing this switch using thin film techniques in order to meet the requirements of compact size in the systems. Such switches are one-shot due to electrodes being too thin to sufficiently resist spark-erosion. Additionally, these switches did not employ any structures in securing internal gas composition, resulting in inconsistent performance under harsh atmospheres. In this work, a novel planar triggered spark-gap switch (PTS) with a hermetically sealed cavity was batched-prepared with printed circuit board (PCB) technology, to achieve reusability with low cost. The proposed PTS was inspected by micro-computed tomography to ensure PCB techniques meet the requirements of machining precision. The results from electrical experiments demonstrated that PCB PTS were consistent and reusable with lifespan over 20 times. The calculated switch voltage and circuit current were consistent with those derived from real-world measurements. Finally, PCB PTS was used to introduce hexanitrostilbene (HNS) pellets in a pulse power system to verify its performance.     

硅藻精土和生物脱氮组合工艺的城市污水资源化研究

在硅藻精土处理城市污水之后,再增加一个生物脱氮工艺,把二者结合起来处理污水,处理效果好,运行成本低,处理后的水可以作为中水回用,满足了污水资源化的需求。     

OPCW第18次水平考试土壤样品的GC—MS分析

报道了OPCW第18次水平考试样品的处理方法和GC-MS分析检测结果．在土壤样品申检出3个化武公约核查化合物,检测结果与配样清单完全一致,并解释了目标化合物的质谱碎片．     

民用企业进入国防科技领域的“信息孤岛”问题研究

民口企业参与军品的科研生产是武器装备发展的大势所趋,在民进军过程中仍有很多的实际问题需要解决。文章从信息沟通角度,研究了当前民口、军口间信息渠道不畅、难以交互的问题,并从宏观和微观层面上分析问题的根源,找出解决问题的思路。     

体系对抗仿真建模中的网络模型与交互模型相关问题研究

从信息化战争体系对抗模拟仿真的EBI模型体系出发,界定了体系对抗的网络模型和交互模型的概念,探讨了网络模型和交互模型的建模内容,分析了利用网络模型和交互模型表现体系对抗复杂性的途径,并在探讨体系对抗仿真网络模型和交互模型的关系和相互作用的基础上,提出了一种基于ABM建模方法构建体系对抗网络模型和交互模型的研究设想.     

直接免疫PCR方法的建立

免疫PCR基本原理与ELISA相似,即用一段可扩增的DNA分子代替ELISA中酶放大检出信号,建立了直接免疫PCR的检测蓖麻毒素技术,实验结果表明,其灵敏度达1pg／ml,比ELISA方法灵敏度高10^3倍.     

剪切机最佳剪切间隙的研究

本文在分析剪切机剪切过程的基础上,建立了剪切过程的物理、数学模型,并导出了剪切机最佳剪切间隙的理论表达式。工程实践证明,该理论表达式是合理、有效的。     

SG高压水室在典型循环工况下的低周疲劳评估

本文应用有限元分析了ＳＧ高压水室在典型负荷波动下的热应力,根据所计算出的峰值应力循环幅,引用低周疲劳设计曲线,对结构的低周疲劳用ＡＳＭＥ规范进行了评估,发现ＳＧ在典型载荷循环下不产生显著的低周疲劳损伤。     

关于自适应滤波技术的一些思考

本文研究工程实践中应用Ｋａｌｍａｎ滤波时出现的滤波异常现象。文中从滤波异常的检测出发,由此构成动力学噪声方差阵的自适应估计。对于常用的衰减记忆滤波,提出了衰减因子的自适应确定方法,对于未知的动力学噪声和观测噪声的方差阵,运用Ｂａｙｅｓ－ＭＬ估计方法给出了递推估算方案。对于构造自适应滤波的技术途径,提出了一些看法。