Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

On the (S-1, S) inventory model under compound poisson demands and i.i.d. unit resupply times

We analyze an (S-1, S) inventory model with compound Poisson demands. Resupply times for individual units are independent and identically distributed. Such a model can also be characterized as an M^X/G/∞ queue. We derive expressions of performance measure such as the steady-state distribution and the expectation of the number of backlogged units. In addition, numerical examples are included to reflect the effects of i.i.d. unit resupply times. © 1996 John Wiley & Sons, Inc.     

舰艇编队防空火力区划分方法研究

通过分析水面舰艇编队内各平台防空火力区,建立了编队防空火力区模型,提出并对比了两种不同的防空火力重叠区划分方法。对基本队形和复杂队形的编队进行了防空火力区划分仿真,仿真结果验证了火力区划分方法的有效性,可为编队协同作战指挥决策提供基础。     

模糊需求下保障设施选址-路径模型及算法

针对装备保障过程中被保障单位需求量不确定的问题,在详细分析保障设施选址-路径相关因素的基础上,利用三角模糊数对需求量进行标定。通过运用模糊综合评价与群决策思想确定保障设施备选址点权重,构建时间满意度函数与惩罚成本函数,建立模糊需求下带有时间窗及容量限制的选址-路径模型,并设计了基于聚类分析与蚁群算法的混合启发式求解算法。通过算例分析验证了模型的正确性及算法的有效性。     

制导航空子母炸弹高速抛撒分离数值仿真

制导航空子母炸弹在跨音速抛撒子弹药过程中,子弹药与母弹的分离伴随着复杂的流场和激波干扰,该过程中不仅存在着激波与激波的相互碰撞、部分激波的多次反射,而且由于受到多体运动的相互作用,其气流方向也发生变化,形成了变化复杂的压力、速度分布区域。采用数值模拟的方法对制导航空子母炸弹子弹药高速抛撒分离过程进行了数值仿真分析,应用嵌套网格技术,耦合多体动力学方程以及 N－S 方程求解子母炸弹高速分离过程,为工程设计、研究提供理论指导与计算依据。     

基于VR与PNN相结合的机电液控制系统故障诊断方法

针对大型复杂机电液控制系统故障诊断中存在的数学模型获取困难、历史故障数据匮乏问题,提出了一种将虚拟样机与概率神经网络相结合的故障诊断混合方法。建立系统的虚拟样机,并对其可信性进行校核与验证。在此基础上进行大量随机性故障植入与仿真实验,获取故障仿真数据。经过特征提取与概率神经网络模式识别训练,形成用于诊断的知识库,从而实现故障诊断。以操舵系统作为研究案例,得到了较高的故障检测和隔离精度与较低的虚警及漏警率,验证了该方法的可行性,为大型复杂机电液控制系统故障诊断提供新的思路。     

地理信息系统专业实践教学体系研究

实践教学是GIS专业教学至关重要的环节。结合GIS知识体系结构、专业特点和社会需求,讨论了GIS专业实践教学体系的基本框架及其依托。     

考虑运行故障的工程安全设施使用检查可用度模型

使用检查是发现工程安全设施系统隐蔽功能故障的有效措施。在考虑检查期间可能发生运行故障的前提下,建立了基于使用检查策略的系统可用度模型。应用该模型对应急柴油发电机的使用检查过程进行可用度分析,确定了其最优检查问隔期和给定可用度条件下的检查间隔期区间;探讨了检查时间和维修时间对可用度的影响。研究表明,该模型对于工程安全设施系统的可用度分析是有效可行的,其结果能够为维修决策提供依据。     

一种基于数据仓库的通用OLAP数据接入构件的新型设计

为了解决异构数据源融合和数据仓库的迁移问题,结合数据仓库和构件技术的思想,提出了一种基于数据仓库的通用OLAP(online analysis process)数据接入构件的设计方案.该方案针对完成数据操作封装的数据接入构件进行了建模,并且针对这种模型设计了一个基于构件的OLAP通用数据接入原型系统,实现了OLAP界面展示工具和异构数据源的自由配对和无缝迁移.     

捷联式惯导系统动态误差特性研究

根据载体运动状态下捷联惯性导航系统 (SINS)的误差方程时变的特点 ,推导出捷联惯性导航系统动态误差模型 ,并对其在几种动态环境下的误差特性进行了仿真研究 ,结果表明 :与静态误差特性相比 ,捷联式惯导系统的动态误差特性发生了较大的变化。