Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

次声波技术与心理战应用

次声波是一种频率变化范围在10?4 Hz～20 Hz之间的声波,它具有穿透力强、传输距离远以及不易被吸收的特点,以此制造的次声波武器伤人但不毁物。近年来,随着高新技术的不断发展,次声波武器在心理战领域得到了广泛应用。本文首先对次声波技术及次声波武器的概念进行了简要介绍;其次,研究了次声波的生物学效应,分析了次声波频率、声压强度以及作用时间与生物学效应的关系,发现三种次声波的作用参数与生物学效应之间的关系虽然错综复杂,但也有一定规律可循;最后,提出了次声波武器在心理战的三个潜在应用前景,即利用次声波穿透力强的特点发展对掩体人员作战的心理战装备、利用次声波的生物学效应发展反恐作战的心理战装备以及利用次声波的生理致伤机理发展心理战防护装备。     

现有军用光电装备快速智能化手段

近年来,人工智能技术在图像处理领域取得了突破性进展,使得目标识别和目标检测算法的性能得到大幅提高,也为军用光电装备智能化创造了有利条件。本文从算法、数据和计算能力等人工智能三要素入手,分析了快速实现军用光电装备智能化的有效途径及过程中可能面临的问题,指出:现有的技术理论基本满足装备升级需求,智能化过程中还应重点加强实时性算法的研究,提早对专用数据集的收集整理进行布局完善,采用低功耗高性能边缘计算设备为装备计算能力水平提升提供支撑等。同时,在工程化过程中仍存在部分实际问题,需根据装备进行个性化设计,以解决理论与应用之间的差距。最后,建议重点加强国产化水平与能力的提高,以实现关键技术自主可控。     

几种UWB-SAR窄带干扰抑制方法的分析和比较

SAR(Synthetic Aperture Radar)信号处理窄带干扰抑制技术是SAR抗干扰技术的重要内容。对3种UWB-SAR(Ultra-W ideBand Synthetic Aperture Radar)窄带干扰抑制方法———陷波滤波法、AR模型参数化干扰抑制法以及小波包分析自适应干扰抑制法进行了分析,利用自行开发的成像软件,对SAR理想点目标和实录数据进行干扰抑制仿真实验,从定性和定量的角度对3种方法的干扰抑制效果作了比较。     

破片模拟弹侵彻钢板的有限元分析

根据破片模拟弹侵彻钢板的实验研究,采用MSC.Dytran对破片模拟弹侵彻钢板的侵彻过程、侵彻特性、钢板的破坏模式以及弹体的侵彻速度、靶板的侵彻阻力进行了有限元分析,并将分析结果与实验结果进行了比较.分析结果表明,破片模拟弹冲击钢装甲的侵彻过程可大致分为初始接触、弹体侵入、剪切冲塞和穿甲破坏4个阶段.有限元分析的破片模拟弹侵彻特性及靶板破坏模式与实验观测结果有较好的一致性,在靶板破口的正面,与弹体平面凸缘两端接触的部分,变形以剪切为主,而与切削面接触的部分,以挤压变形为主;靶板破口背面为剪切冲塞破坏;有限元模拟的弹体剩余速度与实验结果吻合较好,弹体侵彻过程中弹靶作用界面的速度和侵彻速度近似呈线性变化.有限元分析结果还表明,采用适当的模型,有限元法能较好地模拟破片模拟弹侵彻钢板的侵彻过程、侵彻特性以及钢板的破坏模式.     

MILITARY EXPENDITURE AND ECONOMIC GROWTH IN DEVELOPING COUNTRIES: EVIDENCE FROM SYSTEM GMM ESTIMATES

The effect of military expenditure on economic growth in developing countries has been investigated by many empirical literatures. However, there is little consensus of that effect and the diversity seems to come from the use of different models and different estimators. This article applies the Augmented Solow Growth Model to examine the influence of military expenditure on economic growth for 35 developing countries over the period of 1975–2009. By using the system Generalized Method of Moments (GMM) estimators, empirical results indicate that defence has a negative and significant effect on economic growth in the sample countries.     

无目标初始信息情况下舰载直升机搜索优化

根据水面舰艇编队反舰作战中舰载直升机所担负的搜索任务,基于无目标初始信息情况下的搜索问题,选取搜索面积、搜索时间和搜索距离3个指标,建立了搜索优化模型.通过仿真计算,得出了无目标初始信息情况下舰载直升机反舰作战中具体的搜索方法.其结论对于最大限度发挥现有装备的作战效能有一定的现实指导意义.     

基于区间数理论的空战目标威胁评估

针对空战目标威胁评估问题,提出了一种新的基于区间数理论的评估方法。在分析了现有的目标威胁评估方法中距离威胁模型存在不足的基础上,提出了改进的距离威胁模型。给出了区间数特征向量法求解威胁指标权重的计算步骤,建立了基于区间数理论的空战目标威胁评估的数学模型。最后给出了仿真算例,仿真结果表明该方法是合理和有效的。