Dielectric constant predictions for energetic materials using quantum calculations

The dielectric constant (DC) is one of the key properties for detection of threat materials such as Improvised Explosive Devices (IEDs). In the present paper, the density functional theory (DFT) as well as ab-initio approaches are used to explore effective methods to predict dielectric constants of a series of 12 energetic materials (EMs) for which experimental data needed to experimentally determine the dielectric constant (refractive indices) are available. These include military grades energetic materials, nitro and peroxide compounds, and the widely used nitroglycerin. Ab-initio and DFT calculations are conducted. In order to calculate dielectric constant values of materials, potential DFT functional combined with basis sets are considered for testing. Accuracy of the calculations are compared to experimental data listed in the scientific literature, and time required for calculations are both evaluated and discussed. The best functional/basis set combinations among those tested are CAM-B3LYP and AUG-cc-pVDZm, which provide great results, with accuracy deviations below 5% when calculated results are compared to experimental data.     

Technical note: Characterization of binomial semivalues through delegation games

Semivalues are allocation rules for cooperative games that assign to each player in a given game a weighted sum of his marginal contributions to all coalitions he belongs to, where the weighting coefficients depend only on the coalition size. Binomial semivalues are a special class of semivalues whose weighting coefficients are obtained by means of a unique parameter. In particular, the Banzhaf value is a binomial semivalue. In this article, we provide an axiomatic characterization for each binomial semivalue. © 2007 Wiley Periodicals, Inc. Naval Research Logistics, 2007     

Domestic factors in the making of defense policy: The case of the Netherlands

The importance of domestic factors in explaining the foreign-policy process can, today, not be overlooked. It has been suggested that four sets of variables play an important role in determining the chances for domestic groups to exercise influence on this process: external autonomy, internal (domestic) consensus, the availability of time and the presence or absence of conditions of influence such as legitimacy, resources and access. From a series of case studies on foreign policymaking in the Netherlands two were selected for this article: the introduction of the neutron warheads and the deployment of cruise missiles. Both were very controversial in the Netherlands. They show that under favourable conditions, i.e. divisions within the ruling Christian Democratic Party, committed and well-organized domestic groups which are capable of keeping public opinion mobilized over time can have an important and even decisive influence on the outcome of the making of defence and foreign policy. Domestic conditions being what they are, the making of defense policy in the Netherlands is bound to remain a delicate balancing act for any Dutch government.     

Book reviews

Export or Die: Britain's Defence Trade with Iran and Iraq. by Davina Miller, London: Cassell, 1996, ISBN 0-304-33852-4 (hbk), £40.00, 04-33853-2 (pbk), £11.99.

The Storm Passed By: Ireland and the Battle of the Atlantic, 1940-1941. by Trevor Allen, Dublin: Irish Academic Press, 1996, ISBN 0-7165-2616-6, (hbk) £17.50.

Arms Control Toward the 21st Century. by Jeffrey A. Larsen and Greqory J. Rattray (eds). Boulder: Lynne Rienner, 1996.

Asia-Pacific Security, Less Uncertainty, New Opportunities. Edited by Gary Klintworth. Melbourne: Addison Wesley Longman, 1996, ISBN 0-582-80321-7, £24.99.

Masters of War, Military Dissent and Politics in the Vietnam Era. by Robert Buzzanco, Cambridge: Cambridge University Press, 1996, ISBN 0-521-48046-9 (hbk), £29.95

Controlling the Arms Trade: the West Versus the Rest. By Paul Cornish, London: Bowerdean Publishing Co., 1996, ISBN 0-906097-44-4 (pbk), £9.99.

Secret Agencies: US Intelligence in a Hostile World. by Loch K. Johnson, London: Yale University Press, 1997, ISBN 0-300-06611-2 (hbk), £22.50.     

Optimal arrangement of systems

To location L_i we are to allocate a “generator” and n_i “machines” for i = 1, …,k, where n₁ … n₁ ≧ … ≧ n_k. Although the generators and machines function independently of one another, a machine is operable only if it and the generator at its location are functioning. The problem we consider is that of finding the arrangement or allocation optimizing the number of operable machines. We show that if the objective is to maximize the expected number of operable machines at some future time, then it is best to allocate the best generator and the n₁ best machines to location L₁, the second-best generator and the n₂-next-best machines to location L₂, etc. However, this arrangement is not always stochastically optimal. For the case of two generators we give a necessary and sufficient condition that this arrangement is stochastically best, and illustrate the result with several examples.     

A periodic maintenance model with used equipment and random minimal repair

The maintenance strategy considered in this article is in the class of block replacement policies. The working unit is replaced by new ones at instants T,2T,3T,… independently of the age and state of the unit. If a failure occurs between these instants, the random repair cost is evaluated. If it is smaller than a predetermined control limit then a minimal repair is carried out. Otherwise the unit is replaced by a used unit. The performance of this maintenance strategy is evaluated in terms of average total cost per time unit over an infinite time span. The mathematical model is defined and several analytical results are obtained. A computer program has been written, which solves the mathematical problem, and some examples are given for the cases where the underlying life distribution is gamma, Weibull or truncated normal.     

Striking a deal on the F-35: multinational politics and US defence acquisition

Why does joint defence production of advanced weapons systems, which appears like a logical choice at first, become harder for both the primary production state and its allies to manage and justify as the acquisition process runs its course? To answer this question, we analyze the multinational politics of the F-35 JSF with a focus on how secondary states who have bought into the program are affected by domestic politics within the primary production state. We find that US congressional and bureaucratic politics, cuts to US defence spending, and a desire to retain tight control over the program has locked allies into a program with which they have little leverage. Potentially losing the ability to fight along side the US if they don’t follow through, coupled with inter-Alliance pressures, leaves secondary states who are involved with the F-35 program, vulnerable to the whims of US domestic politics.