Light weight HTPB-clay nanocomposites(HCN)with enhanced ablation performance as inhibition materials for composite propellant

In the present study,organically modified Montmorillonite clay with polar moiety,the Cloisite 30B,is used for preparation of Hydroxyl terminated polybutadiene(HTPB)-clay nanocomposites(HCN)by dispersion of nanoclay in polymer matrix under high shear mixing.The nanocomposites thus prepared are evaluated in composite propellants as inhibitor material for their functional utility.Several inhibition formulations containing 5 wt％-15 wt％of nanoclay,with or without the conventional filler Sb2O3,were prepared.All these formulations were evaluated for their physical,mechanical,thermal,and ablative properties.Ablation rate and density of the compositions containing Cloisite 30B is around 23％and 5％lower respectively in comparison of the base composition.Strain capability of these compositions is twofold higher than that of base composition.These compositions have also been evaluated for their smoke generation tendency by measuring infra red(IR)attenuation in the wavelength range 1.3 μm-5.6 μm and 8 μm-13 μm and thereby compared with the base composition.The corresponding results confirmed that the compositions containing Cloisite 30B as filler have much lower IR attenuation than compositions with conventional filler,Sb2O3.Replacement of 5％Sb2O3 by nanoclay showed 8％reduction in IR attenuation rate which further reduced to 16％on replacement of 15％of Sb2O3.Interfacial bonding of HCN based inhibitors is also comparable or even better than conventional inhibitors.Precisely,the nanoclay composites with Cloisite 30B as filler exhibit all desirable properties of an inhibitor.     

Vapor-phase decomposition of dimethyl methylphosphonate (DMMP), a sarin surrogate,in presence of metal oxides

Chemical warfare agents (CWA) are stockpiled in large quantities across the globe. Agents stored in inaccessible facilities need to be destroyed rapidly without dispersing the compounds to surrounding areas. Metal-based energetic formulations are used in such prompt defeat applications to rapidly decompose the CWA by generating a high temperature environment. An alternate, and possibly a more effective decomposition pathway could be provided by chemicidal action of aerosolized condensed combustion products, which typically consist of metal oxides. Toxic fumes that escape the high tem-perature blast zone can be neutralized by smoke generated during combustion, depending on the par-ticle size, surface characteristics, chemical properties, and concentration of this smoke. This review considers relevant experimental and modeling studies quantifying decomposition of CWA comprising organophosphorus compounds and their surrogates on the surface of various metal oxides. Dimethyl methylphosphonate (DMMP), a sarine surrogate, was used most commonly for such experiments. Many reported efforts focused on the mechanisms of adsorption of DMMP to various metal oxides and initial reaction steps cleaving various bonds from the chemisorbed molecules. For selected oxides, these ex-periments were supported by quantum-mechanical calculations. In other studies, the capacity of oxide surfaces to adsorb and decompose DMMP was quantified. In most cases, porous catalysts were used although limited experimental data are available for aerosolized nonporous oxide particles. The reported experimental data applicable to scenarios involving prompt decomposition of CWA are summarized. It is noted that information is lacking describing respective heterogeneous reaction kinetics. Preliminary estimates of aerosolized smoke particle concentrations required to destroy CWA are made considering gas phase diffusion rates and reported values of the oxide capacity to decompose CWA or their surrogates.     

Modeling the operation of multireservoir systems using decomposition and stochastic dynamic programming

Stochastic dynamic programming models are attractive for multireservoir control problems because they allow non‐linear features to be incorporated and changes in hydrological conditions to be modeled as Markov processes. However, with the exception of the simplest cases, these models are computationally intractable because of the high dimension of the state and action spaces involved. This paper proposes a new method of determining an operating policy for a multireservoir control problem that uses stochastic dynamic programming, but is practical for systems with many reservoirs. Decomposition is first used to reduce the problem to a number of independent subproblems. Each subproblem is formulated as a low‐dimensional stochastic dynamic program and solved to determine the operating policy for one of the reservoirs in the system. © 2006 Wiley Periodicals, Inc. Naval Research Logistics, 2006     

Minimizing makespan on a single batch processing machine with nonidentical job sizes

We deal with the problem of minimizing makespan on a single batch processing machine. In this problem, each job has both processing time and size (capacity requirement). The batch processing machine can process a number of jobs simultaneously as long as the total size of these jobs being processed does not exceed the machine capacity. The processing time of a batch is just the processing time of the longest job in the batch. An approximation algorithm with worst‐case ratio 3/2 is given for the version where the processing times of large jobs (with sizes greater than 1/2) are not less than those of small jobs (with sizes not greater than 1/2). This result is the best possible unless P = NP. For the general case, we propose an approximation algorithm with worst‐case ratio 7/4. A number of heuristics by Uzosy are also analyzed and compared. © 2001 John Wiley & Sons, Inc. Naval Research Logistics 48: 226–240, 2001     

Opportunistic retooling of a flexible machine subject to failure

A set of jobs can be processed without interruption by a flexible machine only if the set of tools required by all jobs can be loaded in the tool magazine. However, in practice the total number of tools required by a job set would exceed the tool magazine capacity. In such situations, the job set has to be carefully partitioned at the start of the production run such that each partition can be processed without interruption. During the production run, if there are unscheduled machine downtimes due to machine failure, this provides an additional opportunity to optimally retool the magazine for a smaller job set consisting of just the unprocessed jobs. In this paper, we study job sequencing rules that allow us to minimize the total expected cost of machine down time due to machine failures and magazine retooling, assuming a dynamic re‐sequencing of the unprocessed jobs after each machine failure. Using these rules, we develop a branch‐and‐bound heuristic that allows us to solve problems of reasonable size. © 2001 John Wiley & Sons, Inc. Naval Research Logistics 48: 79–97, 2001     

Analysis of a new vehicle scheduling and location problem

We consider a container terminal discharging containers from a ship and locating them in the terminal yard. Each container has a number of potential locations in the yard where it can be stored. Containers are moved from the ship to the yard using a fleet of vehicles, each of which can carry one container at a time. The problem is to assign each container to a yard location and dispatch vehicles to the containers so as to minimize the time it takes to download all the containers from the ship. We show that the problem is NP‐hard and develop a heuristic algorithm based on formulating the problem as an assignment problem. The effectiveness of the heuristic is analyzed from both worst‐case and computational points of view. © 2001 John Wiley & Sons, Inc. Naval Research Logistics 48: 363–385, 2001     

Learning and costs in airframe production: A multiple-output production function approach

This article examines the influence of both production rate and learning on airframe program costs. A dynamic multiple-output production model is developed and is used to observe the cost impact of changes in production rate and learning. Several simulations are performed to demonstrate the sensitivity of the optimal time path of cost to changes in the model parameters. The model is applied by estimating parameters from the F102 airframe program.     

On nonpreemptive strategies in stochastic scheduling

It is shown that there is an optimal strategy for a class of stochastic scheduling problems which is nonpreemptive. The results which yield this conclusion are generalizations of previous ones due to Glazebrook and Gittins. These new results also lead to an evaluation of the performance of nonpreemptive strategies in a large class of problems of practical interest.     

Inventory models with a mixture of backorders and lost sales

This article presents several single-echelon, single-item, static demand inventory models for situations in which, during the stockout period, a fraction b of the demand is backordered and the remaining fraction 1 - b is lost forever. Both deterministic and stochastic demand are considered. although the case of stochastic demand is treated heuristically. In each situation, a mathematical model representing the average annual cost of operating the inventory system is developed. and an optimum operating policy derived. At the extremes b=1 and b=0 the models presented reduce to the usual backorders and lost sales cases, respectively.