Gas metal arc welding of high nitrogen stainless steel with Ar-N2-O2 ternary shielding gas

High nitrogen stainless steel with nitrogen content of 0.75％was welded by gas metal arc welding with Ar—N2-O2 ternary shielding gas. The effect of the ternary shielding gas on the retention and improvement of nitrogen content in the weld was identified. Surfacing test was conducted first to compare the ability of O2 and CO2 in prompting nitrogen dissolution. The nitrogen content of the surfacing metal with O2 is slightly higher than CO2. And then Ar—N2-O2 shielding gas was applied to weld high nitrogen stainless steel. After using N2-containing shielding gas, the nitrogen content of the weld was improved by 0.1 wt％. As N2 continued to increase, the increment of nitrogen content was not obvious, but the ferrite decreased from the top to the bottom. When the proportion of N2 reached 20％, a full austenitic weld was obtained and the tensile strength was improved by 8.7％. Combined with the results of surfacing test and welding test, it is concluded that the main effect of N2 is to inhibit the escape of nitrogen and suppress the ni-trogen diffusion from bottom to the top in the molten pool.     

Force chains based mesoscale simulation on the dynamic response of Al-PTFE granular composites

Force chains based mesoscale simulation is conducted to investigate the response behavior of aluminum-polytetrafluoroethylene (Al-PTFE) granular composites under a low-velocity impact. A two-dimensional model followed the randomly normal distribution of real Al particles size is developed. The dynamic compressive process of Al-PTFE composites with varied Al mass fraction is simulated and validated against the experiments. The results indicate that, force chains behavior governed by the number and the size of agglomerated Al particles, significantly affects the impact response of the material. The failure mode of the material evolves from shear failure of matrix to debonding failure of particles with increasing density. A high crack area of the material is critical mechanism to arouse the initiation re-action. The damage maintained by force chains during large plastic strain builds up more local stresses concentration to enhance a possible reaction performance. In addition, simulation is performed with identical mass fraction but various Al size distribution to explore the effects of size centralization and dispersion on the mechanical properties of materials. It is found that smaller sized Al particle of com-posites are more preferred than its bulky material in ultimate strength. Increasing dispersed degree is facilitated to create stable force chains in samples with comparable particle number. The simulation studies provide further insights into the plastic deformation, failure mechanism, and possible energy release capacity for Al-PTFE composites, which is helpful for further design and application of reactive materials.     

A reusable planar triggered spark-gap switch batched-fabricated with PCB technology for medium-and low-voltage pulse power systems

Triggered spark-gap switch is a popular discharge switch for pulse power systems. Previous studies have focused on planarizing this switch using thin film techniques in order to meet the requirements of compact size in the systems. Such switches are one-shot due to electrodes being too thin to sufficiently resist spark-erosion. Additionally, these switches did not employ any structures in securing internal gas composition, resulting in inconsistent performance under harsh atmospheres. In this work, a novel planar triggered spark-gap switch (PTS) with a hermetically sealed cavity was batched-prepared with printed circuit board (PCB) technology, to achieve reusability with low cost. The proposed PTS was inspected by micro-computed tomography to ensure PCB techniques meet the requirements of machining precision. The results from electrical experiments demonstrated that PCB PTS were consistent and reusable with lifespan over 20 times. The calculated switch voltage and circuit current were consistent with those derived from real-world measurements. Finally, PCB PTS was used to introduce hexanitrostilbene (HNS) pellets in a pulse power system to verify its performance.     

Influences of different crossing types on dynamic response of underground cavern subjected to ground shock

An intersecting cavern is a common structural form used in underground engineering, and its safety and stability performance directly control the service performance of the whole project. The dynamic re-sponses of the three kinds of crossing type (+-shaped, T-shaped, L-shaped) caverns subjected to ground shock were studied by numerical simulation. The velocity plus force mode boundary setting method was proposed in the coupled static and dynamic analysis of a deep underground cavern. The results show that, among the three types of crossing caverns, the+-shaped cavern is the most significantly affected by the dynamic action, followed by T-shaped, and then L-shaped caverns. The vault settlement, straight wall deformation, vault peak particle velocity, effective plastic strain of surrounding rock, and maximum principal stress and strain at the bottom of the lining of the straight wall increase with the increase of cavern span. The vault settlement, straight wall deformation, effective plastic strain of surrounding rock, and the maximum principal stress and strain at the bottom of lining to the straight wall decrease with the increase of lateral pressure coefficient, and the peak particle velocity at the vault increases. The variation is small compared with the change of cavern span. The influence range of the underground cavern intersection is two cavern diameters from the intersection centre. The bottom of the straight wall at the intersection is the weak part. It is suggested to thicken the support locally to improve the stability of the cavern.     

Effect of metal powders on explosion of fuel-air explosives with delayed secondary igniters

In order to improve the energy level of fuel air explosive(FAE) with delayed secondary igniters, high energetic metal powders were added to liquid fuels mainly composed of ether and isopropyl nitrate. Metal powders' explosive properties and reaction mechanisms in FAE were studied by high-speed video, pressure test system, and infrared thermal imager. The results show that compared with pure liquid fuels, the shock wave overpressure, maximum surface fireball temperature and high temperature duration of the mixture were significantly increased after adding high energetic metal powder. The overpressure values of the liquid-solid mixture at all measuring points were higher than that of the pure liquid fuels. And the maximum temperature of the fireball was up to 1700 ℃, which was higher than that of the pure liquid fuels. After replacing 30％of aluminum powder with boron or magnesium hydride, the shock wave pressure of the mixture was further increased. The high heat of combustion of boron and the hydrogen released by magnesium hydride could effectively increase the blast effect of the mixture. The improvement of the explosion performance of boron was better than magnesium hydride. It shows that adding high energetic metal powder to liquid fuels can effectively improve the explosion performance of FAE.     

Research on fuze microswitch based on corona discharge effect

Abnormal voltages such as electrostatic, constant current, and strong electromagnetic signals can erro-neously trigger operation of MEMS pyrotechnics and control systems in a fuze, which may result in casualties. This study designs a solid-state micro-scale switch by combining the corona gas discharge theory of asymmetric electric fields and Peek's Law. The MEMS switch can be transferred from "off" to"on" through the gas breakdown between the corona electrodes. In the model, one of the two electrodes is spherical and the other flat, so a non-uniform electric field is formed around the electrodes. The theoretical work is as follows. First, the relation among the radius of curvature of the spherical electrode, the discharge gap, and the air breakdown voltage is obtained; to meet the low voltage (30-60 V) required to drive the MEMS switch, the radius of curvature of the spherical electrode needs to be 10-50 μm and the discharge gap between the two electrodes needs to be 9-11 μm. Second, the optimal ratio ε is introduced to parameterize the model. Finally, the corona discharge structural parameters are determined by comparing the theoretical and electric field simulation results. The switch is then fabricated via MEMS processing. A hardware test platform is built and the performing chip tested. It is found that when the electrode gap is 9 μm, the electrostatic voltage is at least 37.3 V, with an error of 2.6% between the actual and theoretical air breakdown voltages. When the electrode gap is 11 μm, the electrostatic voltage is at least 42.3 V, with an error of 10.5% between the actual and theoretical air breakdown voltages. Both cases meet the design requirements.     

Numerical and experimental study on the response characteristics of warhead in the fast cook-off process

The response characteristics of the warhead under thermal stimuli conditions are important to the safety improvement. The goal of this study is to obtain data on the warhead in the fast cook-off process. In this paper, a numerical calculation method is proposed, whose reliability is supported by comparison with experimental results. Through the numerical calculation, the temperature distribution, temperature change, and ignition time are acquired. The numerical results show that the ignition time is 76 s after the warhead started to burn and that the maximum temperature of the explosive's outer surface is 238.3 C at the ignition time. The fast cook-off experiment of the warhead is implemented so as to get the flame temperature and reaction grades that are not available through numerical calculation. The experimental results show that the overpressure fails to reach the preset minimum value which is equivalent to 6 kg of TNT and that the reaction grade is deflagration. The research results have reference value for the design of the warhead and the reduction of detonation risks.     

Thermodynamics and performance of Al/CuO nanothermite with different storage time

The storage stability of energetic materials is important for its application. Here, the storage stability of Al/CuO nanothermite, which was prepared by electrospray method and stored with different storage time, was systematically researched. The activation energy of Al/CuO nanothermite was calculated by differential scanning calorimetry (DSC). The ignition temperature and the curve pressure history of Al/CuO nanothermite was measured using ignition temperature measuring device and constant-volume pressurization tests, respectively. Further, the thermites were characterized by X-ray Diffractometer (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM) and Transmission electron microscopy (TEM). The results show that the morphology of the thermites did not change significantly. The activation energy was decreased from 254.1 kJ/mol to 181.8 kJ/mol after storage for 13 months. When stored for 0, 7 and 13 months, the peak pressures of Al/CuO nanothermite were 685.8 kPa, 626.3 kPa and 625.5 kPa, respectively. In addition to the ignition temperature, it was 775 ℃, 739 ℃ and 754 ℃, respectively. This result indicated that the ignition and combustion properties of Al/CuO nano-thermite are obviously reduced when stored for a long time, at room temperature.     

Hazard evaluation of ignition sensitivity and explosion severity for three typical MH2 (M＝Mg,Ti, Zr) of energetic materials

MgH2, TiH2, and ZrH2 are three typical metal hydrides that have been gradually applied to composite explosives and propellants as additives in recent years. To evaluate ignition sensitivity and explosion severity, the Hartmann device and spherical pressure vessel were used to test ignition energy and ex-plosion pressure, respectively. The results showed that the ignition sensitivity of ZrH2, TiH2 and MgH2 gradually increased. When the concentration of MgH2 is 83.0 g/m3 in Hartmann device, the ignition energy attained a minimum of 10.0 mJ. The explosion pressure of MgH2 were 1.44 times and 1.76 times that of TiH2 and ZrH2, respectively, and the explosion pressure rising rate were 3.97 times and 9.96 times that of TiH2 and ZrH2, respectively, through the spherical pressure vessel. It indicated that the reaction reactivity and reaction rate of MgH2 were higher than that of TiH2 and ZrH2. In addition, to conduct in-depth theoretical analysis of ignition sensitivity and explosion severity, gas production and combus-tion heat per unit mass of ZrH2, TiH2 and MgH2 were tested by mercury manometer and oxygen bomb calorimetry. The experimental results revealed that MgH2 had a relatively high gas production per unit mass (5.15 mL/g), while TiH2 and ZrH2 both had a gas production of less than 2.0 mL/g. Their thermal stability gradually increased, leading to a gradual increase in ignition energy. Furthermore, compared with theoretical combustion heat, the combustion ratio of MgH2, TiH2 and ZrH2 was more than 96.0%, with combustion heat value of 29.96, 20.94 and 12.22 MJ/kg, respectively, which was consistent with the explosion pressure and explosion severity test results.