Preparation and characterization of HMX/EVA/hBNNSs micro-composites with improved thermal stability and reduced sensitivity

Hexagonal boron nitride nanosheets(HBNNSs)have huge potential in the field of coating materials owing to their remarkable chemical stability,mechanical strength and thermal conductivity.Thin-layer hBNNSs were obtained by a liquid-phase exfoliation of h-BN powders and incorporated into EVA coatings for improving the safety performance of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX).HBNNSs and ethylene-vinyl acetate copolymer(EVA)were introduced to HMX by a solvent-slurry process.For com-parison,the HMX/EVA and HMX/EVA/graphene(HMX/EVA/G)composites were also prepared by a similar process.The morphology,crystal form,surface element distribution,thermal decomposition property and impact sensitivity of HMX/EVA/hBNNSs composites were contrastively investigated.Results showed that as prepared HMX/EVA/hBNNSs composites were well coated with hBNNSs and EVA,and exhibited better thermal stability and lower impact sensitivity than that of HMX/EVA and HMX/EVA/G composites,suggesting superior performance of desensitization of hBNNSs in explosives.     

Hypersonic impact flash characteristics of a long-rod projectile collision with a thin plate target

Impact flash occurs when objects collide at supersonic speeds and can be used for real-time damage assessment when weapons rely on kinetic energy to destroy targets.However,the mechanism of impact flash remains unclear.A series of impact flash experiments of flat-head long-rod projectiles impacting thin target plates were performed with a two-stage light gas gun.The impact flash spectra for 6061 aluminum at 1.3-3.2 km/s collision speeds were recorded with a high-speed camera,a photoelectric sensor,and a time-resolved spectrometer.The intensity of the impact flash exhibited a pulse charac-teristic with time.The intensity(I)increased with impact velocity(V0)according to I∝Vn0,where n = 4.41 for V0 ＞ 2 km/s.However,for V0 ＜ 2 km/s,n = 2.21,and the intense flash duration is an order of magnitude less than that of higher V0.When V0 ＞ 2 km/s,a continuous spectrum(thermal radiation background)was observed and increased in intensity with V0.However,for V0 ＜ 2 km/s,only atomic line spectra were detected.There was no aluminum spectral lines for V0 ＜ 2 km/s,which indicated that it had not been vaporized.The initial intense flash was emission from excited and ionized ambient gases near the impact surface,and had little relationship with shock temperature rise,indicating a new mechanism of impact flash.     

Cooperative interception with fast multiple model adaptive estimation

For the case that two pursuers intercept an evasive target, the cooperative strategies and state estimation methods taken by pursuers can seriously affect the guidance accuracy for the target, which performs a bang For the case that two pursuers intercept an evasive target, the cooperative strategies and state estimation methods taken by pursuers can seriously affect the guidance accuracy for the target, which performs a bang-bang evasive maneuver with a random switching time. Combined Fast multiple model adaptive estimation (Fast MMAE) algorithm, the cooperative guidance law takes detection configuration affecting the accuracy of interception into consideration. Introduced the detection error model related to the line-of-sight (LOS) separation angle of two interceptors, an optimal cooperative guidance law solving the optimization problem is designed to modulate the LOS separation angle to reduce the estimation error and improve the interception performance. Due to the uncertainty of the target bang-bang maneuver switching time and the effective fitting of its multi-modal motion, Fast MMAE is introduced to identify its maneuver switching time and estimate the acceleration of the target to track and intercept the target accurately. The designed cooperative optimal guidance law with Fast MMAE has better estimation ability and interception performance than the traditional guidance law and estimation method via Monte Carlo simulation.     

Insensitive energetic microspheres DAAF/RDX fabricated by facile molecular self-assembly

Insensitive energetic materials are promising in the defense weapons field. However, energetic materials still suffer from great challenges and the concern about their safety limits their utilization. In this work, insensitive energetic explosive 3,3′-diamino-4,4′-azoxyfurazan/hexahydro-1,3,5-trinitro-1,3,5-triazine (DAAF/RDX) microspheres were fabricated by self-assembly method. Rod-like DAAF/RDX was prepared by mechanical ball milling for comparison. DAAF/RDX composites with different mass ratios (90:10, 80:20, and 70:30) were obtained. The morphologies and structures of as-obtained DAAF/RDX composites were characterized by scanning electron microscopy (SEM), powder x-ray diffraction (PXRD) and fourier transform infrared spectroscopy (FT-IR). The results showed that DAAF/RDX microspheres exhibited regular shaped microspheres with sizes from 0.5 to 1.2 μm. There was no crystal transition during the modification process. The thermal properties of as-obtained materials were then evaluated by differential scanning calorimetry (DSC) and materials studio software. DAAF/RDX microspheres showed an advanced decomposition peak temperature compared with rod-like DAAF/RDX. The binding energy and peak temperature values at zero β_i (T_P0) of DAAF/RDX (90:10) increased by 36.77 kJ/mol, 1.6 °C, and 58.11 kJ/mol, 12.3 °C compared to DAAF/RDX (80:20) and DAAF/RDX (70:30), indicating the better thermal stability of DAAF/RDX (90:10). The characteristic drop height (H₅₀) of DAAF/RDX (higher than 100 cm) composites was higher than that of raw RDX (25 cm), suggesting significant improvements in mechanical safety. The preparation of DAAF/RDX microspheres is promising for the desensitization of RDX and useful for the formation of other materials and future wide applications.     

Mitigation effects on the reflected overpressure of blast shock with water surrounding an explosive in a confined space

The mitigation of blast shock with water has broad application prospects. Understanding the mitigation effects on the reflected overpressure of the explosion shock with water surrounding an explosive in a confined space is of great significance for military explosives safety applications. To estimate the effects of the parameters on the reflected overpressure of blasted shock wave, a series of experiments were carried out in confined containers with spherical explosives immersed in a certain thickness of water, and numerical simulations were conducted to explore the corresponding mechanisms. The results reveal that the reflected overpressure is abnormally aggravated at a small scaled distance. This aggravation is due to the high impulse of the bulk accelerated water shell converted from the explosion. With increasing scaled distance, the energy will be gradually dissipated. The mitigation effects will appear with the dispersed water phase front impacting at a larger scaled distance, except in the case of a dense water phase state. A critical scaled distance range of 0.7—0.8 m/kg1/3 for effective mitigation was found. It is suggested that the scaled distance of space walls should be larger than the critical value for a certain water-to-explosive weight ratio range (5—20).     

美军军法官制度简介

美军的政治性工作一般由两“师”完成,一个是牧师,另一个则是随军律师。而随军律师是处理法律问题的军官的泛称,主要指的就是军法官(JudgeAdvocate)和其领导下的法律助手、律师等。2003年的伊拉克战争中,美军约有103位军法官、62名法律专职助手深入战场。①他们在拘押战犯,发表对外声明,与英军建立联合军事司法系统和提供交战规则,促使官兵遵守国际战争法、军事行动法上起了相当大的作用。一、起源与概念在美军中没有法律战的明确词汇和概念,但是这并不意味着美军不运用法律武器以达到军事目的。相反,他们相当擅长和重视这一工作,而且已有…     

在柴油机放热曲线计算中两个关键问题的解决方法

对影响柴油机放热曲线精度计算的因素进行了讨论 ,并对影响放热率计算的主要问题如动态上止点修正、示功图光顺处理两个主要环节进行了分析研究 ,提出了解决方法 .     

辅助鞅下投资消费资产模型的一些基本性质

针对所给出的有交易费的资产模型,引入了资产折算函数,并利用辅助鞅和凸函数对偶方法,讨论了该模型下折算资产优化的性质.     

B介子的稀有非轻子衰变和CP破坏

在BS理论框架下,求解了ρ和K*的波函数,计算了B→ρ和B→K*跃迁的形状因子,进而计算出B介子衰变到2个轻介子稀有过程的分支比和CP破坏量.     

用能量法确定层状复合材料疲劳裂纹的扩展方向

含裂纹体疲劳寿命的预测,必须首先了解裂纹扩展路径的全过程,而在层状复合材料中,裂纹扩展的路径非常复杂,不仅可以拐弯,而且可以分叉.因此,首先提出一个简单、适用、统一的裂纹扩展方向的相对强度准则,即应变能释放率比值判据;然后,利用有效解决高梯度问题的数值方法--任意线法,对实测试件的关键时刻(例如,拐弯或进入界面),进行了数值分析;并对典型试件进行了疲劳断裂实验研究.3方面的结果,得到相互的验证.这种一致性,不仅初步证明了这一方法的正确性和适用性,而且为疲劳裂纹扩展全过程的解决,提供了必要的基础.