NiCl2-(CH2)6N4•HCI-H2O 三元体系组成及热致变色性能研究

本文用相平衡法研究了NiCl₂ -(CH₂)₆N₄?HCI-H₂O三元体系在30℃的溶解度,测定了各液相的折光率。结果表明生成了复合物2NiCl₂?(CH₂)₆N₄?HCI?9H₂O。文中介绍了该三元体系在13℃时平衡固相的热致变色性能,通过TG-DTA研究初步探讨了热致变色机理。     

Rigid elliptical cross-section ogive-nose projectiles penetration into concrete targets

The elliptical cross-section ogive-nose projectile (ECOP) has recently attracted attention because it is well suited to the flattened shape of earth-penetrating weapons. However, the penetration performance of ECOPs has not been completely understood. The objective of this study was to investigate the pene-tration performance of ECOPs into concrete targets using a theoretical method. A general geometric model of ECOPs was introduced, and closed-form penetration equations were derived according to the dynamic cavity-expansion theory. The model was validated by comparing the predicted penetration depths with test data, and the maximum deviation was 15.8％. The increment in the penetration depth of the ECOP was evaluated using the proposed model, and the effect of the major—minor axis ratio on the increment was examined. Additionally, the mechanism of the penetration-depth increment was inves-tigated with respect to the caliber radius head, axial stress, and resistance.     

Blast resistance evaluation of urban utility tunnel reinforced with BFRP bars

To improve corrosion-resistance of shallow-buried concrete urban utility tunnels(UUTs),basalt fiber reinforced polymer(BFRP)bars are applied to reinforce UUTs.As the UUT must have excellent survival capability under accidental explosions,a shallow-buried BFRP bars reinforced UUT(BBRU)was designed and constructed.Repetitive blast experiments were carried out on this BBRU.Dynamic responses,damage evolutions and failure styles of the BBRU under repetitive explosions were revealed.The tunnel roof is the most vulnerable component and longitudinal cracks develop along the tunnel.When the scaled distance is larger than 1.10 m/kg1/3,no cracks are observed in the experiments.When the BBRU is severely damaged,there are five cracks forming and developing along the roof.The roof is simplified as a clamped-supported one-way slab,proved by the observation that the maximum strain of the transverse bar is much larger than that of the longitudinal bar.Dynamic responses of the roof slab are predicted by dynamic Euler beam theory,which can consistently predict the roof displacement under large-scaled-distance explosion.Compared with the UUT reinforced with steel bars,the BBRU has advantages in blast resistance with smaller deflections and more evenly-distributed cracks when the scaled distance is smaller than 1.260 m/kg1/3 and the steel bars enter plastic state.Longer elastic defamation of the BFRP bars endows the UUT more excellent blast resistance under small-scaled-distance explosions.     

Numerical studies on four-engine rocket exhaust plume impinging on flame deflectors with afterburning

This paper studies the four-engine liquid rocket flow field during the launching phase. Using three-dimensional compressible Navier-Stokes equations and two-equation realizable k-epsilon turbulence model, an impact model is established and flow fields of plume impinging on the two different shapes of flame deflectors, including wedge-shaped flame deflector and cone-shaped flame deflector, are calcu-lated. The finite-rate chemical kinetics is used to track chemical reactions. The simulation results show that afterburning mainly occurs in the mixed layer. And the region of peak pressure occurs directly under the rocket nozzle, which is the result of the direct impact of exhaust plume. Compared with the wedge-shaped flame deflector, the cone-shaped flame deflector has great performance on guiding exhaust gas. The wedge-shaped and cone-shaped flame deflectors guide the supersonic exhaust plume away from the impingement point with two directions and circumferential direction, respectively. The maximum pressure and temperature on the wedge-shaped flame deflector surface are 37.2% and 9.9% higher than those for the cone-shaped flame deflector. The results provide engineering guidance and theoretical significance for design in flame deflector of the launch platforms.     

Partial penetration of annular grooved projectiles impacting ductile metal targets

Changing and optimizing the projectile nose shape is an important way to achieve specific ballistic performance. One special ballistic performance is the embedding effect, which can achieve a delayed high-explosive reaction on the target surface. This embedding effect includes a rebound phase that is significantly different from the traditional penetration process. To better study embedment behavior, this study proposed a novel nose shape called an annular grooved projectile and defined its interaction process with the ductile metal plate as partial penetration. Specifically, we conducted a series of low-velocity-ballistic tests in which these steel projectiles were used to strike 16-mm-thick target plates made with 2024-O aluminum alloy. We observed the dynamic evolution characteristics of this aluminum alloy near the impact craters and analyzed these characteristics by corresponding cross-sectional views and numerical simulations. The results indicated that the penetration resistance had a brief decrease that was influenced by its groove structure, but then it increased significantly-that is, the fluctuation of penetration resistance was affected by the irregular nose shape. Moreover, we visualized the distribution of the material in the groove and its inflow process through the rheology lines in microscopic tests and the highlighted mesh lines in simulations. The combination of these phenomena revealed the embed-ment mechanism of the annular grooved projectile and optimized the design of the groove shape to achieve a more firm embedment performance. The embedment was achieved primarily by the target material filled in the groove structure. Therefore, preventing the shear failure that occurred on the filling material was key to achieving this embedding effect.     

Transshipment through crossdocks with inventory and time windows

A major challenge in making supply meet demand is to coordinate transshipments across the supply chain to reduce costs and increase service levels in the face of demand fluctuations, short lead times, warehouse limitations, and transportation and inventory costs. In particular, transshipment through crossdocks, where just‐in‐time objectives prevail, requires precise scheduling between suppliers, crossdocks, and customers. In this work, we study the transshipment problem with supplier and customer time windows where flow is constrained by transportation schedules and warehouse capacities. Transportation is provided by fixed or flexible schedules and lot‐sizing is dealt with through multiple shipments. We develop polynomial‐time algorithms or, otherwise, provide the complexity of the problems studied. © 2005 Wiley Periodicals, Inc. Naval Research Logistics, 2005     

次氯酸钙乳液消毒剂模拟剂的研究

研究了一种次氯酸钙乳液消毒剂的模拟剂,以及一些影响稳定性因素．该模拟剂是以氢氧化钙为分散相,水为分散介质,表面活性剂和无机盐为稳定剂组成．实验结果表明,该模拟剂具有与次氨酸钙消毒乳液相同的物理性能,并且无污染,可用于教育、作训之中．     

"三个代表"与马克思主义哲学教育

在马克思主义哲学教学中实现"三个代表"重要思想的"三进入",必须引导学员全面把握"三个代表"蕴涵的哲学智慧和科学实践观,深刻领会"三个代表"对唯物史观的运用和发展,培养其创新意识创新能力,通过"第二课堂"自觉实践"三个代表".     

预燃室内气氢气氧射流燃烧过程数值分析

建立了液体火箭发动机预燃室内气氢气氧射流燃烧过程的数学模型,包括燃烧过程控制守恒方程、湍流流动方程和湍流燃烧模型,以及求解控制方程所需的辅助关系式;给出了模拟射流燃烧过程的数值方法。对于给定的预燃室结构型式和尺寸,研究了喷嘴构型和氧的喷射方式对化学反应流场和燃烧性能的影响规律。结果表明,喷嘴构型和氧的喷射方式对流动过程和燃烧性能都有影响,且喷嘴结构的影响较为明显。     

湍流射流火焰中煤粉颗粒尺寸和结构的变化

采用湍流煤粉射流火焰模拟实际工业煤粉燃烧中的迅速热解,取样分析实验研究煤粉热解过程中颗粒尺寸和内部结构的变化。结果表明：在热解过程中煤粉颗粒体积发生了明显的膨胀,膨胀程度强烈地依赖于颗粒的初始尺寸和加热速率;热解时挥发份的迅速释放及煤的热塑性导致了颗粒内部的空心结构,这种结构有效地提高炭粒的燃烧速率。