二价钴、镍氯化物的四齿N4大环席夫碱配合物的合成及表征

以Cocl_2·6H_2O和NiCl_2·6H_2O为模板剂,邻苯二胺和邻苯二醛为原料,在无水乙醇中模板合成了两种新型的大环席夫碱配合物。通过元素分析、摩尔电导和磁化率的测定,红外光谱、紫外可见光谱等项表征,确定了配合物的组成和结构,进而观察和研究了它们的电致变色现象,并对其电致变色机理进行了初步探讨。     

“逆解”与“顺解”标准值之再认识

从火控系统论证和动态精度检验需要出发,对火控系统动态误差应该用“逆解”还是“顺解”求取标准值问题,提出了已被否定的“顺解法”有再研讨、认识之必要。     

牵连运动为平动时单自由度自动机的动力学普遍方程

本文根据戴成勋教授的思想,对戴氏方程和韩氏方程予以修正,并导出了牵连运动为平动时,单自由度自动机动力学普遍方程。     

声自导鱼雷攻击弹道工程化分析

本文通过对主被动声自导鱼雷攻击弹道(水平面)几种方式的分析,取长补短,提出了综合攻击弹道的方案,即初始为尾追方式,最后为固定提前角方式攻击。并通过计算机仿真,获得了与世界先进雷取得一致的最佳调整方案。此外,本方案为其它尾追方式攻击的鱼雷提供了改进攻击弹道的依据。     

拓扑度理论之近期发展

这是一篇综述文章,介绍了拓扑度理论近十年来的主要成果。     

稀土配合物热致变色性能研究(VI)—稀土铬天青 S 配合物的热致变色性能

本文研究了BE(Ⅱ)-CAS 水溶液体系热致变色性能;探讨了酸度、温度等条件对体系热致变色性能的影响。实验结果表明该体系在特定条件下具有较明显的热致变色现象,且仅由配合物所产生,其特征是:体系受热时颜色由深色(玫瑰红)变为浅色(黄色);与RE(Ⅲ)-XO,RE(Ⅲ)-SXO 体系的色变趋向相反,达种差异性与螯合物分子的结构特征有关。     

NiCl2-(CH2)6N4•HCI-H2O 三元体系组成及热致变色性能研究

本文用相平衡法研究了NiCl₂ -(CH₂)₆N₄?HCI-H₂O三元体系在30℃的溶解度,测定了各液相的折光率。结果表明生成了复合物2NiCl₂?(CH₂)₆N₄?HCI?9H₂O。文中介绍了该三元体系在13℃时平衡固相的热致变色性能,通过TG-DTA研究初步探讨了热致变色机理。     

Rigid elliptical cross-section ogive-nose projectiles penetration into concrete targets

The elliptical cross-section ogive-nose projectile (ECOP) has recently attracted attention because it is well suited to the flattened shape of earth-penetrating weapons. However, the penetration performance of ECOPs has not been completely understood. The objective of this study was to investigate the pene-tration performance of ECOPs into concrete targets using a theoretical method. A general geometric model of ECOPs was introduced, and closed-form penetration equations were derived according to the dynamic cavity-expansion theory. The model was validated by comparing the predicted penetration depths with test data, and the maximum deviation was 15.8％. The increment in the penetration depth of the ECOP was evaluated using the proposed model, and the effect of the major—minor axis ratio on the increment was examined. Additionally, the mechanism of the penetration-depth increment was inves-tigated with respect to the caliber radius head, axial stress, and resistance.     

Blast resistance evaluation of urban utility tunnel reinforced with BFRP bars

To improve corrosion-resistance of shallow-buried concrete urban utility tunnels(UUTs),basalt fiber reinforced polymer(BFRP)bars are applied to reinforce UUTs.As the UUT must have excellent survival capability under accidental explosions,a shallow-buried BFRP bars reinforced UUT(BBRU)was designed and constructed.Repetitive blast experiments were carried out on this BBRU.Dynamic responses,damage evolutions and failure styles of the BBRU under repetitive explosions were revealed.The tunnel roof is the most vulnerable component and longitudinal cracks develop along the tunnel.When the scaled distance is larger than 1.10 m/kg1/3,no cracks are observed in the experiments.When the BBRU is severely damaged,there are five cracks forming and developing along the roof.The roof is simplified as a clamped-supported one-way slab,proved by the observation that the maximum strain of the transverse bar is much larger than that of the longitudinal bar.Dynamic responses of the roof slab are predicted by dynamic Euler beam theory,which can consistently predict the roof displacement under large-scaled-distance explosion.Compared with the UUT reinforced with steel bars,the BBRU has advantages in blast resistance with smaller deflections and more evenly-distributed cracks when the scaled distance is smaller than 1.260 m/kg1/3 and the steel bars enter plastic state.Longer elastic defamation of the BFRP bars endows the UUT more excellent blast resistance under small-scaled-distance explosions.     

Numerical studies on four-engine rocket exhaust plume impinging on flame deflectors with afterburning

This paper studies the four-engine liquid rocket flow field during the launching phase. Using three-dimensional compressible Navier-Stokes equations and two-equation realizable k-epsilon turbulence model, an impact model is established and flow fields of plume impinging on the two different shapes of flame deflectors, including wedge-shaped flame deflector and cone-shaped flame deflector, are calcu-lated. The finite-rate chemical kinetics is used to track chemical reactions. The simulation results show that afterburning mainly occurs in the mixed layer. And the region of peak pressure occurs directly under the rocket nozzle, which is the result of the direct impact of exhaust plume. Compared with the wedge-shaped flame deflector, the cone-shaped flame deflector has great performance on guiding exhaust gas. The wedge-shaped and cone-shaped flame deflectors guide the supersonic exhaust plume away from the impingement point with two directions and circumferential direction, respectively. The maximum pressure and temperature on the wedge-shaped flame deflector surface are 37.2% and 9.9% higher than those for the cone-shaped flame deflector. The results provide engineering guidance and theoretical significance for design in flame deflector of the launch platforms.