Formation and characterization of core-shell CL-20/TNT composite prepared by spray-drying technique

The core-shell 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane/2,4,6-Trinitrotoluene (CL-20/TNT) composite was prepared by spray-drying method in which sensitive high energy explosive (CL-20) was coated with insensitive explosive (TNT). The structure and properties of different formulations of CL-20/TNT composite and CL-20/TNT mixture were characterized by scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Laser particle size analyzer, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), differential scanning calorimetry (DSC), impact sensitivity test and detonation performance. The results of SEM, TEM, XPS and XRD show that ϵ-CL-20 particles are coated by TNT. When the ratio of CL-20/TNT is 75/25, core-shell structure is well formed, and thickness of the shell is about 20–30 nm. And the analysis of heat and impact show that with the increase of TNT content, the TNT coating on the core-shell composite material can not only catalyze the thermal decomposition of core material (CL-20), but also greatly reduce the impact sensitivity. Compared with the CL-20/TNT mixture (75/25) at the same ratio, the characteristic drop height of core-shell CL-20/TNT composite (75/25) increased by 47.6% and the TNT coating can accelerate the nuclear decomposition in the CL-20/TNT composites. Therefore, the preparation of the core-shell composites can be regarded as a unique means, by which the composites are characterized by controllable decomposition rate, high energy and excellent mechanical sensitivity and could be applied to propellants and other fields.     

Improving the damage potential of W-Zr reactive structure material under extreme loading condition

Projectiles made of reactive structure materials(RSM)can damage the target with not only kinetic but also chemical energy,but the enhanced damage potential of RSM may become compromised if extreme loading condition disintegrates the projectile before the target is reached.In this work,a ductile coating of Ni was introduced to a tungsten-zirconium(W-Zr)alloy,a typical brittle RSM,to preserve the damage potential of the projectile.Detonation driving tests were carried out with X-ray photography and gun-powder deflagration driving tests were carried out with high-speed photography for the coated and uncoated RSM samples,respectively.The craters on the witness target were analyzed by scanning electron microscopy and X-ray diffraction.The Ni coating was found to effectively preserve the damage potential of the W-Zr alloy under extreme loading conditions,whereas the uncoated sample fractured and ignited before impacting the target in both detonation and deflagration driving.The crack propa-gation between the reactively brittle core and the ductile coating was analyzed based on the crack arrest theory to mechanistically demonstrate how the coating improves the structural integrity and preserves the damage potential of the projectile.Specifically,the Ni coating envelops the W-Zr core until the coated sphere penetrates the target,and the coating is then eroded and worn to release the reactive core for the projectile to damage the target more intensively.     

热分析逸出气体氨的测定

用化学吸收光度法 (CAP)和热重 气相色谱联用法 (TG GC)测定了热分析逸出气中的氨。两种方法均简便、快捷和准确 ,通常回收率在 1 0 0± 6 %。比较了这些方法的使用范围     

用光测图像确定空间目标俯仰角和偏航角的中轴线法

提出了一种用电影经纬仪等光测设备获得的图像确定火箭等空间轴对称目标的俯仰角和偏航角的新方法——中轴线法 ;并对此方法进行了误差分析。此方法利用了目标图像上的大量信息 ,测量精度高。采用了间接的方法提取目标的中轴线 ,避免了多相机目标匹配的问题     

小波理论在大型空间智能结构振动控制中的应用

采用最优控制理论设计智能结构主动振动控制器,针对大型空间智能结构的低频和密频的特性,基于小波尺度函数变换,设计了智能结构的传感器、致动器;最后通过针对某大型空间智能桁架结构的仿真,表明该控制方法是行之有效的。     

用多重网格TVD方法求解三维高超音速粘性流场

本文采用时间相关法求解了三维Ｎ－Ｓ方程。在计算中，对于压力和对流项采用Ｒｏｅ的通量差分分裂技术和Ｏｓｈｅｒ－Ｃｈａｋｒａｖａｒｔｈｙ的ＴＶＤ格式，对于粘性项，采用了中心差分格式。通过数值模拟得到了钝头双锥体高超音速层流流场在不同攻角下的数值解。计算的重点放在壁面热流率的预测。在攻角为４°和１２°的状态下，Ｓｔａｎｔｏｎ数的计算值与实验值进行了比较，二者吻合较好。为了加快收敛速率，计算时采用了多重网格方法。     

高超音速流场的隐式TVD格式并行计算

本文采用区域分割技术和拼接网格的并行策略，发展了一个适合于分布式存贮多机系统的ＴＶＤ隐式有限体积并行算法；并在ＰＶＭ并行环境下，对三维高超音速绕流流场实现了多机并行计算，通过负载平衡等方法得到了较高的加速比（在二处理机系统上加速比为１∶８４，在四处理机系统上为３∶４４）。     

非线性控制在磁悬浮系统中的应用

用滑模变结构控制原理设计磁悬浮系统非线性控制器，并在磁悬浮球装置上进行了试验，结果证实这种控制器具有完全的鲁棒性、良好的参数适应性，设计方法也有广泛的适用性。悬浮系统的刚度有显著的提高。     

“9·11”世贸大楼坍塌原因数值分析

数值分析表明,"9·11"恐怖袭击事件造成纽约世贸大楼的内部竖向承重钢结构的防火保护层在爆炸中严重脱落,火灾高温使钢材强度大幅度降低,导致着火层群柱失稳,上部巨大的冲击荷载把下层柱逐层压渍,引发连续坍塌.最后对超高层建筑的结构设计提出建议.     

C3I系统效能仿真方法及环境研究

采用面向对象的方法和离散事件仿真技术,探讨了C3I系统效能仿真方法,并介绍了C3I系统效能仿真环境的设计思想。该环境能够支持多种模型的集成仿真,并易于扩展和扩充。