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31.
功能化离子液体的合成表征及其作为润滑剂的性质 总被引:2,自引:1,他引:2
通过两步法合成了含酯基官能团的咪唑类离子液体1-乙酸乙酯基-3-甲基咪唑四氟硼酸盐,用核磁共振、红外光谱、元素分析对其进行了结构表征,证明了该合成方法的可靠性;对功能化离子液体的基本物化性质、熔点、热稳定性及其作为润滑剂的粘温性、蒸发损失、金属腐蚀性等进行了全面研究,并选择了含有相同烷基的1-丁基-3-甲基咪唑四氟硼酸盐传统离子液体进行对比,发现官能团的引入,使传统烷基咪唑类离子液体展现出不同的特性,同时发现两种离子液体均对金属表面有较强的腐蚀作用,为进一步开展功能化离子液体的摩擦学研究打下了基础。 相似文献
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金属风暴武器射速与命中概率关系研究 总被引:1,自引:0,他引:1
基于对超音速、高超声速导弹的防御需求,从研究未来空域窗发射体制入手,利用"金属风暴"武器所具有的超高射速能力,通过分析超高射频弹幕武器在对空防御过程中的作战效能,计算目标命中概率与武器射速之间的关系,从而提高了发射系统的作战效能.并对发射系统的配置提出了理论上的要求. 相似文献
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非均匀焊接接头的力学建模与断裂分析 总被引:1,自引:0,他引:1
建立了非均匀焊接接头"4区连接"的新模型,并利用积分变换-奇异积分方程的方法,研究了焊缝区的反平面断裂问题。数值计算表明:增大界面区的刚度或者适当地增大焊缝区、热影响区和界面区的宽度都有利于降低焊缝区裂纹的应力强度因子;相对于高匹配情形而言,低匹配焊接接头焊缝区的抗断裂能力明显较高。 相似文献
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金属磁记忆信号表征铁磁材料变形的基础研究 总被引:1,自引:0,他引:1
为探索利用金属磁记忆技术进行再制造毛坯质量控制的方式方法,制作了18CrNiWA钢退火处理和调质处理的板状静载拉伸试件,在MTS810型液压饲服试验机上进行了拉伸试验,采用EMS2003金属磁记忆仪检测拉伸过程试件表面磁记忆信号变化,并利用OLYMPUSGX51观察了2种热处理状态的金相组织。研究结果表明:轴向拉伸载荷诱发试件产生磁有序状态,磁信号曲线在弹性和塑性变形阶段内呈现不同分布特征,磁曲线斜率Ks可以表征拉应力导致的变形程度;2种试件微观组织不同导致拉伸过程中呈现不同的力磁效应。 相似文献
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Nano-sized aluminum(Nano-Al)powders hold promise in enhancing the total energy of explosives and the metal acceleration ability at the same time.However,the near-detonation zone effects of reaction between Nano-Al with detonation products remain unclear.In this study,the overall reaction process of 170 nm Al with RDX explosive and its effect on detonation characteristics,detonation reaction zone,and the metal acceleration ability were comprehensively investigated through a variety of experiments such as the detonation velocity test,detonation pressure test,explosive/window interface velocity test and confined plate push test using high-resolution laser interferometry.Lithium fluoride(LiF),which has an inert behavior during the explosion,was used as a control to compare the contribution of the reaction of aluminum.A thermochemical approach that took into account the reactivity of aluminum and ensuing detonation products was adopted to calculate the additional energy release by afterburn.Combining the numerical simulations based on the calculated afterburn energy and experimental results,the param-eters in the detonation equation of state describing the Nano-Al reaction characteristics were calibrated.This study found that when the 170 nm Al content is from 0%to 15%,every 5%increase of aluminum resulted in about a 1.3%decrease in detonation velocity.Manganin pressure gauge measurement showed no significant enhancement in detonation pressure.The detonation reaction time and reaction zone length of RDX/Al/wax/80/15/5 explosive is 64 ns and 0.47 mm,which is respectively 14%and 8%higher than that of RDX/wax/95/5 explosive(57 ns and 0.39 mm).Explosive/window interface velocity curves show that 170 nm Al mainly reacted with the RDX detonation products after the detonation front.For the recording time of about 10 μs throughout the plate push test duration,the maximum plate velocity and plate acceleration time accelerated by RDX/Al/wax/80/15/5 explosive is 12%and 2.9 μs higher than that of RDX/LiF/wax/80/15/5,respectively,indicating that the aluminum reaction energy significantly increased the metal acceleration time and ability of the explosive.Numerical simulations with JWLM explosive equation of state show that when the detonation products expanded to 2 times the initial volume,over 80%of the aluminum had reacted,implying very high reactivity.These results are significant in attaining a clear understanding of the reaction mechanism of Nano-Al in the development of aluminized explosives. 相似文献
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《防务技术》2019,15(3):450-456
The aim of this research study was to determine optimal resistance spot brazing parameters for joining between AHSS and AISI 304 stainless steel by using filler metal. The key parameters investigated in this study consist of the brazing current, electrode pressure and brazing time. The Taguchi method was applied to the design of experiments. Signal-to-Noise ratio was introduced in the study to identify optimal levels from the process where input parameters yield increased shear strength. Brazing was thus implemented with 5,000A brazing current, 0.70 MPa electrode pressure, and 1.50s brazing time. The maximum shear strength obtained was 54.31 N·mm−2 in accordance with input parameter settings. In addition, Cu-rich phase and Ag0.4Fe0.6 intermetallic phases were found at the interface zone. 相似文献