石英/双酚E型氰酸酯复合材料的制备与性能

采用实验方法研究双酚E型氰酸酯树脂的黏度和固化特性,揭示催化剂对双酚E型氰酸酯树脂固化特性的影响规律;采用树脂传递模塑和真空导入模塑工艺制备石英纤维/双酚E型氰酸酯复合材料,并考察其力学性能。结果表明,双酚E型氰酸酯树脂室温至90℃范围内的黏度小于300 m Pa·s,凝胶时间大于10 h,起始固化温度、固化温度和终止固化温度分别为186±5℃,235±5℃和286±5℃;固化特征温度随着催化剂含量的增加而降低,直至催化剂饱和,其饱和范围为0.02%~0.03%,可使双酚E型氰酸酯树脂体系的固化温度降低约60℃,从而避免爆聚,实现液相法成型其复合材料;真空导入模塑工艺制备的石英纤维/双酚E型氰酸酯复合材料的力学性能明显优于树脂传递模塑制备试样。     

临近空间大型柔性充气囊体结构特性分析

以临近空间平流层飞艇柔性充气囊体为研究对象,根据充气结构设计理论对充气囊体结构的最小压差和应力进行计算,建立平流层飞艇充气囊体结构有限元模型。在模型验证的基础上,采用非线性有限元方法对平流层飞艇充气囊体结构特性进行仿真分析,得到了囊体结构在不同压差和吊舱载荷作用下应力和变形分布及变化规律,并分析了结构加强配置对囊体应力和变形的影响,为平流层飞艇结构设计提供技术支撑和参考依据。     

含诱导缺陷复合材料T型接头的弯曲失效实验

通过实验研究含不同诱导缺陷的复合材料T型接头的弯曲力学性能和失效过程,采用引入脱黏缺陷和三角区填充率缺陷来诱导T型接头的不同失效模式。结果表明不同失效模式下T型接头所表现出来的弯曲力学性能差异极大,完好的T型接头所能承受的载荷为288.5N,界面脱黏会削弱其30%的承载能力,而三角区填充率的减少会导致裂纹在填充区内部引发和扩展,导致T型接头的弯曲力学性能大幅降低。     

关于影剧院消防设计的探讨

通过分析大型剧场火灾的特点 ,针对其结构特点阐述了大型剧场在消防设计上应注意的几个方面 ,旨在探讨大型剧场的消防设计方法。     

Optimizing the defensive characteristics of mild steel via the electrodeposition of ZnSi3N4 reinforcing particles

The effect of ZnSi₃N₄ deposition prepared via direct electrolytic co-deposition on mild steel was studied as a result its inherent vulnerability to corrosion in an aggressive environment and failure on the application of load. The experiment was conducted varying the mass concentration of silicon nitride (Si₃N₄) between 7 and 13 g at cell voltage of 0.3 and 0.5 V, at constant temperature of 45 °C. The morphologies of the coated surfaces were characterized using high resolution Nikon Optical Microscope and Scanning Electron Microscope (SEM) revealing that the particles of the ZnSi₃N₄ were homogeneously dispersed. The corrosion behaviour was studied using potentiodynamic polarization technique in 3.65% NaCl solution and the microhardness was examined using Brinell hardness testing technique. The result of the corrosion experiment confirmed an improved corrosion resistance with a reduction in corrosion rate from 9.7425 mm/year to 0.10847 mm/year, maximum coating efficiency of 98.9%, maximum polarization resistance of 1555.3 Ω and a very low current density of 9.33 × 10⁻⁶ A/cm². The negative shift in the E_corr revealed the cathodic protective nature of the coating. The microhardness was also found to have increased from 137.9 HBN for the unmodified steel to a maximum value of 263.3 HBN for the 0.5Zn13Si₃N₄ coated steel representing 90.9% increment in hardness as a result of the matrix grain refining and dispersion-strengthening ability of the incorporated Si₃N₄ particles.     

船舶尾部结构振动计算

船舶尾部结构的振动问题应同时从船体总振动和尾部结构的局部振动两方面来考虑。本文从这一基本认识出发,利用有限元法编制了船舶尾部结构振动计算程序,并以实船为对象进行了尾部结构振动的计算,取得了较好的效果。     

钢结构防火材料应用问题及对策探讨

介绍了钢结构防火涂料的分类及特性,分析了钢结构建筑在火灾中的特点,探讨了钢结构防火涂料在技术和应用方面存在的问题,提出了钢结构建筑防火涂料施工时应注意的事项等对策。     

Analysis for the residual prestress of composite barrel for railgun with tension winding

Based on the elastic theory of cylindrical shells and the theory of composite laminates, a prediction model for the residual prestress of the simplified round composite barrel for railgun is established. Only the fibre pretension is considered in this model. A three dimensional numerical simulation for the residual prestress in the railgun barrel is carried out, by combining the temperature differential method with the element birth and death technology. The results obtained by the two methods are compared. It reveals that the distribution trends of residual prestress are consistent. And the difference for residual prestress in the filament wound composite housing of barrel is relatively small. The same finite element method is used to analysis the residual prestress in the non-simplified composite barrels for railgun, which are under different control modes of winding tension. The results mean that the residual prestress in barrel will increase while the taper coefficient for winding is decreasing. Therefore, the sealing performance in bore is improved, but the strength of the filament wound composite housing drops. In addition, the axial and circumferential residual prestress in the filament wound composite housing with constant torque winding are close to the ones in iso-stress design for barrel.     

Simulation of the plasticizing behavior of composite modified double-base (CMDB) propellant in grooved calendar based on adaptive grid technology

The frequent occurrence of safety accidents during the calendering process is caused by the flammable and explosive properties of composite modified double-base (CMDB) propellant. Optimization of process parameters with the aid of fluid simulation technology could effectively ensure the safety of the calendering process. To improve the accuracy of the simulation results, material parameters and model structure were corrected based on actual conditions, and adaptive grid technology was applied in the local mesh refinement. In addition, the rheological behavior, motion trajectories and heat transfer mechanisms of CMDB propellant slurry were studied with different gaps, rotational rates and temperatures of two rollers. The results indicated that the refined mesh could significantly improve the contour clarity of boundaries and simulate the characteristics of CMDB propellant slurry reflux movement caused by the convergent flow near the outlet. Compared with the gap, the increased rotational rate of roller could promote the reflux movement and intensify the shear flow of slurry inside the flow region by viscous shear dragging. Meanwhile, under the synergistic effect of contact heat transfer as well as convective heat exchange, heat accumulated near the outlet and diffused along the reflux movement, which led to the countercurrent heat dissipation behavior of CMDB propellant slurry. The plasticizing mechanism of slurry and the safety of calendering under different conditions were explored, which provided theoretical guidance and reference data for the optimization of calendering process conditions. Based on the simulation results, the safety of the CMDB propellant calendering process could be significantly improved with a few tests conducted during a short research and development cycle.     

Recent advances in catalytic combustion of AP-based composite solid propellants

Composite solid propellants (CSPs) have widely been used as main energy source for propelling the rockets in both space and military applications. Internal ballistic parameters of rockets like characteristic exhaust velocity, specific impulse, thrust, burning rate etc., are measured to assess and control the performance of rocket motors. The burn rate of solid propellants has been considered as most vital parameter for design of solid rocket motors to meet specific mission requirements. The burning rate of solid propellants can be tailored by using different constituents, extent of oxidizer loading and its particle size and more commonly by incorporating suitable combustion catalysts. Various metal oxides (MOs), complexes, metal powders and metal alloys have shown positive catalytic behaviour during the com-bustion of CSPs. These are usually solid-state catalysts that play multiple roles in combustion of CSPs such as reduction in activation energy, enhancement of rate of reaction, modification of sequences in reaction-phase, influence on condensed-phase combustion and participation in combustion process in gas-phase reactions. The application of nanoscale catalysts in CSPs has increased considerably in recent past due to their superior catalytic properties as compared to their bulk-sized counterparts. A large surface-to-volume ratio and quantum size effect of nanocatalysts are considered to be plausible reasons for improving the combustion characteristics of propellants. Several efforts have been made to produce nanoscale combustion catalysts for advanced propellant formulations to improve their energetics. The work done so far is largely scattered. In this review, an effort has been made to introduce various combustion catalysts having at least a metallic entity. Recent developments of nanoscale combustion catalysts with their specific merits are discussed. The combustion chemistry of a typical CSP is briefly discussed for providing a better understanding on role of combustion catalysts in burning rate enhancement. Available information on different types of combustion nanocatalysts is also presented with critical comments.