Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

An interface shear damage model of chromium coating/steel substrate under thermal erosion load

The Cr-plated coating inside a gun barrel can effectively improve the barrel's erosion resistance and thus increase the service life.However,due to the cyclic thermal load caused by high-temperature gun-powder,micro-element damage tends to occur within the Cr coating/steel substrate interface,leading to a gradual deterioration in macro-mechanical properties for the material in the related region.In order to mimic this cyclic thermal load and,thereby,study the thermal erosion behavior of the Cr coating on the barrel's inner wall,a laser emitter is utilized in the current study.With the help of in-situ tensile test and finite element simulation results,a shear stress distribution law of the Cr coating/steel substrate and a change law of the interface ultimate shear strength are identified.Studies have shown that the Cr coating/steel substrate interface's ultimate shear strength has a significant weakening effect due to increasing temperature.In this study,the interfacial ultimate shear strength decreases from 2.57 GPa(no erosion)to 1.02 GPa(laser power is 160 W).The data from this experiment is employed to establish a Cr coating/steel substrate interface shear damage model.And this model is used to predict the flaking process of Cr coating by finite element method.The simulation results show that the increase of coating crack spacing and coating thickness will increase the service life of gun barrel.     

车用磁流变减振器动力性能实验分析

MRF阻尼器结构简单、体积小、能耗低、反应迅速且阻尼力可调范围广, 已经成为新型履带车辆半主动悬挂系统优先选择的方案。基于磁流变液体本构关系的Bingham模型,对影响车用磁流变减振器的阻尼力的各种因素进行了综合分析。对自行研制的双出杆剪切阀式磁流变减振器进行了实验研究,获得了不同振幅、频率、电流强度下的阻尼力变化曲线,从不同的侧面获得了MRF阻尼器的动力性能。结合Hrovat限界最优半主动控制算法和车辆悬挂系统振动的半主动控制策略,仿真分析了磁流变阻尼器对整车振动的控制效果,并与LQR控制结果作了比较。     

基于电流变液的火炮反后坐技术研究

根据火炮反后坐装置的技术特点和电流变液的力学性能,从理论上分析了电流变液技术用于火炮反后坐装置的可行性,设计了简易电流变液驻退装置的结构和控制策略,并对关键的技术问题进行了探讨。     

基于模糊均值聚类算法的图像分割

将图像直方图统计特性引入到FCM聚类算法的目标函数中,用混合粒子群优化算法对目标函数进行全局最优求解,提高了图像分割的运算速度。     

基于RTP协议H．264视频流传输QoS保证的研究

提出一个Linux环境下基于RTP/RTCP的H.264视频流传输的方案,在Linux中调用V4L(VideofourLinux)的API函数采集视频流,经X264压缩,RTP/RTCP协议打包进行传输。并通过RTCP的RR(接收方报告)包反馈信息和吞吐量公式来计算近似带宽,以起始帧量化参数start-qp为视频编码的调节参数,由近似带宽来控制视频编码的参数调整,达到控制输出码率的目的,实现对视频传输的QoS(QualityofService)保证。     

可拓工程方法在效能-费用权衡中的应用

介绍可拓学及物元理论,提出用可拓工程方法对武器装备效能-费用进行权衡分析。建立了装备效费权衡分析的高阶复合物元模型,对初始效费方案进行了延拓,提出可拓特征集的概念。在此基础上,对效能-费用方案进行可拓聚类分析。     

避雷针保护范围的图形仿真与图解法分析

针对避雷针设计过程中计算公式过于复杂的问题,提出了利用平面几何作图求解避雷针联合保护范围的方法,给出了单支、双支和四支避雷针保护范围的作图解题步骤,并利用计算机图形仿真,给出了避雷针保护范围的空间结构图形。     

过程方法在防化科研质量管理系统中的应用

介绍了根据国军标要求建立的科研质量管理系统．运用“过程方法”,对现行科研体制下的科研进程进行了识别,并提出了具体的控制要求。     

利用混合编程改善SMP机群上并行矩阵乘法的性能

针对SMP机群,探讨了分别利用单机优化、OpenMP与MPI从指令级、共享存储级与分布主存级三个层次上改善矩阵并行乘Fox算法性能的方法。并通过调用数学函数库与混合编程的方式,在深腾6800上进行了实验,取得了相当满意的数值效果。