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用Ⅰ(n=2,4,7,8)的氯甲基化反应合成出相应的四种氯甲基化产物Ⅱ(n=2,4,7,8),讨论了反应条件对产率的影响,产物结构由IR和1HNMR确定,并讨论了反应机理。CH3OO(CH2)nH(Ⅰ)CH3OCH2C1O(CH2)nHCH2C1(Ⅱ 相似文献
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用1,4-二氯甲基-2,5-二甲基苯和1,4-二氯甲基-2-甲氧基-5-辛氧基苯共聚合成了一种可溶的聚对苯乙炔的衍生物,对共聚物结构进行了红外光谱、核磁共振氢谱表征 相似文献
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本文通过故障状态-特征的模糊聚类分析,按故障间的相似性对故障进行分类,然后按类别实施故障诊断,可在最少监测点的条件下,获得最多的设备运行故障信息。从而简化故障诊断过程,提高诊断速度和精度。 相似文献
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目前在网络中,基于仿冒IP的攻击非常普遍,在IPv4中源地址验证比较困难,而在IPv6中,地址位较长,使得基于地址本身验证IP是否合法成为可能。Hash运算具有计算的单向性、寻找相同散列值的明文消息的困难性和对初值的敏感性,利用Hash运算生成IPv6地址,增加了伪造的难度,有效地防止了基于仿冒IP的攻击。 相似文献
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Li-xiaosong Du Shao-hua Jin Qing-hai Shu Li-jie Li Kun Chen Ming-lei Chen Jun-feng Wang 《防务技术》2022,18(1):72-80
3-nitro-1,2,4-triazol-5-one (NTO) is the main component of insensitive munitions (IM) formulation because of its outstanding insensitive properties.In this paper,a series of NTO/HMX-based composite explosives were prepared and characterized.The study focuses on the effect of NTO on the performance of the formulations,especially the safety performance.The results revealed that the mechanical sensi-tivity of formulations was associated with NTO content,as well as the thermal conductivity,specific heat capacity and Arrhenius parameters.Then,the high amount of NTO using in formulation was proved to be helpful for NTO/HMX-based formulation to exhibit good thermal safety.Besides,by accelerating rate calorimeter (ARC) and a modified cook-offequipment,the pressure and pressure rise rate were proved as the important indicator for judging the thermal safety performance in confined spaces.Finally,the numerical simulation was used as a credible method for predicting the respond temperature of cook-off experiment. 相似文献
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Ammonium nitrate and fuel oil (ANFO) based explosive is a classic example of non-ideal high explosives. Its detonation is characterized by a strong dependence of detonation parameters on explosive charge diameter, presence and characteristics of confinement, as well as incomplete consumption of explosive at the sonic point.In this work we propose a detonation model based on the Wood-Kirkwood (WK) theory coupled with the thermochemical code EXPLO5 and supplemented with reaction rate models. Our objective is to analyze the validity of the model for highly non-ideal ANFO explosives, with emphasis on effect of reaction rate models.It was found that both single-step and two-step pressure-based models can be calibrated to reproduce experimental detonation velocity-charge radius data of ANFO at radii significantly above the failure radius (i.e. for D/Did > ∼0.6). Single-step pressure-based model, with the pressure exponent equal to 1.4, proved to be the most accurate, even in the vicinity of the failure radius. The impact of the rate models is most evident on temporal (and spatial) distribution of flow parameters in detonation driving zone, especially when it comes to the conversion and width of detonation driving zone. 相似文献