Investigation of the shock compression behaviors of Al/PTFE composites with experimental and a 3D mesoscale-model

The responses of AI/PTFE reactive materials (RMs) under shock compression were investigated by a single-stage gas gun.A 3D mesoscale-model was established based on micro-computed tomography(micro-CT) slice images and confirmed with experimental results.In the high-pressure stage,the com-posites reacted partially,whereas there were no deviations between the partially reacted Hugoniot and the inert simulation results.The simulation reveals that the Teflon matrix melting on the high shock pressure.Melts and decomposition of the PTFE accelerated the diffusion of the atoms.Thus,the reactions of the Al/PrFE composites are more like a combustion rather than a detonation.     

采用PWPF调节器的再入飞行器最优控制分配方法

针对具有反作用控制系统(Reaction Control System,RCS)和气动舵两类控制机构的再入飞行器,提出一种基于脉宽脉频(Pulse-Width Pulse-Frequency,PWPF)调节器的最优控制分配方法。将RCS的输入信号转化为连续变化量,RCS与气动舵的控制分配问题被描述为二次规划问题,并采用有效集方法对其求解。采用离散法和PWPF调节器将优化结果转化为RCS的开关机状态。与混合整数规划问题相比,连续二次规划问题更容易求解,计算速度更快。通过对二次规划问题的重构,该算法能有效地应对故障情况。     

空空导弹越肩发射初制导转弯控制与仿真

针对空空导弹越肩发射初制导俯仰平面180°转弯,提出了一种基于最优控制理论的最优转弯方法,该方法是确定一个最佳推力方向角,使转弯完成时导弹的末端速度最大。建立了简化的用于姿态控制的姿态动力学模型,采用反作用喷气控制系统(RCS)设计了导弹的姿态控制律。对空空导弹180°转弯的飞行过程进行了仿真并给出分析结果。     

扩链剂对TDI封端聚醚预聚物反应速度的影响

用FTIR研究了不同活性的扩链剂对TDI封端PPG预聚物固化速度和反应动力学的影响.结果表明:3种扩链剂与TDI封端PPG预聚物固化反应速度分别按1,3丁二醇、1,4丁二醇、MOCA的顺序增加,室温下3种扩链剂在固化前期均遵循二级反应动力学规律,其固化反应为二级反应,因此不同活性的扩链剂不影响TDI封端PPG预聚物固化反应的反应级数.     

核裂变链式反应过程中裂变中子密度计算公式建立的研究

针对作者先前发表的研究成果--"考虑缓发中子在内的中子倍增公式"中存在的随着核裂变代数的增加,公式的项数迅速增加,给计算造成不方便的问题,采用将缓发中子的先驱核浓度累积的方法建立了"改进的考虑缓发中子在内的中子倍增公式".该公式简单明了,计算方便,对核裂变链式反应裂变中子密度的计算有极其重要的意义.     

高速核在高温热平衡等离子体中的非平衡弛豫过程对热核反应率参数的影响

高速核入射到高温热平衡等离子体背景中,由于入射核动能远大于背景等离体中带电粒子之平均动能,入射核在与背景等离子体达到热平衡之前,会存在一段逐渐损失能量的非平衡弛豫过程。本文以高速氘核入射到高温氘化锂等离子体为例,在计及氘核的这种非平衡弛豫过程时,给出了一种计算热核反应D(t,n)~4He之反应率参数的方法。氘核在弛豫过程中的能量损失考虑了氘核与各种带电粒子的库仑散射过程,其能量损失率采用快速带电粒子的慢化理论来计算;氘与背景等离子体中的原子核发生的核反应过程,考虑了非平衡状态下束靶机制的D(t,n)~4He反应和热平衡状态下的D(t.n)~4He反应。在暂未考虑核散射的情况下,计算结果表明,当等离子体温度在7.5KeV～20KeV范围内变化时,氘核的非平衡弛豫过程对热平衡状态下D(t,n)~4He反应率参数的修正因子大致在1.0062～1.0943范围内变动,且温度越高,修正因子越小。计算还表明,当温度一定时,修正因子随等离子体中粒子的数密度变化不明显。     

一类三分子饱和反应动力系统的定性分析

研究化学反应中一类多分子一级饱和反应的数学模型应用微分方程定性理论,研究了该系统极限环的存在性、不存在性和唯一性问题。     

渗碳气氛的热力学及动力学分析

本文对渗碳气氛进行热力学及动力学分析,给出炉气各组分间反应速率的测试方法及测试数据。结果表明,渗碳气氛的独立反应数为4,自由度为3,甲烷的渗碳作用不可忽略,控制甲烷这一碳源有利于提高碳势控制精度.     

建筑材料燃烧性能分级新变革

介绍我国建筑材料燃烧性能分级的现状和未来的发展方向,提出引进欧盟的分级体系形成新的分级方法,并进行分析比较。     

Effects of nano-sized aluminum on detonation characteristics and metal acceleration for RDX-based aluminized explosive

Nano-sized aluminum(Nano-Al)powders hold promise in enhancing the total energy of explosives and the metal acceleration ability at the same time.However,the near-detonation zone effects of reaction between Nano-Al with detonation products remain unclear.In this study,the overall reaction process of 170 nm Al with RDX explosive and its effect on detonation characteristics,detonation reaction zone,and the metal acceleration ability were comprehensively investigated through a variety of experiments such as the detonation velocity test,detonation pressure test,explosive/window interface velocity test and confined plate push test using high-resolution laser interferometry.Lithium fluoride(LiF),which has an inert behavior during the explosion,was used as a control to compare the contribution of the reaction of aluminum.A thermochemical approach that took into account the reactivity of aluminum and ensuing detonation products was adopted to calculate the additional energy release by afterburn.Combining the numerical simulations based on the calculated afterburn energy and experimental results,the param-eters in the detonation equation of state describing the Nano-Al reaction characteristics were calibrated.This study found that when the 170 nm Al content is from 0％to 15％,every 5％increase of aluminum resulted in about a 1.3％decrease in detonation velocity.Manganin pressure gauge measurement showed no significant enhancement in detonation pressure.The detonation reaction time and reaction zone length of RDX/Al/wax/80/15/5 explosive is 64 ns and 0.47 mm,which is respectively 14％and 8％higher than that of RDX/wax/95/5 explosive(57 ns and 0.39 mm).Explosive/window interface velocity curves show that 170 nm Al mainly reacted with the RDX detonation products after the detonation front.For the recording time of about 10 μs throughout the plate push test duration,the maximum plate velocity and plate acceleration time accelerated by RDX/Al/wax/80/15/5 explosive is 12％and 2.9 μs higher than that of RDX/LiF/wax/80/15/5,respectively,indicating that the aluminum reaction energy significantly increased the metal acceleration time and ability of the explosive.Numerical simulations with JWLM explosive equation of state show that when the detonation products expanded to 2 times the initial volume,over 80％of the aluminum had reacted,implying very high reactivity.These results are significant in attaining a clear understanding of the reaction mechanism of Nano-Al in the development of aluminized explosives.