排序方式: 共有31条查询结果,搜索用时 15 毫秒
11.
12.
Li-xiaosong Du Shao-hua Jin Qing-hai Shu Li-jie Li Kun Chen Ming-lei Chen Jun-feng Wang 《防务技术》2022,18(1):72-80
3-nitro-1,2,4-triazol-5-one (NTO) is the main component of insensitive munitions (IM) formulation because of its outstanding insensitive properties.In this paper,a series of NTO/HMX-based composite explosives were prepared and characterized.The study focuses on the effect of NTO on the performance of the formulations,especially the safety performance.The results revealed that the mechanical sensi-tivity of formulations was associated with NTO content,as well as the thermal conductivity,specific heat capacity and Arrhenius parameters.Then,the high amount of NTO using in formulation was proved to be helpful for NTO/HMX-based formulation to exhibit good thermal safety.Besides,by accelerating rate calorimeter (ARC) and a modified cook-offequipment,the pressure and pressure rise rate were proved as the important indicator for judging the thermal safety performance in confined spaces.Finally,the numerical simulation was used as a credible method for predicting the respond temperature of cook-off experiment. 相似文献
13.
14.
Ammonium nitrate and fuel oil (ANFO) based explosive is a classic example of non-ideal high explosives. Its detonation is characterized by a strong dependence of detonation parameters on explosive charge diameter, presence and characteristics of confinement, as well as incomplete consumption of explosive at the sonic point.In this work we propose a detonation model based on the Wood-Kirkwood (WK) theory coupled with the thermochemical code EXPLO5 and supplemented with reaction rate models. Our objective is to analyze the validity of the model for highly non-ideal ANFO explosives, with emphasis on effect of reaction rate models.It was found that both single-step and two-step pressure-based models can be calibrated to reproduce experimental detonation velocity-charge radius data of ANFO at radii significantly above the failure radius (i.e. for D/Did > ∼0.6). Single-step pressure-based model, with the pressure exponent equal to 1.4, proved to be the most accurate, even in the vicinity of the failure radius. The impact of the rate models is most evident on temporal (and spatial) distribution of flow parameters in detonation driving zone, especially when it comes to the conversion and width of detonation driving zone. 相似文献
15.
目前在网络中,基于仿冒IP的攻击非常普遍,在IPv4中源地址验证比较困难,而在IPv6中,地址位较长,使得基于地址本身验证IP是否合法成为可能。Hash运算具有计算的单向性、寻找相同散列值的明文消息的困难性和对初值的敏感性,利用Hash运算生成IPv6地址,增加了伪造的难度,有效地防止了基于仿冒IP的攻击。 相似文献
16.
G. Jones 《Defence and Peace Economics》2013,24(3):225-249
By way of an evolutionary game model we show that mediation in international conflicts might be harmful to the conflicting parties. In fact, under anarchy both parties can be better off than under an international regime if mediation reduces the parties’ reactive capacities (i.e. their abilites to respond to an aggression). This result is applied to issues currently discussed in the literature on international relations such as the role of the United Nations as a mediator of international conflicts. 相似文献
17.
《防务技术》2022,18(12):2181-2189
An adverse effect resulting from explosive mine blasts is the production of toxic nitrogen oxides (NO and NO2) and carbon monoxide (CO). The empirical measurements of the concentration of toxic gases showed that it depends not only on the composition of an explosive and properties of its ingredients but also on several other parameters, such as volume of blasting chamber, explosive charge mass and design, confinement characteristics, surrounding atmosphere, etc. That explains why measured concentrations of toxic gases reported in literature significantly differ.In this paper, we discuss the possibility of theoretical prediction of the concentration of toxic gases by thermochemical equilibrium calculation applying two models: ideal detonation model and deflagration model. It can be demonstrated that thermochemical calculations can provide a good estimation of the measured concentrations and reproduce experimentally obtained effects of additives on the production of toxic gases. It was also found that the ideal detonation model applies to heavily confined explosive charges, while the deflagration model is more suitable for low detonation velocity explosives with light confinement. 相似文献
18.
五电平有源中点钳位(five-level active-neutral-point-clamped, 5L-ANPC)变频器拓扑结构简单,可直接通过公共直流母线供电,易于实现能量回馈,非常适合用于5~10 kV直流供电的船舶推进变频调速领域。简要介绍了5L-ANPC的主电路拓扑和工作原理,针对5L-ANPC拓扑杂散参数较大的四种换流回路,在兼顾可靠性及适装性前提下,设计了纯电容吸收电路。在上述基础上,分析了设置吸收电路后的5L-ANPC拓扑采用传统电压过零切换策略时存在的内开关管过压问题,并提出一种考虑吸收电路的切换策略,实现了输出电压过零器件安全切换,且避免了电压异常跳变。通过仿真和实验验证了所提考虑吸收电路的输出电压过零切换策略的有效性、正确性。 相似文献
19.
用对硝基苯乙酮、乙二醇、苯乙腈、氢气、高氯酸为原料,经酮基保护,环化,催化加氢和消除反应,合成出较高产率的5-乙酰基-2-氨基二苯甲酮。对反应机理作了初步探讨,并用元素分析、IR和1HNMR对其结构进行了表征。 相似文献
20.
本文用对甲氧基苯酚、正溴丁烷、聚甲醛为原料, 经醚化, 双氯甲基化和碱性消除反应, 合成出长链共轭且可溶的聚(2甲氧基5丁氧基)亚苯基亚乙烯,用 I R 和1 H N M R 表征了中间体和聚合物的结构,并测定了聚合物的伏—安特性曲线。 相似文献