几种气相缓蚀剂组分间协同作用研究

采用气相防锈甄别实验及量子化学计算方法对钼酸铵、亚硝酸钠、苯甲酸、苯甲酸钠、肉桂酸和肉桂酸钠等6种气相缓蚀剂的气相防锈能力和组分之间的协同作用进行研究．结果表明,4种单组分盐类物质本身不具备气相防锈能力,但2种无机盐和2种有机盐之间具有良好的协同效应．从防锈效果上看,钼酸铵完全可以代替亚硝酸钠,但由于其用量较高,成本上会高于传统的亚硝酸钠系气相缓蚀剂．     

网络中心与平台中心的声纳浮标探测概率建模

针对基于网络中心与平台中心的声纳浮标组网探测问题,在分析声纳浮标瞥概率模型的基础上,建立了两种方式下声纳浮标网的发现概率计算模型,给出了评价声纳浮标网探测效能指标.最后以声纳浮标拦截阵探测为例,对基于网络中心和基于平台中心的声纳浮标网探测效能进行分析,仿真了声纳浮标布设数量与布设间距对探测效能的影响.结果表明:当声纳浮标布设数量超过一定值时,继续增加并不能使网络中心的探测效能显著增加;与平台中心探测相比,声纳浮标瞥概率为Fermi模型时,网络中心探测的优势并不显著.     

跨文化教育与文化适应

跨文化教育在多民族、多文化并存的环境中突显出一定的优势和吸引力,从文化适应的角度来说,其基本理念和目标能够令受教育者获得不同文化的体验,从而获得对异质文化的理解,达到增加不同文化之间容忍度的目的,而这一目的实现的关键除了跨文化教育的设计和实施之外,还在于学校教育能否转化为社会效应。     

课堂教学中的问题情境创设

课堂教学中创设恰当的问题情境,能唤醒学生强烈的求知欲望,保持持久的学习热情,培养学生探索知识的能力和方法,促进学生全面地获得知识。在教学过程中,从学生的生活经验和已有知识出发,创设生动有趣的情境,使学生在课堂教学中通过有效的课堂活动,掌握基本的知识和技能,学会从多角度去观察事物、思考问题,激发学习兴趣和愿望。在课堂教学设计中,要根据学生实际、教学内容实际、社会实际去设计、创设问题情境,以便提高教学效果。     

Sandwich structure for enhancing the interface reaction of hexanitrohexaazaisowurtzitane and nanoporous carbon scaffolds film to improve the thermal decomposition performance

Improving the thermal decomposition performance of hexanitrohexaazaisowurtzitane (CL-20) by appropriate methods is helpful to promote the combustion performance of CL-20-based solid propellants. In this study, we synthesized a sandwich structure of CL-20 and nanoporous carbon scaffolds film (NCS) and emphatically studied the thermal decomposition performance of the composite structure. Thermogravimetric analysis and differential scanning calorimetry were used to measure the thermal decomposition process of the composite structure. The kinetic parameters of thermal decomposition were calculated by the thermal dynamic analysis software AKTS. These results showed that the thermal decomposition performance of the sandwich structure of CL-20 and NCS was better than CL-20. Among the tested samples, NCS with a pore size of 15 nm had the best catalytic activity for the thermal decomposition of CL-20. Moreover, the thermal decomposition curve of the composite structure at the heating rate of 1 K/min was deconvoluted by mathematical method to study the thermal decomposition process. And a possible catalytic mechanism was proposed. The excellent thermal decomposition performance is due to the sandwich structure enhances the interface reaction of CL-20 and NCS. This work may promote the extensive use of CL-20 in the field of solid rocket propellant.     

Thermal hazard assessment of TKX-50-based melt-cast explosive

In the present study, thermal hazards of TNT and DNAN used as the molten binder in TKX-50-based melt-cast explosives were comparatively studied through accelerating rate calorimeter (ARC) and Cook-off experiments. Two kinds of ARC operation modes were performed to investigate the thermal safety performance under adiabatic conditions (HWS mode) and constant heating (CHR mode). The obtained results demonstrated that at both heating modes, DNAN/TKX-50 outperformed TNT/TKX-50 from the thermal safety point of view. However, the sensitivity to heat of the samples was reverse because of the different heating modes. In addition, the results of thermal hazard assessment obtained from the cook-off experiment complied with ARC analysis which indicated the molten binder TNT replaced by DNAN would reduce the hazard of the TKX-50 melt cast explosive. Furthermore, the results of cook-off experiments also showed that DNAN/TKX-50 outperformed TNT/TKX-50 from the aspect of thermal stability, which was consistent with the result of CHR mode because of the similar heating process.     

基于认知实验的虚拟维修训练效果评估研究

为了客观、准确地评估虚拟维修训练系统的训练效果,从实验的角度出发,提出了基于认知实验的虚拟维修训练效果评估方法。首先,分析了虚拟维修训练的评估现状;其次,重点阐述了该方法的实施步骤,并通过对比维修人员基于传统训练手段和虚拟维修训练手段的考试成绩,评估训练系统的训练效果,为系统的改进、优化以及下一步的推广使用提供了重要的理论依据;最后,通过实例分析,验证了该方法的可行性和科学性.     

基于FLAC^3D的岩土边坡施工效应研究

采用FLAC3D对预应力锚索框架梁支护的岩土边坡施工过程进行数值模拟,围绕施工中坡体位移场与应力场的变化以及下级边坡施工对上部已完成的支挡结构受力影响进行研究.结果表明坡体开挖引起的松弛区呈圆弧状,且位移由临空面向坡体内逐渐减小,坡体弹性模量与其变形呈非线性递减关系;预应力锚索框架梁能有效抑制坡体变形,从坡顶到坡脚锚索轴力依次增大,故工程设计中宜对其分别设计,做到“强腰固脚”;下级边坡与上级边坡的支挡结构相互约束,共同承担滑坡推力,形成一种“联合支挡结构”.     

The non-isothermal gravimetric method for study the thermal decomposition kinetic of HNBB and HNS explosives

The hexanitrostilben (HNS) is a thermally stable explosive that can be prepared from hexanitrobibenzyl (HNBB). Therefore, the investigation of thermal stability of HNBB can be important in the yield of preparation of HNS. The decomposition kinetic of HNBB and HNS are studied by non-isothermal gravimetric method. The TG/DTG curves in non-isothermal method are obtained in range of 25°C–400 °C at heating rates of 3 °C/min, 5 °C/min, 8 °C/min, 10 °C/min and 12 °C/min. The data of weight-temperature are used for calculation of activation energy (E_a) of thermal decomposition reactions by methods of Ozawa, Kissinger, Ozawa-Flynn-Wall (OFW) and Kissinger-Akahira-Sunose (KAS) as model-free methods and Strink's equation as model-fitting method. The compensation effect is used for prediction of mechanism and determination of pre-exponential factor (lnA) of the decomposition reaction. A reduction 60 kj/mol for the average of activation energy of thermal decomposition reaction of HNBB is obtained versus HNS. This result shows the lower thermal stability of HNBB in comparison to HNS. The Avrami equation (A_3/2) with function f(α) = 3/2(1-α)[-ln(1-α)]^1/3 indicates the predicted mechanism for thermal decomposition reaction both explosives.     

大数据视角下的心理战效果评估

心理战效果评估是对心理战对敌毁伤效能的评估,是战争各方都很关注的重点领域,也一直是困扰心理战研究者的难题,有效评估心理战的效果对心理战过程形成完整闭锁回路、确定心理战实施重点方向和促进心理战战略战术手段的发展有着至关重要的作用。目前,对心理战效果评估的研究已取得了一系列学术成果,为效果评估的实施和实际操作提供了强有力的理论支撑,但现有研究多为指标体系建立等理论的提出和界定,缺少实际操作性的思路,本文主要从大数据的视角来探究心理战效果评估,并尝试从大数据技术的应用角度阐述大数据和心理战效果评估的融合。 