Insensitive energetic microspheres DAAF/RDX fabricated by facile molecular self-assembly

Insensitive energetic materials are promising in the defense weapons field. However, energetic materials still suffer from great challenges and the concern about their safety limits their utilization. In this work, insensitive energetic explosive 3,3′-diamino-4,4′-azoxyfurazan/hexahydro-1,3,5-trinitro-1,3,5-triazine (DAAF/RDX) microspheres were fabricated by self-assembly method. Rod-like DAAF/RDX was prepared by mechanical ball milling for comparison. DAAF/RDX composites with different mass ratios (90:10, 80:20, and 70:30) were obtained. The morphologies and structures of as-obtained DAAF/RDX composites were characterized by scanning electron microscopy (SEM), powder x-ray diffraction (PXRD) and fourier transform infrared spectroscopy (FT-IR). The results showed that DAAF/RDX microspheres exhibited regular shaped microspheres with sizes from 0.5 to 1.2 μm. There was no crystal transition during the modification process. The thermal properties of as-obtained materials were then evaluated by differential scanning calorimetry (DSC) and materials studio software. DAAF/RDX microspheres showed an advanced decomposition peak temperature compared with rod-like DAAF/RDX. The binding energy and peak temperature values at zero β_i (T_P0) of DAAF/RDX (90:10) increased by 36.77 kJ/mol, 1.6 °C, and 58.11 kJ/mol, 12.3 °C compared to DAAF/RDX (80:20) and DAAF/RDX (70:30), indicating the better thermal stability of DAAF/RDX (90:10). The characteristic drop height (H₅₀) of DAAF/RDX (higher than 100 cm) composites was higher than that of raw RDX (25 cm), suggesting significant improvements in mechanical safety. The preparation of DAAF/RDX microspheres is promising for the desensitization of RDX and useful for the formation of other materials and future wide applications.     

救生伞背带参数对假人动载的影响研究

针对救生伞假人高速开伞空投试验,建立降落伞-背带-假人系统的动力学模型,分析背带及脱离锁参数对假人质心过载的影响。在合理简化的基础上,采用多体动力学方法建立降落伞、背带脱离锁和假人的十五自由度动力学模型;采用质量-阻尼弹簧模型建立背带模型,连接降落伞、脱离锁和假人;利用实测过载计算降落伞开伞力。利用所建立的动力学模型仿真典型状态下假人和背带的动力学响应,验证所建立模型的合理性。分析脱离锁位置、背带松紧程度、背带材料特性对假人质心最大过载的影响,用于指导背带设计以及确定最佳的背带脱离锁位置。     

救生伞背带分系统对假人动载的影响

为了改善救生伞背带分系统的安全性,建立降落伞-背带-假人系统的动力学模型,分析背带及脱离锁参数对假人质心过载的影响。针对救生伞假人高速开伞空投试验,采用多体动力学方法建立降落伞、背带脱离锁和假人的十五自由度动力学模型;采用半质量-阻尼弹簧模型建立背带模型,连接降落伞、脱离锁和假人;利用实测过载计算降落伞开伞力。利用所建立的动力学模型仿真典型状态下假人和背带的动力学响应,验证所建立模型的合理性。分析了脱离锁位置、背带松紧程度、背带材料特性对假人质心最大过载的影响,可用于指导背带设计以及确定最佳的背带脱离锁位置。     

可实现以期望角度过顶迂回打击的制导律设计

在已有的小型导弹角度约束制导律设计中,对敌方目标打击角度约束范围往往有限.为了扩大角度约束的可行范围,实现对目标的全方位打击,基于双圆弧原理设计了可实现过顶迂回打击的制导律.首先,建立了导弹的末制导段相对运动模型,然后对双圆弧曲线拟合的原理进行了介绍和推导证明,对于两段圆弧的关键参数进行了推导,最后基于该原理设计了一种...     

Dynamic parameters of multi-cabin protective structure subjected to low-impact load – Numerical and experimental investigations

The dynamic response of a multi-cabin protective structure subjected to impact load directly affects the protective performance of materials; thus, studying the dynamic response and communication law of wave effect of the load plays an important role in the prediction of protective performance. In this study, the protection experiments of box-structure under air- and/or water-medium are conducted, the dynamic response of the structure subjected to low-impact load is analyzed, and the corresponding numerical simulations are analyzed using the theory of finite element method (FEM). Combined with experimental and FEM simulations, the shock strain distribution, acceleration attenuation, and signal energy in defensive materials are determined. Based on the results, the metal structure exhibits good absorption characteristics for shock vibration. Using the experimental data, we also show that the attenuation of shock wave in water medium should be significantly better than that in air medium, and the protective structure should be designed for a combination of water and air mediums. Meanwhile, the numerical simulation can provide a quantitative analysis process for dynamic analysis of defensive materials.     

某家具城火灾危险性研究

对西部家具城进行现场调研,了解其建筑概况以及内部可燃物种类、材质、数量等,统计火灾荷载,对其潜在的火灾危险性进行分析,提出减少火灾荷载、明确疏散路线和出入口、加强火源管理、提高消防安全意识等防火措施。     

舰船电力系统运行负荷估算方法研究

针对舰船电力系统的运行负荷估算常见算法的不足,提出了改进算法.改进算法用随机模型和回归模型描述舰船电力负荷,用回归模型描述的负荷采用回归算法,用随机模型描述的负荷采用逐步聚类法进行计算,并对获得随机负荷的计算参数提出了具体方法.通过对某船的计算和实测,进行了各算法的比较,验证了改进算法的可信性.     

军体课程密度与运动负荷初探

对军事体育课中运动负荷与课的密度进行研究,阐述了军事体育课合理运用课的密度与运动负荷的重要性,为进一步深化军事体育训练提供借鉴。     

复合材料层合板疲劳寿命形状参数与门槛值分析方法

复合材料性能具有较大的分散性,在表征复合材料疲劳寿命时,必须考虑分散性的影响.以M21C复合材料开孔层合板为研究对象,采用Sendeckyj等效静强度模型和随机变量函数的概率分布方法推导了复合材料层合板疲劳寿命形状参数和剩余强度形状参数的关系,通过试验和统计的方法获得了M21 C复合材料开孔层合板的疲劳寿命形状参数和疲...     

基于重构相空间AD-SVM的短期电力负荷预测

利用重庆市九龙坡区电网2009年7月1日000-10月8日4：00 99 d共2 380个历史电力负荷数据,分析其特点和规律.将构建混沌理论的平均位移（AD）法和支持向量机（SVM）相结合,提出了一种新的短期电力负荷预测模型.通过仿真计算,将结果与神经网络法预测结果进行对比,可得新方法能较好反应数据变化趋势,并且具备较好的拟合能力,能够提高负荷预测精度.在实际短期电力负荷预测中,可优先选用平均位移法与支持向量机相结合的新方法.