聚碳硅烷／二乙烯基苯快速升温裂解制备Cf/SiC复合材料

以聚碳硅烷(PCS)/二乙烯基苯(DVB)为先驱体,采用快速升温裂解制备了3D-B Cf/SiC复合材料.结果证明:裂解升温速率的提高可以大大缩短制备周期,同时可以提高材料密度和形成较好的界面结合,从而提高材料的力学性能.制备得到的Cf/SiC材料室温弯曲强度达到556.7MPa.     

三维编织碳纤维增强莫来石复合材料的制备与性能

结合Al2O3溶胶—凝胶技术和聚硅氧烷浸渍裂解技术制备出三维编织碳纤维增强莫来石复合材料(3D BCf/mullite)。研究表明,以AlCl3·6H2O和(CH2)6N4为原料的溶胶—凝胶工艺能制备出纳米γ Al2O3粉,它与聚硅氧烷在1400℃N2中共裂解可反应生成莫来石。所得3D BCf/mullite的密度为1.784g/cm3,弯曲强度和断裂韧性分别为282.5MPa和17.7MPa·m1/2。材料中较多的孔隙是材料密度和弯曲强度不高的原因所在。     

长杆射弹侵彻三种混凝土靶的实验研究

为了研究钻地武器的侵彻性能,在57mm口径的气炮上发射长杆射弹对三种靶体进行模拟侵彻实验。靶体为水泥砂浆石靶、钢纤维混凝土靶和含单层密排刚玉球的钢纤维混凝土靶。实验结果表明,弹头形状对侵彻深度有明显影响;当长杆射弹和撞击速度都相同时,与侵彻钢纤维混凝土靶相比,含单层密排刚玉球的钢纤维混凝土靶中的侵彻深度大约降低了11%,而水泥砂浆石靶中的侵彻深度增加了12%。     

高温空气下C/SiC复合材料力学性能测试

测试了C/SiC复合材料在高温空气下的压缩、弯曲和拉伸性能,利用扫描电子显微镜分析复合材料在室温与高温条件下的断口微观形貌。结果表明:从室温升温到1 000 ℃测试温度时,C/SiC复合材料的压缩强度由247 MPa降低至78 MPa,性能降低68%;弯曲强度由480 MPa降低至277 MPa,性能降低42%;拉伸强度由247 MPa降低至152 MPa,性能降低38%。高温氧化导致界面退化,损伤材料基体与碳纤维结构,加剧了纤维断裂程度,改变了纤维与基体的结合状态,纤维增韧机制逐渐消失,导致复合材料性能下降。     

Micromechanical simulation and experimental investigation of aluminum-based nanocomposites

Ceramic reinforced metal matrix nanocomposites are widely used in aerospace and auto industries due to their enhanced mechanical and physical properties. In this research, we investigate the mechanical properties of aluminum/Nano-silica composites through experiments and simulations. Aluminum/Nano-silica composite samples with different weight percentages of silica nanoparticles are prepared via powder metallurgy. In this method, Nano-silica and aluminum powders are mixed and compressed in a mold, followed by sintering at high temperatures. Uniaxial tensile testing of the nanocomposite samples shows that adding one percent of Nano-silica causes a considerable increase in mechanical properties of nanocomposite compared to pure aluminum. A computational micromechanical model, based on a representative volume element of aluminum/silica nanocomposite, is developed in a commercial finite element software. The model employs an elastoplastic material model along with a ductile damage model for aluminum matrix and linear elastic model for nano-silica particles. Via careful determination of model parameters from the experimental results of pure aluminum samples prepared by powder metallurgy, the proposed computational model has shown satisfactory agreement with experiments. The validated computational model can be used to perform a parametric study to optimize the micro-structure of nanocomposite for enhanced mechanical properties.     

Supercritical carbon dioxide as a new working medium for pneumatic launch: A theoretical study

Compared with the conventionally gaseous or liquid working media, the specific internal energy of supercritical carbon dioxide (SCD) is higher at the same temperature and pressure, and the critical temperature of carbon dioxide is close to room temperature, making SCD a potential new working medium for pneumatic launch. To analyze the feasibility of this conception, an analytical model of a pneumatic catapult is established on basis of the conservations of mass and energy. The model consists of a high-pressure chamber and a low-pressure chamber connected by multiple valves, and there is a movable piston in the low-pressure chamber that can push an aircraft to accelerate. The effects of the launch readiness state of SCD in the high-pressure chamber, the initial volume of the low-pressure chamber and the valve control on the movement of the aircraft are analyzed. It is found that there is a restrictive relation between the temperature and pressure of the launch readiness state of SCD, i.e., there is a maximum allowable launch readiness pressure when the launch readiness temperature is fixed. If this restrictive relation is not satisfied, the working medium in the low-pressure chamber will drop to its triple point within a few milliseconds, leading to a launch failure. Owing to this restrictive relation, there is an optimal launch readiness state of SCD with the highest working capacity for any allowable launch readiness temperature. The pressure of the low-pressure chamber will decrease significantly as the initial volume increases, leading to a decreased acceleration of the aircraft. The ac-celeration can be controlled below a critical value by a designed sequential blasting technique of multiple valves. The calculated results show that a 500 kg aircraft can be accelerated from 0 to 58 m/s in 0.9 s with 36 kg of carbon dioxide. This research provides a new technique for the controllable cold launch of an aircraft.     

一种新型甲醛气体清除材料的实验研究

采用溶胶-凝胶法将纳米TiO2负载在活性碳纤维上,制备出一种新型甲醛气体清除材料。在制备中依次掺杂Fe3+和十二烷基苯磺酸钠(SDBS)对纳米TiO2进行改性,研究了纳米TiO2光催化活性的变化,并测试了自制材料的甲醛清除效率。结果表明:Fe3+和SDBS的添加不会改变纳米TiO2的晶型结构,但有利于晶粒的成长和负载膜的光催化活性;添加体积分数分别为0.8%的Fe3+和3%的SDBS时,材料的甲醛清除效率最高。     

大温差条件下碳纤维混凝土无约束变形试验

为了研究碳纤维、聚酯纤维对混凝土在自由条件下的约束作用,通过设计对碳纤维混凝土、聚酯纤维混凝土和素混凝土加热放热试验,比较掺入不同纤维体积分数的纤维混凝土在大温差条件下无约束自由变形的差异,并用温度线膨胀系数表达。对试验数据进行分析,得到体积分数为1%的碳纤维混凝土比素混凝土抗自由变形能力提高了38.8%,在本试验的各种体积分数中效果最好。结果表明碳纤维与混凝土,虽然热力学性能不同,但是二者结合之后碳纤维因其高弹性模量的特性,反而可以更好地抑制混凝土自由变形。试验效果也表明,随着施工工艺的完善,碳纤维体积分数可能会超过1%,碳纤维对混凝土性能的提升仍然有很大的帮助。     

碳纤维混凝土单轴受压应力-应变本构关系

碳纤维混凝土受压应力-应变全曲线研究是对其基本力学性能进行全面认识的基础,也是表现碳纤维混凝土基本受压特性的综合宏观反映。对9组（碳纤维体积分数分别为0,0.2%,0.4%,0.6%,0.8%,1.0%,1.2%,1.4%,1.6%）碳纤维混凝土试件进行了立方体和棱柱体抗压强度试验,结果表明碳纤维混凝土立方体和棱柱体抗压强度随碳纤维体积分数的增加呈下降趋势,峰值应变随碳纤维体积分数的增加呈增大趋势。基于各体积分数碳纤维混凝土的棱柱体抗压强度和峰值应变的试验数据,拟合得到了棱柱体抗压强度和峰值应变与体积分数之间的函数表达式。利用微机控制电液伺服压力试验机测定了9组碳纤维混凝土应力-应变全曲线,参照非线弹性理论的混凝土单轴受压应力-应变本构模型,根据测得的全曲线应力-应变数据,拟合得到了应力-应变全曲线上升段表达式参数和下降段表达式参数,最后给出了基于碳纤维体积分数变化的碳纤维混凝土单轴受压应力-应变本构方程。     

3维C/SiC-ZrC复合材料的制备及其性能研究

针对超高温环境应用需求,采用化学气相渗透工艺(CVI)与先驱体浸渍-裂解工艺(PIP)联用制备了3维碳纤维增强SiC-ZrC基复合材料(C/SiC-zrC),并研究了SiC含量对C/SiC-ZrC复合材料力学性能、抗氧化性能和抗烧蚀性能的影响.结果表明,随着SiC含量的增加,C/SiC-ZrC复合材料的强度逐渐降低,静...