化学危险品运输车辆应防火灾爆炸事故

本文通过具体案例分析了化学危险品运输车辆可能发生火灾爆炸事故的原因,并提出了应采取的安全措施。     

气体化学反应速率的 DSMC 方法

为预报化学反应过程,应用ＤＳＭＣ方法研究了双原子分子的离解反应,讨论了高温情况下（Ｔ～Ｅａ／ｋ）采用由实验测定得到的反应速率与气体温度间Ａｒｒｈｅｎｉｕｓ经验关系式的可靠性问题,分析了振动热非平衡效应对于离解反应速率的影响,给出了由ＤＳＭＣ方法得到的离解反应速率与气体温度的关系曲线。     

吸收光谱法测量COIL水含量的实验研究

介绍了吸收光谱测量水蒸汽绝对浓度的方法,标定了实验环境下水蒸汽的吸收系数,并在氧碘化学激光器(COIL)上进行了初步的实验研究.测量结果显示,在常规工作条件下由于BHP温度变化所引起的水汽百分含量变化可以忽略,气体流速是引起水汽含量变化的主要原因.     

日本遗弃化学武器紧急处置中挖掘清理技术研究

就日本遗弃化学武器紧急处置中的挖掘清理技术进行了论述。着重论述了紧急处置现场的设置、挖掘方法步骤、程序、初始位置的挖掘以及污染物的包装等技术。同时,介绍了该技术在南京黄胡子山等地日本遗弃化学武器紧急处置中的应用情况。并对挖掘方法、进度及现场管理等工作提出了探讨性建议。     

Study on energy release characteristics of reactive material casings under explosive loading

Reactive Materials (RMs), a new material with structural and energy release characteristics under shock-induced chemical reactions, are promising in extensive applications in national defense and military fields. They can increase the lethality of warheads due to their dual functionality. This paper focuses on the energy release characteristics of RM casings prepared by alloy melting and casting process under explosive loading. Explosion experiments of RM and conventional 2A12 aluminum alloy casings were conducted in free field to capture the explosive fireballs, temperature distribution, peak overpressure of the air shock wave and the fracture morphology of fragments of reactive material (RM) warhead casings by using high-speed camera, infrared thermal imager temperature and peak overpressure testing and scanning electron microscope. Results showed that an increase of both the fireball temperature and air shock wave were observed in all RM casings compared to conventional 2A12 aluminum ally casings. The RM casings can improve the peak overpressure of the air shock wave under explosion loading, though the results are different with different charge ratios. According to the energy release characteristics of the RM, increasing the thickness of RM casings will increase the peak overpressure of the near-field air shock wave, while reducing the thickness will increase the peak overpressure of the far-field air shock wave.     

过程方法在防化科研质量管理系统中的应用

介绍了根据国军标要求建立的科研质量管理系统．运用“过程方法”,对现行科研体制下的科研进程进行了识别,并提出了具体的控制要求。     

“课后记”点滴谈

“课后记”是常规教学中的重要一环,它对探索教学规律,提高教学艺术,积累教学经验,提高教学质量,都有积极的作用。本文就“课后记”的好处、内容及写“课后记”时应注意的问题进行了探讨。     

OPTING OUT OF THE IRON TRIANGLE

Between the 1960s and the 1990s, the US chemical industry went from lobbying against the Geneva Protocol and promoting increased funding for chemical warfare to refusing to produce binary chemical weapons and assisting with the negotiations of the Chemical Weapons Convention (CWC)—even though the treaty included provisions that could be costly to industry. What happened in those thirty years to make the US chemical industry reverse its position on chemical weapons? This article argues these changes were largely caused by the chemical industry's desire to reform the negative public image it had acquired due to its involvement in the Agent Orange scandal and other high-profile incidents during the 1970s and 1980s. The chemical industry's assistance with CWC negotiations may be explained after an examination of the US public policy literature, which argues that industry will support apparently costly regulations if doing so helps it repair a damaged public image and ensures greater profits in the long run.     

Deterrence in the Gulf War

A recently published collection of captured Iraqi records offers an opportunity to better understand Saddam Hussein's perception of US and Israeli deterrence signals, affording innovative insights into the reasons behind Iraq's restraint from using weapons of mass destruction against Israeli targets during the 1991 Gulf War. This article tests a wide range of suggested hypotheses, and suggests that US and Israeli deterrence played only a minimal role in dissuading Iraqi use of WMD. The article concludes with some thoughts on the practical implications, particularly on the effectiveness of a “no-first-use” nuclear policy.     

超声波辅助微波消解预处理测量污泥金属元素

以实验室污泥和污水厂污泥为研究对象,建立了超声波辅助微波消解预处理测量污泥金属元素的方法与程序。首先通过超声波分散污泥絮体,然后对污泥进行加热预处理和微波消除,最后采用火焰原子吸收法测量污泥中的金属元素。结果表明,150 W超声波作用于25 mL污泥3 min为超声波分散污泥的较优条件,能保证后续操作过程取样均匀。微波消解前适宜的加热预处理条件为90℃,20 min。实验室污泥微波消解的较优酸体系为2 mL双氧水＋4 mL反王水（或4 mL王水）;污水厂污泥微波消解的较优酸体系为1 mL氢氟酸＋2 mL双氧水＋4 mL王水,同时,第3阶段消解条件为压强2.0 MPa下消解20 min。超声波辅助微波消解预处理具有用酸量少、简易快捷、准确度和精密度高等优点,测量K,Ca,Mg,Fe的相对标准偏差≤2.75%,加标回收率为97.5%～102%。