气体化学反应速率的 DSMC 方法

为预报化学反应过程,应用ＤＳＭＣ方法研究了双原子分子的离解反应,讨论了高温情况下（Ｔ～Ｅａ／ｋ）采用由实验测定得到的反应速率与气体温度间Ａｒｒｈｅｎｉｕｓ经验关系式的可靠性问题,分析了振动热非平衡效应对于离解反应速率的影响,给出了由ＤＳＭＣ方法得到的离解反应速率与气体温度的关系曲线。     

HF化学激光器燃烧室中燃料配比的数值分析

利用最小自由能法及质量流量守恒原则,对HF化学激光器的NF3-D2-He体系的化学平衡组分进行了计算,提出了F原子摩尔流量密度参量,分析了各输入气流的流量调节对燃烧室总温、总压、F原子产率等的影响.在燃料配比不变的情况下,总流量的增加使得F原子流量也成比例增加,而由此带来的总压升高引起的F2解离度、绝热燃烧温度、F原子...     

在线并列生产装置固有火灾危险度评估

石油化工生产工艺装置复杂 ,工艺控制参数苛刻 ,处理的物料大都具有易燃易爆等特殊的危险性。针对石化生产装置的共同特点 ,通过三套在线并列存在的炼油生产装置 ,从物料特性、工艺装置、工艺控制参数、操作控制等方面综合分析其火灾危险因素 ,并采用美国道化学公司火灾、爆炸危险指数评价法评估装置间的固有火灾危险 ,为消防安全设施的配置以及灭火预案的制定提供依据。     

案例教学在《化学事故应急救援》课程中的应用

案例教学首先要了解“案例教学法”的含义及特点,在此基础上介绍《化学事故应急救援》的课程特点,并就该课程案例教学实施过程中案例的选取、课堂案例讨论、案例总结与评价等问题进行分析,最后对案例教学实施中应注意的问题提出三点意见。     

An Analysis of the Threat of Malicious Chemical Use by Nonstate Actors: Questioning the State-based Approach to Chemical Nonproliferation

ABSTRACT

This study seeks to evaluate the threat of malicious chemical use by non-state actors. It finds that non-state actors have primarily turned to ready-to-use crude chemical weapons (CW) instead of traditional CW agents. Interestingly, the worst crude CW attacks have been more destructive than those employing traditional CW. Scenarios for catastrophic consequences exist, but chemical attacks have typically been used to accomplish tactical goals, which leverage psychological and economic impacts. Therefore, successful efforts to counter CW proliferation by non-state actors must be substantially different from those targeting states.     

Development of cost effective personnel armour through structural hybridization

The objective of the present study is to develop cost effective thermoplastic hybrid laminate using Dyneema® HB50 and Tensylon®HSBD 30A through structural hybridization method. Laminates having 20 mm thickness were fabricated and subjected to 7.62 × 39 mm mild steel core projectile with an impact velocity of 730 ± 10 ms⁻¹. Parameters such as energy absorption, back face deformation and rate of back face deformation were measured as a function of hybridization ratio. It was observed that hybrid laminate with 50:50 ratio (w/w) of Tensylon® and Dyneema® with Tensylon® as front face showed 200% more energy absorption when compared to 100% Tensylon® laminate and showed equal energy absorption as that of expensive 100% Dyneema® laminate. Moreover, hybrid laminate with TD50:50 ratio showed 40% lower in terms of final back face deformation than Dyneema® laminate. Rate of back face deformation was also found to be slow for hybrid laminate as compared to Dyneema® laminate. Dynamic mechanical analysis showed that, Tensylon® laminate has got higher stiffness and lower damping factor than Dyneema® and hybrid laminates. The interface between Tensylon® and Dyneema® layers was found to be separating during the penetration process due to the poor interfacial bonding. Failure behaviour of laminates for different hybridization ratios were studied by sectioning the impacted laminates. It was observed that, the Tensylon® laminate has undergone shear cutting of fibers as major failure mode whereas the hybrid laminate showed shear cutting followed by tensile stretching, fiber pull out and delamination. These inputs are highly useful for body armour applications to design cost effective armour with enhanced performance.     

石化工业园区消防安全分析及灾害事故处置对策研究

针对全国各地石化工业园区不断新建,化学灾害事故风险增大,以及灾害事故处置难度大的问题,以天津滨海新区石化工业园区为例,对石化工业园区灾害事故风险进行了全面分析,有针对性地提出了石化工业园区灾害事故处置的对策与建议。     

化学毒剂及相关化合物的色谱及质谱分析检测研究进展

介绍了当前对毒剂及相关化合物的色谱及质谱分析检测研究进展和发展趋势。仪器设备方面,气相色谱-质谱联用仪仍是主力仪器：但对热不稳定性及难挥发性化合物来说,用液相色谱-质谱来分析则更为合适;发展现场可用的、便携式鉴别技术和设备也是一个发展趋势。分析化合物方面,不能局限于附表化学品,应该积极开展对毒素及毒物与生物体加合物等复杂化合物的分析研究。样品基质方面,应该展开对新型消毒剂样品及生物样品的研究。     

基于层次分析法的化工企业火灾风险评估研究

化工企业火灾风险评估对于化工生产至关重要。针对化工行业的火灾风险,结合层次分析法和模糊识别模式的优点,提出了基于层次分析—模糊识别的综合评价方法,并通过实例评估证明了这种评价方法行之有效。     

论内初班化学课的教与学

内初班学生在学习化学时,教师应尽可能的了解民族学生的生活习惯和汉语水平。从学习习惯、化学用语、基础知识、作业、实验等方面入手培养严谨认真的学习习惯,细心观察和动手能力。