建筑材料燃烧性能分级新变革

介绍我国建筑材料燃烧性能分级的现状和未来的发展方向,提出引进欧盟的分级体系形成新的分级方法,并进行分析比较。     

分解炉内煤粉燃烧和CaCO3分解流场的数值模拟

针对国内某大型水泥高性能分解炉,基于Fluent软件,采用有限速率/涡耗散模型模拟了炉内煤粉燃烧和生料分解的湍动多相流场,给出了炉内速度矢量、温度、压力和组分分布,结果显示,炉内流动趋势合理,可为分解炉的研究提供参考.     

固体热容激光器温度场应力场分析

采用有限元分析方法,对Nd:YAG作为激活介质的固体热容激光器的温度场及应力场进行了研究.结果表明固体热容激光器的温度场、应力场与常规的固体激光器有很大的差异,常规的固体激光器激活介质必须在泵浦的同时进行冷却,晶体表面温度比中心温度低,晶体表面受到的是张应力.固体热容激光器发射激光时,激活介质处于绝热状态.激活介质表面的温度要比中心高,激活介质表面出现的是压应力.这种差异是固体热容激光器可以高功率运转的物理机制.     

储氢电极合金的温度特性研究

针对目前储氢电极合金不适用于电动汽车用大型电池的情况 ,以Ml (NiCoMnTi) 5 合金为例 ,系统研究了温度对储氢电极合金电化学性能的影响。结果表明 :随着温度升高 ,合金的放电容量降低 ,循环稳定性恶化 ,自放电加剧 ;但是在高温下合金的高倍率放电特性得到显著改善。     

天然气在土壤中泄漏的稳态温度场分析

埋地高压天然气经小孔泄漏会导致土壤冻结形成冻土,应用一元气体动力学、流体力学和传热学知识建立了天然气小孔泄漏吸热率模型和土壤稳态温度场模型,并进行了实例计算。结果表明：当天然气输送压力小于临界压力,小孔泄漏吸热率随压力的增大而增大;当天然气输送压力大于等于临界压力,小孔泄漏吸热率达到最大值;冻土厚度随土壤热导率或空气对流传热系数的增大而减小,但土壤热导率对其影响较小,空气对流传热系数对其影响较大。     

环管型燃烧室喷雾燃烧DES模拟

为研究燃气轮机燃烧室内复杂的两相三维湍流燃烧问题,采用基于Realizable k-ε模型的分离涡模拟(DES)方法对环管型燃烧室进行喷雾燃烧数值模拟.数值模拟结果表明:DES模拟在燃烧区发挥出大涡模拟(LES)的作用,能获取结构复杂的流场、温度场和涡量场,其对流场内涡结构的捕捉和分辨能力明显强于传统的RANS(雷诺时均N-S方法)模拟.与实验数据对比发现,DES模拟所得燃烧产物含量和燃烧室出口温度分布更符合.因此,DES方法可用于复杂形状燃烧室的燃烧数值模拟,能够避免RANS模型对湍流脉动进行平均处理导致耗散过大、抹平涡结构的缺点,从而可获取更准确的计算结果.     

Vapor-phase decomposition of dimethyl methylphosphonate (DMMP), a sarin surrogate,in presence of metal oxides

Chemical warfare agents (CWA) are stockpiled in large quantities across the globe. Agents stored in inaccessible facilities need to be destroyed rapidly without dispersing the compounds to surrounding areas. Metal-based energetic formulations are used in such prompt defeat applications to rapidly decompose the CWA by generating a high temperature environment. An alternate, and possibly a more effective decomposition pathway could be provided by chemicidal action of aerosolized condensed combustion products, which typically consist of metal oxides. Toxic fumes that escape the high tem-perature blast zone can be neutralized by smoke generated during combustion, depending on the par-ticle size, surface characteristics, chemical properties, and concentration of this smoke. This review considers relevant experimental and modeling studies quantifying decomposition of CWA comprising organophosphorus compounds and their surrogates on the surface of various metal oxides. Dimethyl methylphosphonate (DMMP), a sarine surrogate, was used most commonly for such experiments. Many reported efforts focused on the mechanisms of adsorption of DMMP to various metal oxides and initial reaction steps cleaving various bonds from the chemisorbed molecules. For selected oxides, these ex-periments were supported by quantum-mechanical calculations. In other studies, the capacity of oxide surfaces to adsorb and decompose DMMP was quantified. In most cases, porous catalysts were used although limited experimental data are available for aerosolized nonporous oxide particles. The reported experimental data applicable to scenarios involving prompt decomposition of CWA are summarized. It is noted that information is lacking describing respective heterogeneous reaction kinetics. Preliminary estimates of aerosolized smoke particle concentrations required to destroy CWA are made considering gas phase diffusion rates and reported values of the oxide capacity to decompose CWA or their surrogates.     

Phenomenological modelling of flow behaviour of 20MnMoNi55 reactor pressure vessel steel at cryogenic temperature with different strain rates

In the present study a phenomenological constitutive model is developed to describe the flow behaviour of 20MnMoNi55 low carbon reactor pressure vessel (RPV) steel at sub-zero temperature under different strain rates. A set of uniaxial tensile tests is done with the variation of strain rates and temperature ranging from 10⁻⁴ s⁻¹ to 10⁻¹ s⁻¹ and -80 °C to −140 °C respectively. From the experimental data, family of flow curves at different temperatures and strain rates are generated and fitted exponentially. The strain rate and temperature dependence of the coefficients of the exponential flow curves are extracted from these curves and characterised through a general phenomenological constitutive coupled equation. The coefficients of this coupled equation are optimised using genetic algorithm. Finite element simulation of tensile tests at different strain rates and temperatures are done using this coupled equation in material model of Abaqus FEA software and validated with experimental results. The novelties of proposed model are: (a) it can predict precisely the flow behaviour of tensile tests (b) it is a simple form of equation where fitting parameters are both function of strain rate ratio and temperature ratio, (c) it has ability to characterize flow behaviour with decreasing subzero temperatures and increasing strain rates.     

测量火焰中氢氧基分布的激光诱导荧光技术

使用平面激光诱导荧光(PLIF)技术测量了不同火焰的氢氧基分布图像,简述了测量原理,讨论了影响测量结果的主要因素,并将测量结果与自发辐射测量结果进行了比较。对PLIF技术在燃烧过程研究中的应用进行了尝试,证明该技术是燃烧分析的有力工具。     

数值模拟气/气喷嘴速度比对燃烧性能的影响

为研究应用于全流量补燃循环发动机的不同气/气喷嘴得到的燃烧流场,通过求解NavierStokes方程组,对不同燃料与氧化剂速度比下的流动燃烧过程进行了数值计算,计算结果与实验结果吻合。仿真结果表明:增加速度比能使燃烧火焰面提前,燃烧效率变大。如果发动机的长度受到限制,可以适当增加速度比以实现高效燃烧。