Thermal decomposition of ammonium perchlorate catalyzed with CuO nanoparticles

Ammonium perchlorate (APC) is the most common oxidizer in use for solid rocket propulsion systems. However its initial thermal decomposition is an endothermic process that requires 102.5 J·g⁻¹. This manner involves high activation energy and could render high burning rate regime. This study reports on the sustainable fabrication of CuO nanoparticles as a novel catalyzing agent for APC oxidizer. Colloidal CuO nanoparticles with consistent product quality were fabricated by using hydrothermal processing. TEM micrographs demonstrated mono-dispersed particles of 15 nm particle size. XRD diffractogram demonstrated highly crystalline material. The synthesized colloidal CuO particles were effectively coated with APC particles via co-precipitation by using fast-crash solvent–antisolvent technique. The impact of copper oxide particles on APC thermal behavior has been investigated using DSC and TGA techniques. APC demonstrated an initial endothermic decomposition stage at 242 °C with subsequent two exothermic decomposition stages at 297.8 °C and 452.8 °C respectively. At 1 wt%, copper oxide offered decrease in initial endothermic decomposition stage by 30%. The main outcome of this study is that the two main exothermic decomposition peaks were merged into one single peak with an increase in total heat release by 53%. These novel features can inherit copper oxide particles unique catalyzing ability for advanced highly energetic systems.     

空间应用载荷的天地端到端IP隧道协议通信架构设计

在地面运控子网和载荷信息网中设计IPsec、GRE或RFC2003三种IP隧道协议,通过平台信息网和天地测控网,封装的用户数据包能在天地通信链路中路由,以支持在轨载荷和地面运控终端之间端到端的灵活通信。设计支持IP隧道协议通信的天地一体化信息网络架构,给出各级路由器的设置和网段IP地址分配,计算和分析出三种IP隧道协议的通信效率与实时性。分析结果表明,采用IP隧道协议对改变传统地面运控模式、提高运控效率具有重要意义。     

系统复杂性及度量

复杂性是科学技术面临的挑战之一,研究系统复杂性有着重要意义。综述系统复杂性基本语义研究背景,分析国内外历史上对复杂性的界定及不同定义;针对复杂性的分类,以本体论和认识论分类为基本框架,吸纳最新的复杂性分类定义成果,重新对复杂性进行归类。在此基础上,对复杂性的度量指标进行分类阐述,对相应的数学工具进行归类说明。设计案例说明了复杂性概念分类及度量的有效性。     

陆军无人装备作战指挥信息系统

本文对陆战场无人化、智能化作战需求及其对指挥信息系统的能力要求进行分析。以美军为典型样例对无人装备的指挥信息系统发展现状进行分析,对无人装备作战指挥信息系统体系架构进行构想,并提出未来需重点突破的关键技术,最后对军队无人装备指挥信息体系的发展提出了几点建议。     

模糊论的复杂系统评价方法

模糊综合评价法对复杂系统进行评价具有其他评价方法无法比拟的优越性.介绍了模糊评价的基本原理及其数学模型,给出了复杂系统的模糊矩阵的表示方法及推理过程.重点分析了其在某型垂直/短距飞行器设计中的应用,证明了该方法在系统评价中的有效性.该方法可以有效地对复杂系统进行评价并对系统的设计有一定的指导意义.     

On a class of multiple failure mode systems

The primary objective of this work is to introduce and perform a detailed study of a class of multistate reliability structures in which no ordering in the levels of components' performances is necessary. In particular, the present paper develops the basic theory (exact reliability formulae, reliability bounds, asymptotic results) that will make it feasible to investigate systems whose components are allowed to experience m ≥ 2 kinds of failure (failure modes), and their breakdown is described by different families of cut sets in each mode. For illustration purposes, two classical (binary) systems are extended to analogous multiple failure mode structures, and their reliability performance (bounds and asymptotic behavior) is investigated by numerical experimentation. © 2002 Wiley Periodicals, Inc. Naval Research Logistics 49: 167–185, 2002; DOI 10.1002/nav.10007     

CPN在海上防空建模中的应用

着色 Petri网 (CP-网或 CPN )是一种面向图形的语言 ,用来设计、说明、模拟和验证系统。尤其适用于通信系统等同步和资源共享占有重要地位的系统。在通信协议、分步式系统、嵌入系统、自动生产系统、工作流分析、VL SI芯片等方面都有典型的应用。本文简单介绍了 CPN的发展过程和基本原理 ,重点就 CPN在海上防空系统建模仿真中的应用进行了探讨     

计算潜艇空调热负荷的传递函数法

通过对圆筒壁的导热微分方程进行拉氏变换 ,提出以传递函数为基础的空调动态负荷计算方法 ,推导出圆筒壁热力系统的动态数学模型 .根据此模型得出的潜艇空调热负荷动态计算结果比采用静态负荷计算法更准确 .     

单输入不确定系统离散变结构控制

研究单输入不确定离散时间系统的变结构控制设计问题.提出一种新形式的离散趋近律,它具有良好的动、静态特性,可有效消除由传统离散趋近律参数引起的抖振.设计扰动预估器以补偿不确定因素的影响,从而提高系统鲁棒性并进一步减弱抖振.仿真结果表明了所提设计方法的有效性.