Novel aluminum-based fuel: Facile preparation to improve thermal reactions

To improve the thermal properties of aluminum (Al) in the energetic system, a coated structure with ammonium perchlorate (AP) was prepared by a facile approach. And N, N-Dimethylformamide (DMF) was chosen as an ideal solvent based on heterogeneous nucleation theory and molecular dynamics simulation. This coated structure could enlarge the contact area and improve the reaction environment to enhance the thermal properties. The addition of AP could accelerate oxidation temperature of Al with around 17.5 °C. And the heat release of 85@15 composition rises to 26.13 kJ/g and the reaction degree is 97.6% with higher peak pressure (254.6 kPa) and rise rate (1.397 MPa/s). An ideal ratio with 15 wt% AP was probed primarily. The high energy laser-induced shockwave experiment was utilized to simulate the reaction behavior in hot field. And the larger activated mixture of coated powder could release more energy to promote the growth of shockwave with higher speed up to 518.7 ± 55.9 m/s. In conclusion, 85@15 composition is expected to be applied in energetic system as a novel metal fuel.     

不同初始条件下乙醇-空气预混合气层流燃烧火焰结构分析

给出了一个扩展的乙醇化学反应动力学机理并给予了验证。利用此扩展机理分别计算了不同初始条件下乙醇-空气混合气一维层流自由传播火焰中反应物、自由基、碳基中间产物和燃烧产物的分布规律,预测了NOx的浓度分布曲线。对于乙醇-空气火焰,得到的主要结论有：主要自由基OH、H和O浓度随初始压力增加而减小;随初始温度增加而增加;随氮气稀释度的增加而减小。自由基浓度随初始条件的变化规律部分地解释了实验和计算得到的层流燃烧速度随初始条件的变化规律。     

对Reimer-Tiemann反应的改进

传统的Reimer-Tiemann反应产率不高(一般低于35%).通过改进反应条件,控制反应过程,使产率提高到60%,并对反应中的有关问题进行了讨论.     

一类可逆多分子饱和反应系统的定性研究

研究了一类具有饱和输出的可逆多分子反应动力学模型 x=( y b) (δ-xyn cyn 1 ) y=( y b) yn(x-cy) -ay应用微分方程定性理论 ,较完整地解决了该系统极限环的存在性、唯一性及不存在性。     

微小型飞行器姿态快速机动控制方法

针对某弹道导弹释放的微小型飞行器的姿态控制任务需求,提出一种基于Gauss伪谱法的姿态快速机动控制方法。建立精确的姿态控制模型,并考虑反作用飞轮的耦合力矩项;采用Gauss伪谱法获取最优姿态轨迹,设计准滑模跟踪控制器以跟踪该最优轨迹。数字仿真结果表明,Gauss伪谱法计算得到的轨迹是最优的,准滑模跟踪控制器能实现对最优轨迹的良好跟踪,且对干扰力矩有较好的抑制作用。     

新消防法下保险与消防良性互动机制探析

根据新《消防法》国家鼓励保险公司承担火灾公众责任保险的规定,阐述了保险业在火灾公众责任保险中发挥经济补偿的功能和作用,有利于消防工作社会化和提高公共消防安全保障,并就如何开展良性互动机制进行分析。     

航空燃料水反应试验条件对试验结果的影响

航空燃料水反应试验是检测喷气燃料和航空汽油洁净性指标的一个重要方法,该方法的试验结果受试验条件影响.探讨了试验条件对试验结果的影响,通过考察摇动速率和摇动幅度,提出了优化摇动速率和摇动幅度的试验控制条件.在摇动时间为2min、摇动速率为150次/min、摇动幅度控制在185 mm、静置时间为5 min进行试验时,其试验结果均呈现很好的重复性和再现性,较好地消除了方法中试验条件控制对试验结果的影响.     

化工企业使用丙酮过程中火灾危险性研究

以某使用丙酮危化品企业为例,分析计算丙酮在使用过程中发生火灾爆炸事故的可能性及后果严重性,重点针对反应釜失控后果危险性、蒸气云爆炸后果危险性进行定量分析,并针对定量分析结果提出了相应的消防安全控制措施。     

侧链含锑聚硅烷的合成与性能研究

侧链含锑聚硅烷的合成可通过聚甲基硅烷的高分子反应在室温条件下实现,聚合物产率为75.2%,数均分子量为1600.其分子结构与组成可由元素分析、FT-IR、1H-NMR、29Si CP/MAS NMR、GPC和UV来确认.PSA可溶于一般常见的有机溶剂,紫外吸收的最大波长为330nm,其热分解特性表明,陶瓷收率为80%,可用作SiC陶瓷先驱体;其本体电导率为10-8～10-7S/cm,将其与碘掺杂,电导率可以达到10-5S/cm以上.     

Revisiting inspection game and inspector leadership through reaction networks

The inspection game is a two-player noncooperative game that models a situation where an inspector verifies whether the inspectee complies with the rules (on the assumption that the inspectee has the tendency to violate at least one of the rules). The usual approach in the analysis of this game seeks to find an optimal strategic inspection scheme for each of the two players yielding favorable payoffs. Recently, there have been some developments in the study of such games that use a mathematical structure known as reaction network involving a set of molecular species and the existing reactions among these species. In this paper, we use a reaction network to analyze the inspection game giving an alternative way of modeling the social situation. The molecular species play the role of the players' decision moves and their resulting gain or loss, while the reactions are the encounters of the decisions of the players which, as expected, yield payoffs. We reexamine the dynamics of the inspection game through the lens of reaction network theory and consider various situations that call for more detailed analyses such as equal or unequal reaction rates and inspection leadership. Conditions concerning reaction rates, initial population of decision species, benefits, and costs are determined in order to identify strategies that yield better payoffs both for the inspector and inspectee. These results illustrate practical insights rooted from the formulated simple game models.