磷碳键的构建

含有磷碳键的有机磷化合物广泛应用于农药、医药、塑料添加剂等领域,构建磷碳键是有机磷化学研究的基本问题之一．概要的评述了Michaelis-Arbuzov反应、Becker反应、过渡金属催化反应和含磷氢键化合物对不饱和烯炔的加成等几种形成磷碳键的化学反应．     

燃烧型焊条焊接A3钢的研究

基于燃烧合成技术的燃烧机理,结合焊接母材的材质,制备可用于手工施焊的燃烧型焊条焊接A3钢。对焊接试件进行力学性能测试和金相分析,结果表明:焊接试件的结合方式为冶金结合,焊缝合金在细晶强化和弥散强化的作用下,试件的抗拉强度(σb)达到370 MPa,抗弯强度(σf)达到1 100 MPa,成功实现了燃烧型焊条对A3钢的焊接。     

一类多分子化学反应系统的极限环

本文研究由低浓度三分子反应模型改进而建立的一类多分子化学反应模型,应用微分方程定性理论,完整地解决了该模型极限环的存在性、不存在性和唯一性问题,从而给出了化学浓度阀。     

导弹初始大角度转弯复合控制研究

基于直接力/气动力复合控制方法,研究了导弹初始快速大角度转弯问题。给出了直/气复合控制回路稳定性分析方法,并应用极点配置求得系统控制参数。最后对直/气复合控制回路稳定性进行了分析,对其时域跟踪进行了数学仿真。仿真结果表明,提出的控制方法可以提高系统转弯快速性,验证了复合控制方法的可行性。     

Revisiting inspection game and inspector leadership through reaction networks

The inspection game is a two-player noncooperative game that models a situation where an inspector verifies whether the inspectee complies with the rules (on the assumption that the inspectee has the tendency to violate at least one of the rules). The usual approach in the analysis of this game seeks to find an optimal strategic inspection scheme for each of the two players yielding favorable payoffs. Recently, there have been some developments in the study of such games that use a mathematical structure known as reaction network involving a set of molecular species and the existing reactions among these species. In this paper, we use a reaction network to analyze the inspection game giving an alternative way of modeling the social situation. The molecular species play the role of the players' decision moves and their resulting gain or loss, while the reactions are the encounters of the decisions of the players which, as expected, yield payoffs. We reexamine the dynamics of the inspection game through the lens of reaction network theory and consider various situations that call for more detailed analyses such as equal or unequal reaction rates and inspection leadership. Conditions concerning reaction rates, initial population of decision species, benefits, and costs are determined in order to identify strategies that yield better payoffs both for the inspector and inspectee. These results illustrate practical insights rooted from the formulated simple game models.     

一类化学反应动力系统的极限环

本文研究具有饱和输出的Prigogine三分子反应动力学模型,应用微分方程定性理论,完整地解决了系统极限环的存在性和唯一性问题。     

非均匀形核法制备Cu包覆纳米SiO2复合粉体

采用非均匀形核法制备了Cu包覆纳米SiO2复合颗粒,利用X射线衍射仪、扫描电镜、能谱仪及透射电镜等分析手段对复合颗粒进行了表征,并探讨了包覆结构的形成机制。结果表明:复合颗粒分散均匀,无团聚,单颗粒内包含多个分布均匀的纳米SiO2颗粒,且均被Cu包覆层隔离,纳米SiO2颗粒的分散性得到了显著改善;新制备的复合颗粒不存在氧化,在存放或者制样过程中会部分氧化为Cu2O;纳米SiO2颗粒表面Cu包覆层的形成机制主要是非均匀形核作用,包覆的结构取决于 Cu晶粒在纳米SiO2颗粒表面的沉积以及对复合颗粒的团聚控制。     

一类可逆生化反应动力系统的定性分析

研究生化反应中一类可逆饱和反应的数学模型：应用微分方程定性理论,比较完整地解决了该系统极限环的存在性、唯一性和不存在性等问题。     

A melt-cast Duan-Zhang-Kim mesoscopic reaction rate model and experiment for shock initiation of melt-cast explosives

A melt-cast Duan-Zhang-Kim (DZK) mesoscopic reaction rate model is developed for the shock initiation of melt-cast explosives based on the pore collapse hot-spot ignition mechanism. A series of shock initiation experiments was performed for the Comp B melt-cast explosive to estimate effects of the loading pressure and the particle size of granular explosive component, and the mesoscopic model is validated against the experimental data. Further numerical simulations indicate that the initial density and formula proportion greatly affect the hot-spot ignition of melt-cast explosives.     

药物爆燃产生强红外辐射的分析研究

定向红外脉冲强光辐射是定向红外对抗技术中的关键技术,用来破坏敌方精确制导武器或C4I系统中的红外传感器。本文主要研究了药物爆燃产生近红外辐射的特性,通过计算化学反应热分析了药物爆燃产生的总能量,并且详细介绍了几种不同的实验方法和实验结果。