Theoretical design of new bridge-ring insensitive high energy compounds by selected normal Diels-Alder reactions between NH2-substituted oxazoles and NO2/NF2/NHNO2-substituted ethylenes/acetylenes

In this work, NH₂-substituted oxazoles and NO₂/NF₂/NHNO₂-substituted ethylenes/acetylenes were designed and used as dienes and dienophiles, respectively, in order to develop new bridge-ring insensitive high energy compounds through the Diels-Alder reaction between them. The reaction type, reaction feasibility and performance of reaction products were investigated in detail theoretically. The results showed that dienes most possibly react with dienophiles through the HOMO-diene controlled normal Diels-Alder reaction at relatively low energy barrier. Tetranitroethylene could react with the designed dienes much more easily than other dienophiles, and was employed to further design 29 new bridge-ring energetic compounds. Due to high heat of formation, density and oxygen balance, all designed bridge-ring energetic compounds have outstanding detonation performance, 16 of them have higher energy than HMX (1,3,5,7-tetranitro-1,3,5,7-tetrazocine) and 2 others even possess comparative energy with the representative of high energy compounds CL-20 (2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane). The predicted average h₅₀ value of these bridge-ring energetic compounds is 83 cm, showing their low impact sensitivity. The NH₂ groups could obviously impel the proceeding of Diels-Alder reactions, but would slightly decrease the energy and sensitivity performance. In all, the new designed bridge-ring compounds have both high energy and low sensitivity, and may be produced through Diels-Alder reactions at relatively low energy barrier. This paper may be helpful for the theoretical design and experiment synthesis of new advanced insensitive high energy compounds.     

Damage to aircraft composite structures caused by directed energy system: A literature review

This paper presents a comprehensive review of the research studies on direct energy system effect on aircraft composite structures to develop a good understanding of state-of-the-art research and devel-opment in this area. The review begins with the application of composite materials in the aircraft structures and highlights their particular areas of application and limitations. An overview of directed energy system is given. Some of the commonly used systems in this category are discussed and the working principles of laser energy systems are described. The experimental and numerical studies re-ported regarding the aircraft composite structures subject to the effect of directed energy systems, especially the laser systems are reviewed in detail. In particularly, the general effects of laser systems and the relevant damage mechanisms against the composite structures are reported. The review draws attention to the recent research and findings in this field and is expected to guide engineers/researchers in future theoretical, numerical, and experimental studies.     

涡轮泵故障检测的频段能量比SOM算法

为了解决缺少故障样本情况下的涡轮泵健康状态判别问题,分析了涡轮泵振动信号的频谱,提取了频段能量比作为其故障检测特征,并讨论了自组织映射的竞争学习原理及聚类结果的U-矩阵表示,提出了一种基于频段能量比的自组织映射故障检测算法,并实现了该算法最佳匹配神经元的选择和权重向量的自适应更新。通过某型液体火箭发动机历史试车数据的验证,结果表明,健康涡轮泵数据利用该算法聚类时仅存在一个类别,相邻神经元距离小于0.1;反之,故障涡轮泵数据利用该算法聚类时明显存在两个或多个类别,且相邻神经元的最大距离大于0.1。因此,基于频段能量比的SOM算法能有效地判别涡轮泵的健康状况。     

机械法超细粉碎技术

固体物料经超细粉碎,可以改善其物理化学性质,提高应用性能．机械法超细粉碎技术成熟,易实现工业化,而且生产能力大,成本低．介绍了机械法超细粉碎设备,重点介绍了气流粉碎机,包括工作原理、特点,机计、注意事项,在农药、食品工业的典型应用,并对其在国防工业的应用作了展望．     

水蒸发冷却空调在班用帐篷中的应用研究

通过介绍西北地区班用帐篷夏季降温用水蒸发冷却空调器的设计过程及基本原理,分析得出结论：水蒸发冷却空调在西北干旱地区班用帐篷中的应用潜力巨大。     

反导动能拦截武器的现状与发展研究

介绍了动能拦截弹在弹道导弹防御中的应用,分助推段拦截、中段拦截、末段拦截对美国发展的动能拦截武器进行了详细说明。介绍了动能拦截弹的组成,给出了动能拦截器的关键技术,对动能拦截器技术的发展进行了阐述。     

一种面向节点定位的移动信标动态路径规划方法

针对基于移动信标的传感器节点定位问题,提出一种基于在线决策的移动信标动态路径规划方法.针对以往算法大都只适用于节点均匀分布的局限,该方法用移动信标不断获取两跳范围内的未定位节点数目,并向最大覆盖未定位节点方向移动,不需要网络先验信息,即可实现路径的优化.仿真结果表明:与传统方法相比,该方法无需网络的先验信息,在移动路径长度上具有明显优越性,减少了信标的能量消耗,更适用于户外部署的大规模传感器网络.     

基于小波包能量谱的管道缺陷磁记忆检测信号特征研究

现有磁记忆检测技术判定准则,只能指示应力集中位置,无法进一步获取应力集中信息。为获取应力集中信息,提出一种基于小波包能量谱的磁记忆信号分析方法,进行试件拉伸试验。拉伸应力为200 MPa时,信号小波包能量谱分布较为均匀,各频带能量占总能量之比均小于15%,不存在集中分布的频带范围。拉伸应力为410 MPa时,信号小波包能量谱最大值分布在1,3,4频带,1~4频带能量之和占总能量的73.8%,小波包能量主要集中在低频段。试件屈服后,信号小波包能量谱最大值分布在1,2频带,能量谱分布极为分散,能量主要集中在低频段的1,2频带,1~3频带能量之和占总能量的87.3%。管道试件应力集中程度与磁记忆信号的小波包能量谱分布特征有关,应力集中程度越低,小波包能量谱分布越均匀;应力集中程度越高,小波包能量谱分布越集中,能量主要向低频段集中。     

运用统计能量分析法解决高频声振问题的研究

为了得出统计能量分析法的适用范围和成功应用的关键因素,应用模态理论对系统的输入功率和耦合损耗因子进行了研究,挖掘了统计能量分析法中“统计”的更深层次的含义.通过对统计能量分析法原理的分析,提出增大系统的特征尺寸和系统阻尼、增大分析带宽和采用宽带激励均可提高统计能量分析的精度.     

室温下单电子晶体管3种临界尺寸的确定

为使单电子晶体管达到实际应用的地步,开展室温条件下相关研究成为必然。从正统理论出发,推导、计算出室温条件下单电子晶体管能否正常工作的库仑岛临界尺寸:存储器件为6.5nm,逻辑器件为1.5nm;本文还推导和计算出单电子晶体管室温下发生能量量子化效应的临界尺寸:4.7nm,并对这3种临界尺寸进行了验证和分析。另外,通过比较分析本文还得出了室温条件下,所有逻辑器件均必须考虑能量量子化效应,所有存储器件应尽量考虑能量量子化效应的结论。分析结果表明,库仑岛临界尺寸的确定对单电子晶体管的实际应用具有重要意义。