Theoretical study of an energetic material di-1H-1,3,4-triazole derivatives

Computations by density functional theory (DFT) method are performed on a series of di-1H-1,3,4-triazole derivatives with different substituents and linkages. The heat of formation (HOF) is predicted by the designed isodesmic reactions. The predicted results reveal that –N₃ and –NN– groups are effective structural units for increasing the HOF values of the di-1H-1,3,4-triazole derivatives. The HOMO–LUMO gap is affected by the substituents and linkage groups. Detonation performance is evaluated using the Kamlet–Jacobs approach based on the calculated density and HOF. The results indicate that –NO₂, –NF₂, –NH–, –NH–NH– and –NN– groups are helpful for enhancing the detonation properties of di-1H-1,3,4-triazole derivatives. The bond dissociation energy and bond order of the weakest bonds are analyzed to investigate their stability. It is observed that the –CH₂–, –CH₂–CH₂– and –CHCH– groups are effective structural units for improving the stabilities of these derivatives. Considering the detonation performance and the stability, five compounds are screened as the potential candidates for high energy density materials.     

高科技武器装备发展推动作战理念的创新

结合美国在近几年的几次局部战争中所使用的高科技的信息化武器装备、远程作战武器和精确打击武器等武器装备,研究分析了高科技武器装备的发展动态,促进产生了一些新的作战理念(战术战法、作战理论),如网络中心战、夺取制信息权、非对称作战和非线性作战,而新的作战理念又推动了高科技武器装备的完善和进一步发展。同时还分析了高科技武器装备目前尚存在的一些不足。     

管道机器人在三通处的通过性分析

三通是管道机器人经常遇到的典型障碍之一,克服该障碍的能力用管道机器人在三通处通过性来描述。文中提出一种描述差压驱动式管道机器人三通通过性的数学模型,该模型由一组组合约束构成。通过对约束方程的分析讨论、与管道机器人弯道通过性的对比分析,得出了规律性的结论。管道机器人在三通处的姿态、单元体的几何尺寸、行走轮结构形式对其通过性都有不同程度的影响。所提出数学模型是管道机器人三通自主行走控制策略设计和相应结构设计的理论基础。     

二维拉格朗日和欧拉结合法在流处理器MASA上的实现与评测

现代半导体工艺技术的发展使得在单芯片上放置数百个运算单元成为可能,但是全局片上片外带宽受限。通用处理器体系结构不能较好地适应变化,仍然依靠全局片上结构,少量的运算单元。而流体系结构拥有大量的运算单元、鲜明的存储层次,使得在有限的片外带宽下,用高的本地带宽来满足大量运算单元的需求。首先介绍了原型MASA流体系结构,然后给出了爆轰流体力学中的二维拉格朗日和欧拉结合法(Ygx2)在流体系结构上实现的实例研究,最后用时钟精确的模拟器来评测应用的运行性能,结果表明Ygx2应用在500MHz的MASA上运行结果与1.6GHz的Iantium2的比较快近4倍,证实了流体系结构在高性能计算领域的极大潜力。     

Preparation of reduced sensitivity co-crystals of cyclic nitramines using spray flash evaporation

The present day weapon technology demands novel energetic materials that exhibit simultaneous high explosive yield and reduced sensitivity. This article demonstrates application of spray evaporation to prepare reduced sensitive co-crystals of high performance nitramine explosives like HMX and CL-20 with a relatively less insensitive explosive 1,1-diamino-2,2-dinitroethylene or FOX-7. Stronger intermolecular hydrogen bonding in FOX-7 is responsible for limited solubility in most of organic solvents. Large solubility differences of FOX-7 with HMX and CL-20 restricts it's co-crystallization through classical methods that yields thermodynamically favorable product. Spray flash evaporation, a kinetic crystallization method, has been therefore adopted and could successfully produce CL-20/FOX-7 (2:1) and HMX/FOX-7 (4:1) co-crystals. The fine powdered materials obtained were characterized by SEM, powder XRD, Raman spectroscopy, DSC-TGA etc. Multipoint Raman spectra showed consistent occurrence of spectral features indicating stoichiometric co-existence of ingredients in the crystal lattices. DSC analysis showed absence of all thermally assisted solid-solid phase transformation in the co-crystals as they were observed in pristine materials. The thermal stability calculated in terms of activation barrier for decomposition, revealed the CL-20/FOX-7 co-crystal to be intermediately stable on comparison to their constituents while, the HMX/FOX-7 co-crystal is more stable. Compared to pure HMX and CL-20, both the co-crystals have shown higher insensitivity to impact force, suggesting them to be suitable for future generation insensitive munitions.     

纤维缠绕复合材料夹芯圆柱体高应变率压缩吸能机理

为研究纤维缠绕复合材料夹芯圆柱体吸能元件在高应变率冲击压缩载荷作用下的变形损伤模式和能量吸收机理,采用ABAQUS商用有限元软件和分离式Hopkinson压杆装置开展数值模拟分析和试验验证研究。对比分析宏观力学响应规律和微观损伤破坏机理,可知吸能结构元件在高应变率压缩载荷下的力学响应具有典型的弹塑性特征,内部芯材主要产生压缩塑性损伤,而表层复合材料沿环向产生拉伸断裂破坏。研究表明,该吸能元件冲击压缩吸能特性优异,可满足水下结构平台的冲击防护和浮力储备要求。     

靴形喷油速率耦合预喷射对超高压共轨柴油机性能的影响

在介绍超高压共轨系统工作原理的基础上,基于GT-Power软件建立单缸超高压共轨柴油机的仿真模型,并利用试验验证模型的准确性,而后通过模型分析不同喷油速率、靴形喷油速率耦合不同预喷油量和靴形喷油速率耦合不同预喷提前角对超高压共轨柴油机动力性、经济性以及燃烧排放特性的影响。结果表明:通过调整超高压共轨系统中电控增压器电磁阀和喷油器电磁阀的开启时间,能够实现喷油速率的柔性可调。随着喷油速率从矩形变化到靴形,柴油机缸内压力、温度以及NO_x排放量均逐渐降低,而soot排放量逐渐升高,且靴形喷油速率可使柴油机获得最大的功率(扭矩)和最低的油耗率。靴形喷油速率耦合较小的预喷油量可以使柴油机获得更好的动力性、经济性和燃烧特性,但同时也会导致NO_x排放量的升高。靴形喷油速率耦合较大的预喷提前角有助于改善柴油机排放特性,但受到预喷油量的限制,效果并不明显。     

满足大动压模拟要求的试验弹道优化设计

为了解决弹道导弹在高海拔发射场进行飞行试验时的大动压检验问题,提出一种模拟大动压条件的试验弹道设计方法。针对发射场的实际特点,建立残骸再入的动力学模型与落区边界模型;将大动压模拟条件转化为过程约束,提出一种主动段联合优化策略。基于自适应模拟退火算法,分别设计了三组满足不同大动压模拟条件和各项约束的试验弹道,并给出了对应的落区调整方案,验证了该方法的可行性。设计结果表明,最大动压主要出现在一级,一级最大负攻角增加,则最大动压也明显提高;同时调整发射方位角和二、三级程序角可以保证试验弹道满足弹头落点约束条件。     

建立雷达超视距探测效能库的一种快速算法

蒸发波导环境中微波雷达经常会出现超视距探测,建立雷达超视距探测效能库有利于微波超视距雷达探测效能的发挥。提出了一种计算雷达超视距探测效能的快速算法,即以蒸发波导高度、总体理查森数和海面风速为变量,先建立雷达超视距探测效能查询表,再利用查表的方法得到各种气象条件下雷达的探测效能,以此作为探测效能库的数据基础。最后将基于此算法得到的雷达探测规律与实际观测进行了比较,表明此算法是可行的。     

弹体压心位置变化对末制导炮弹弹道的影响

首先对比弹体压心位置变化对火箭增程弹道和末制导炮弹名义弹道的不同影响,重点分析弹体压心位置变化对末制导炮弹末导段弹道的影响特点,得出弹体压心位置变化对末导段弹道的捕获域和有效攻击区有着重要影响的结论。该结论对末制导炮弹的射表编拟以及新型末制导炮弹的设计都具有重要指导意义。