超声波辅助微波消解预处理测量污泥金属元素

以实验室污泥和污水厂污泥为研究对象,建立了超声波辅助微波消解预处理测量污泥金属元素的方法与程序。首先通过超声波分散污泥絮体,然后对污泥进行加热预处理和微波消除,最后采用火焰原子吸收法测量污泥中的金属元素。结果表明,150 W超声波作用于25 mL污泥3 min为超声波分散污泥的较优条件,能保证后续操作过程取样均匀。微波消解前适宜的加热预处理条件为90℃,20 min。实验室污泥微波消解的较优酸体系为2 mL双氧水＋4 mL反王水（或4 mL王水）;污水厂污泥微波消解的较优酸体系为1 mL氢氟酸＋2 mL双氧水＋4 mL王水,同时,第3阶段消解条件为压强2.0 MPa下消解20 min。超声波辅助微波消解预处理具有用酸量少、简易快捷、准确度和精密度高等优点,测量K,Ca,Mg,Fe的相对标准偏差≤2.75%,加标回收率为97.5%～102%。     

金属橡胶／橡胶复合叠层耗能器试验建模研究

采用电液伺服材料试验机的位移加载方式,对金属橡胶／橡胶复合叠层耗能器进行动态试验研究,结果表明：耗能器的恢复力同时受频率和振幅的影响具有非线性迟滞特性。在此基础上,结合理论分析建立耗能器的动力学模型,提出一种参数分离识别法,辨识出模型中的未知参数。将辨识结果与试验曲线进行对比,结果表明,所建模型可靠,且参数识别精度能够满足工程应用的要求。     

三峡库区水环境污染预警与决策系统设计与实现

以三峡库区重庆段水环境地质调查项目为基础,综合应用数据库,GIS,RS,GPS,计算机网络和现代检测技术及水环境中有机污染物、营养物、重金属污染的研究方法,提出了库区水环境污染物预警与决策支持信息系统总体设计和数据库设计架构。为政府部门科学决策和管理监控提供一个先进的信息平台,也为整个三峡库区水环境可持续发展提供有效的信息参考。     

焊接切割与火灾

焊割火灾事故呈上升趋势。文章分析了焊割火灾爆炸危险性,并提出了预防措施。     

介子跃迁形状因子的重夸克极限和1/m_Q修正

在BS理论框架下,对0~-→0~-和0~-→1~-(0~-和1~-分别代表赝标介子和矢量介子)跃迁的形状因子进行模型无关的分析.结果表明BS框架既能给出重夸克极限下的自旋—味对称性,又能给出重夸克有效理论关于1/m_Q修正的Luke定理及其它关系.     

营房室内有害气体污染预测研究

由于营房建筑、装饰材料质量不合格,施工工艺不正确等原因,引起营房室内有害气体污染,严重威胁到住用者的生命健康和部队战斗力。研究营房室内有害气体污染变化发展的规律,对营房室内有害气体污染进行准确的预测,做好预防措施,可以避免营房室内有害气体污染的发生。采用灰色预测方法对营房室内有害气体污染水平进行预测,在 GM(1,1)模型的基础上进行改进,从而建立起营房室内有害气体污染水平预测模型。通过对预测模型进行检验,证实营房室内有害气体污染预测模型能较好的预测营房室内有害气体污染水平的发展变化趋势,模型的建立是成功的。     

开口金属腔体对强电磁脉冲的耦合效应

为了评价腔体开口因素对核电磁脉冲(High-amplitude Electro Magnetic Pulse,HEMP)和高功率微波(High Power Microwave,HPM)破坏效能的影响,采用CST电磁计算软件建立强电磁脉冲的孔缝耦合模型,研究孔缝的位置、大小以及长宽比对HEMP和HPM耦合效应的影响。结果表明,孔缝的位置、大小及长宽比对HEMP的耦合效应影响较大,合理控制孔缝的位置、大小以及长宽比能在一定程度上削弱HEMP的破坏效能。对于HPM,相同条件下其耦合效应要明显强于HEMP。在孔缝达到一定尺寸后,其大小和长宽比对HPM的耦合效应影响较小,仅孔缝位置会带来较大的影响。当开口平面与HPM入射方向平行时,耦合效应最弱,但此时耦合进入腔体内的能量还是很容易达到多种电子元器件的电磁损伤阈值级别。     

Effect of fusion welding processes on tensile properties of armor grade,high thickness,non-heat treatable aluminium alloy joints

AA5059 is one of the high strength armor grade aluminium alloy that finds its applications in the military vehicles due to the higher resistance against the armor piercing (AP) threats. This study aimed at finding the best suitable process among the fusion welding processes such as gas tungsten arc welding (GTAW) and gas metal arc welding (GMAW) by evaluating the tensile properties of AA5059 aluminium alloy joints. The fracture path was identified by mapping the low hardness distribution profile (LHDP) across the weld cross section under tensile loading. Optical and scanning electron microscopies were used to characterize the microstructural features of the welded joints at various zones. It is evident from the results that GTAW joints showed superior tensile properties compared to GMAW joints and this is primarily owing to the presence of finer grains in the weld metal zone (WMZ) and narrow heat-affected zone (HAZ). The lower heat input associated with the GTAW process effectively reduced the size of the WMZ and HAZ compared to GMAW process. Lower heat input of GTAW process results in faster cooling rate which hinders the grain growth and reduces the evaporation of magnesium in weld metal compared to GMAW joints. The fracture surface of GTAW joint consists of more dimples than GMAW joints which is an indication that the GTAW joint possess improved ductility than GMAW joint.     

Optimization of resistance spot brazing process parameters in AHSS and AISI 304 stainless steel joint using filler metal

The aim of this research study was to determine optimal resistance spot brazing parameters for joining between AHSS and AISI 304 stainless steel by using filler metal. The key parameters investigated in this study consist of the brazing current, electrode pressure and brazing time. The Taguchi method was applied to the design of experiments. Signal-to-Noise ratio was introduced in the study to identify optimal levels from the process where input parameters yield increased shear strength. Brazing was thus implemented with 5,000A brazing current, 0.70 MPa electrode pressure, and 1.50s brazing time. The maximum shear strength obtained was 54.31 N·mm⁻² in accordance with input parameter settings. In addition, Cu-rich phase and Ag_0.4Fe_0.6 intermetallic phases were found at the interface zone.     

Cu粉粒径及含量对Ni/MH电池负极放电性能的影响

为了提高Ni/MH电池中储氢电极的放电性能,以电解Cu粉为充填材料与活性物质混合制备电极,研究Cu粉粒径及含量对电极性能的影响。研究发现,Cu粉粒径越小,含量越高,电极的放电容量、高倍率放电性能、及在低温和高温下的放电能力均提高,且Cu充填电极的性能优于Ni充填电极。Cu充填电极中析氢反应的交换电流密度较大,过电势较小,说明其电催化活性好,电极反应阻力小。SEM分析发现,充放电循环后的Cu充填电极,其储氢合金颗粒表面覆盖着一层细小Cu颗粒和丝状物,这是电极性能提高的主要原因。