Multifunctional A356 alloy/ PKSAnp composites: Microstructure and mechanical properties

Mechanical properties and microstructure of multifunctional composites produced with palm kernel shell ash nanoparticle (PKSAnp)-A356 alloy composites was studied. The composites were produced using Double layer feeding stir casting method (DLF-SCM) by adding 1 wt%‒4 wt.% PKSAnp. The microstructure, density, electrical and mechanical properties were determined. The results shows that there was a uniform distribution of the PKSAnp in A356 alloy. The mismatch at the interface between the PKSAnp and A356 alloy was 4.26%. Improvement of 30.47%, 41.91%, 49.52%, 40.90% and 65.09% were obtained for hardness values, tensile, yield strength, %elongation and impact energy at 4 wt% PKASnp. The work has established that the developed composites can be used for multifunctional applications where combination of toughness and strength is vital.     

高陡度非球面磨削亚表面损伤深度规律

具有高陡度非球面特性的光学元件可以明显改善光学系统的空气动力学性能,从而提升和优化系统综合性能。磨削加工方法可以作为此类元件的前期加工工序,而磨削难免会造成零件的亚表面损伤,且在这种高陡度非球面磨削加工中磨削参数是实时变化的,造成整个工件亚表面损伤深度不一致。针对这种情况,建立亚表面损伤预测模型,并结合半球形砂轮磨削的特点,通过理论计算预测非球面磨削亚表面损伤深度分布规律。在此基础上,以热压多晶氟化镁平面为对象进行模拟参数实验,通过磁流变抛斑点法得到各组参数下亚表面损伤深度情况,结果显示损伤深度范围在12.79μm~20.96μm之间,且沿试件半径方向由内向外呈增大趋势,结果与预测模型相吻合。     

Thomas Firth and Sons – Steelmakers to the Arms Industries. Part 2: Heavy Armaments

Firth’s were the first of the Sheffield steel makers to enter the field armaments. Their involvement with Colt has been outlined in an article in the journal of the Colt Collectors Association in America and their activities as steelmakers to the small-arms industries has been covered in a previous issue of this Journal. This article gives a brief overview of their involvement as manufacturers in the field of heavy armaments, being the first to make all-steel guns and their evolving role in the use of steel for ordnance, culminating in the displacement of wrought iron by the adoption of steel for ordnance manufacture by the Royal Gun Factory in the 1880s. It also highlights their development of stainless steel in this context.     

两栖车辆用牺牲阳极材料研究进展

结合两栖车辆的发展和两栖车辆牺牲阳极阴极保护性能指标要求,介绍了两栖车辆用牺牲阳极材料研究进展,分析了主要合金元素作用机理。根据牺牲阳极耐干湿交替性能要求和实车试验结果,采用极化时间、车体保护电位、活化性能等技术指标,评价了五元和六元牺牲阳极对两栖车辆阴极保护效果。展望了两栖车辆牺牲阳极阴极保护研究的下一步工作方向和重点。     

2A12铝合金焊接接头超声冲击处理前后拉伸性能分析

为克服铝合金薄板焊接接头强度偏低、韧性不足的缺点,用ER5356焊丝对不同厚度的2A12铝合金板材进行了手工氩弧焊接,并采用超声冲击处理对焊接接头进行全覆盖强化处理。采用金相显微镜观察了处理和未处理焊接接头的显微组织结构,对接头的力学性能进行了测试分析,分析了超声冲击处理改善2A12铝合金焊接接头力学性能的机理。结果表明：铝合金焊接接头经超声冲击强化处理后,6 mm和4 mm厚板材对接接头的抗拉强度分别提高了17.4%和23.7%,延伸率分别提高了28%和44%,焊缝表层组织得到明显细化。分析认为：晶粒大幅细化、组织致密化和缺陷减少,是超声冲击处理改善铝合金焊接接头抗拉伸性能的主要原因。     

储氢电极合金的温度特性研究

针对目前储氢电极合金不适用于电动汽车用大型电池的情况 ,以Ml (NiCoMnTi) 5 合金为例 ,系统研究了温度对储氢电极合金电化学性能的影响。结果表明 :随着温度升高 ,合金的放电容量降低 ,循环稳定性恶化 ,自放电加剧 ;但是在高温下合金的高倍率放电特性得到显著改善。     

磁性合金A1-xBx相图的理论计算

采用变分累积展开方法,研究了块体磁性合金的相图.利用随机键海森堡模型计算了面心立方、体心立方的居里点和耐尔点,给出了磁性合金临界点的计算公式,进而分别给出自旋1/2和3/2情况下Tc-x相图,并加以分析.     

Tuning the reactivity of Al–Ni by fine coating of halogen-containing energetic composites

In this paper, various core-shell structured Al–Ni@ECs composites have been prepared by a spray-drying technique. The involved ECs refer to the energetic composites (ECs) of ammonium perchlorate/nitrocellulose (AP/NC, NA) and polyvinylidene fluoride/hexanitrohexaazaisowurtzitane (PVDF/CL-20, PC). Two Al–Ni mixtures were prepared at atomic ratios of 1:1 and 1:3 and named as Al/Ni and Al/3Ni, respectively. The thermal reactivity and combustion behaviors of Al–Ni@ECs composites have been comprehensively investigated. Results showed that the reactivity and combustion performance of Al–Ni could be enhanced by introducing both NA and PC energetic composites. Among which the Al/Ni@NA composite exhibited higher reactivity and improved combustion performance. The measured flame propagation rate (v = 20.6 mm/s), average combustion wave temperature (T_max = 1567.0 °C) and maximum temperature rise rate (γ_t = 1633.6 °C/s) of Al/Ni@NA are higher than that of the Al/Ni (v = 15.8 mm/s, T_max = 858.0 °C, and γ_t = 143.5 °C/s). The enhancement in combustion properties could be due to presence of the acidic gaseous products from ECs, which could etch the Al₂O₃ shell on the surface of Al particles, and make the inner active Al to be easier transported, so that an intimate and faster intermetallic reaction between Al and Ni would be realized. Furthermore, the morphologies and chemical compositions of the condensed combustion products (CCPs) of Al–Ni@ECs composites were found to be different depending on the types of ECs. The compositions of CCPs are dominated with the Al–Ni intermetallics, combining with a trace amount of Al₅O₆N and Al₂O₃.     

Influence of yttrium on microstructure and properties of Ni–Al alloy coatings prepared by laser cladding

Ni–Al alloy coatings with different Y additions are prepared on 45^# medium steel by laser cladding. The influence of Y contents on the microstructure and properties of Ni–Al alloy coatings is investigated using X-ray diffraction, scanning electron microscopy, electron probe microanalyzer, Vickers hardness tester, friction wear testing machine, and thermal analyzer. The results show that the cladding layers are mainly composed of NiAl dendrites, and the dendrites are gradually refined with the increase in Y additions. The purification effect of Y can effectively prevent Al₂O₃ oxide from forming. However, when the atomic percent of Y addition exceeds 1.5%, the extra Y addition will react with O to form Y₂O₃ oxide, even to form Al₅Y₃O₁₂ oxide, depending on the amount of Y added. The Y addition in a range of 1.5–3.5 at.% reduces the hardness and anti-attrition of cladding layer, but improves obviously its wear and oxidation resistances.     

Dynamic globularization prediction during cogging process of large size TC11 titanium alloy billet with lamellar structure

The flow behavior and dynamic globularization of TC11 titanium alloy during subtransus deformation are investigated through hot compression tests. A constitutive model is established based on physical-based hardening model and phenomenological softening model. And based on the recrystallization mechanisms of globularization, the Avrami type kinetics model is established for prediction of globularization fraction and globularized grain size under large strain subtransus deformation of TC11 alloy. As the preliminary application of the previous results, the cogging process of large size TC11 alloy billet is simulated. Based on subroutine development of the DEFORM software, the coupled simulation of one fire cogging process is developed. It shows that the predicted results are in good agreement with the experimental results in forging load and microstructure characteristic, which validates the reliability of the developed FEM subroutine models.