Thermal decomposition of ammonium perchlorate catalyzed with CuO nanoparticles

Ammonium perchlorate (APC) is the most common oxidizer in use for solid rocket propulsion systems. However its initial thermal decomposition is an endothermic process that requires 102.5 J·g⁻¹. This manner involves high activation energy and could render high burning rate regime. This study reports on the sustainable fabrication of CuO nanoparticles as a novel catalyzing agent for APC oxidizer. Colloidal CuO nanoparticles with consistent product quality were fabricated by using hydrothermal processing. TEM micrographs demonstrated mono-dispersed particles of 15 nm particle size. XRD diffractogram demonstrated highly crystalline material. The synthesized colloidal CuO particles were effectively coated with APC particles via co-precipitation by using fast-crash solvent–antisolvent technique. The impact of copper oxide particles on APC thermal behavior has been investigated using DSC and TGA techniques. APC demonstrated an initial endothermic decomposition stage at 242 °C with subsequent two exothermic decomposition stages at 297.8 °C and 452.8 °C respectively. At 1 wt%, copper oxide offered decrease in initial endothermic decomposition stage by 30%. The main outcome of this study is that the two main exothermic decomposition peaks were merged into one single peak with an increase in total heat release by 53%. These novel features can inherit copper oxide particles unique catalyzing ability for advanced highly energetic systems.     

空间应用载荷的天地端到端IP隧道协议通信架构设计

在地面运控子网和载荷信息网中设计IPsec、GRE或RFC2003三种IP隧道协议,通过平台信息网和天地测控网,封装的用户数据包能在天地通信链路中路由,以支持在轨载荷和地面运控终端之间端到端的灵活通信。设计支持IP隧道协议通信的天地一体化信息网络架构,给出各级路由器的设置和网段IP地址分配,计算和分析出三种IP隧道协议的通信效率与实时性。分析结果表明,采用IP隧道协议对改变传统地面运控模式、提高运控效率具有重要意义。     

Optimizing natural gas pipeline transmission with nonuniform elevation: A new initialization approach

In this paper, we develop an iterative piecewise linear approximation approach with a novel initialization method to solve natural gas pipeline transmission problems with the nonuniform network elevation. Previous approaches, such as energy minimization methods, cannot be applied to solve problems with the nonuniform network elevation because they exclude pressure range constraints, and thus provide solutions far from optimum. We propose a new initialization model that considers pressure range constraints and improves the optimality of the solutions and the computational efficiency. Furthermore, we extend the energy minimization methods and provide the necessary conditions under which the extended methods operate in networks with the nonuniform elevation. We test the performances of the methods with previously reported pipeline networks from the literature, with the open data set GasLib, and with our industrial collaborator. The initialization approach is shown to be more efficient than the method with fixed initial breakpoints. The newly proposed initialization approach generates solutions with a higher accuracy than the extended energy minimization methods, especially in large‐size networks. The proposed method has been applied to natural gas transmission planning by the China National Petroleum Corporation and has brought a direct profit increase of 330 million U.S. dollars in 2015‐2017.     

系统复杂性及度量

复杂性是科学技术面临的挑战之一,研究系统复杂性有着重要意义。综述系统复杂性基本语义研究背景,分析国内外历史上对复杂性的界定及不同定义;针对复杂性的分类,以本体论和认识论分类为基本框架,吸纳最新的复杂性分类定义成果,重新对复杂性进行归类。在此基础上,对复杂性的度量指标进行分类阐述,对相应的数学工具进行归类说明。设计案例说明了复杂性概念分类及度量的有效性。     

同轴环缝气流作用下锥形液膜线性稳定性分析

为了分析气液同轴离心式喷嘴的雾化机理,对同轴气体作用下的锥形液膜进行时间稳定性分析,推导同轴气体作用下锥形液膜的色散方程,建立离心式喷嘴出口参数预测模型,用于数值求解色散方程。结果表明：喷嘴出口液膜厚度随着喷注压降的增加而减小,喷雾锥角、液膜速度和轴向速度随着喷注压降的增加而增大。同轴气体作用下液膜由正弦模式的表面波主导,因为正弦模式的表面波增长率远大于曲张模式的表面波增长率。当环缝气体喷注速度较小时,增加气体速度会减小气液相对速度,从而减弱气液相互作用,使得液膜主导表面波增长率和频率减小、破碎时间和破碎长度增加。而当环缝气体速度超过一个临界值后,随着气体速度的增大,液膜主导表面波增长率和频率迅速增大,破碎时间和破碎长度迅速减小。     

陆军无人装备作战指挥信息系统

本文对陆战场无人化、智能化作战需求及其对指挥信息系统的能力要求进行分析。以美军为典型样例对无人装备的指挥信息系统发展现状进行分析,对无人装备作战指挥信息系统体系架构进行构想,并提出未来需重点突破的关键技术,最后对军队无人装备指挥信息体系的发展提出了几点建议。     

定子磁钢轨道拼接错位对动圈式永磁直线电机性能的影响

陆基车载无人机电磁弹射器是一种新型的弹射起飞装置。为了实现高机动性,提出双边动圈式永磁直流直线电机和定子磁钢轨道分段拼接结构方案。为了评估定子磁钢轨道拼接可能对电机性能的影响,建立了永磁直线电机模型。利用有限元分析软件,分析研究了轨道分段拼接上下错位、左右错位以及倾斜错位可能造成的影响,根据分析结果给出了磁钢轨道拼接错位所允许的偏移范围大小。     

模糊论的复杂系统评价方法

模糊综合评价法对复杂系统进行评价具有其他评价方法无法比拟的优越性.介绍了模糊评价的基本原理及其数学模型,给出了复杂系统的模糊矩阵的表示方法及推理过程.重点分析了其在某型垂直/短距飞行器设计中的应用,证明了该方法在系统评价中的有效性.该方法可以有效地对复杂系统进行评价并对系统的设计有一定的指导意义.     

永磁无刷直流直线电机齿槽力补偿控制研究

永磁无刷直流直线电机的齿槽定位力对其低速性能影响很大,而单纯的设计方法不可能完全消除齿槽力的影响,为此,必须在控制系统中对齿槽力进行补偿。针对包含齿槽力模型的理想电机控制系统进行了理论分析,指出通过引入位置反馈环节可以消除齿槽力的不良影响。利用有限元分析方法计算了电机的推力和齿槽力波形,验证了低速条件下推力波动主要由齿槽力引起,并说明可以通过位置反馈来补偿推力波动。最后,提出将一个齿槽力周期分为多个区间,然后分段进行线性补偿的简易控制方法。该方法无需高精度的定位装置和复杂的控制算法即可实现对电机齿槽力的补偿,实验结果表明,所提方法能够有效抑制电机的推力波动。